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omeli [17]
2 years ago
9

The mechanism for the reaction described by 2N2O5(g) ---> 4NO2(g) + O2(g) is suggested to be (1) N2O5(g) (k1)--->(K-1) NO2

(g) + NO3(g) (2) NO2(g) + NO3(g) --->(K2) NO2(g) + O2(g) + NO(g)
(3) NO(g) + N2O5(g) --->(K3) 3NO2(g) Assuming that [NO3] is governed by steady-state conditions, derive the rate law for the production of O2(g) and enter it in the space below.
Rate of reaction= ∆[O2]/∆t = ???
Chemistry
1 answer:
aliina [53]2 years ago
5 0
Go add me on Snapchat christian3cruz
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A student dissolved a sample in hexane, spotted it on to a TLC plate and eluted using ethyl acetate. After visualizing the TLC p
Zepler [3.9K]

1) Consider the following silica gel TLC plate of compounds A, B, and C developed in hexanes:

<span><span>Determine the Rf values of compounds A, B, and C run on a silica gel TLC plate using hexanes as the solvent.</span>Which compound, A, B, or C, is the most polar?<span>What would you expect to happen to the Rf values if you used acetone instead of hexanes as the eluting solvent?</span><span>How would the Rf values change if eluted with hexanes using an alumina TLC plate?</span></span>

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2) You are trying to determine a TLC solvent system which will separate the compounds X, Y, and Z. You ran the compounds on a TLC plate using hexanes/ethyl acetate 95:5 as the eluting solvent and obtained the chromatogram below. How could you change the solvent system to give better separation of these three compounds?

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3) After a rather lengthy organic chemistry synthesis procedure, a student ran the product of the reaction on a TLC plate and obtained the result below. What might he/she have done wrong, if anything?

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4) A student spots an unknown sample on a TLC plate. After developing in hexanes/ethyl acetate 50:50, he/she saw a single spot with an Rf of 0.55. Does this indicate that the unknown material is a pure compound? What can be done to verify the purity of the sample?

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5) Consider a sample that is a mixture composed of biphenyl, benzoic acid, and benzyl alcohol. The sample is spotted on a TLC plate and developed in a hexanes/ethyl acetate solvent mixture. Predict the relative Rf values for the three compounds in the sample.

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6) Plate A, below, represents the TLC chromatogram of a compound run in hexanes. The same compound was then spotted on a large TLC plate and again run in hexanes. Which TLC plate, B, C, or D, correctly represents how far the compound would run on the longer plate?

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Back to TLC

Original content © University of Colorado at Boulder, Department of Chemistry and Biochemistry.
The information on these pages is available for academic use without restriction.
3 0
2 years ago
How many grams of sodium acetate ( molar mass = 83.06 g/mol ) must be added to 1.00 Liter of a 0.200 M acetic acid solution to m
Pie

<u>Answer:</u> The mass of sodium acetate that must be added is 30.23 grams

<u>Explanation:</u>

To calculate the number of moles for given molarity, we use the equation:

\text{Molarity of the solution}=\frac{\text{Moles of solute}}{\text{Volume of solution (in L)}}

Molarity of acetic acid solution = 0.200 M

Volume of solution = 1 L

Putting values in above equation, we get:

0.200M=\frac{\text{Moles of acetic acid}}{1L}\\\\\text{Moles of acetic acid}=(0.200mol/L\times 1L)=0.200mol

To calculate the pH of acidic buffer, we use the equation given by Henderson Hasselbalch:

pH=pK_a+\log(\frac{[\text{salt}]}{[\text{acid}]})  

pH=pK_a+\log(\frac{[CH_3COONa]}{[CH_3COOH]})

We are given:

pK_a = negative logarithm of acid dissociation constant of acetic acid = 4.74

[CH_3COONa]=?mol  

[CH_3COOH]=0.200mol

pH = 5.00

Putting values in above equation, we get:

5=4.74+\log(\frac{[CH_3COONa]}{0.200})

[CH_3COONa]=0.364mol

To calculate the mass of sodium acetate for given number of moles, we use the equation:

\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}

Molar mass of sodium acetate = 83.06 g/mol

Moles of sodium acetate = 0.364 moles

Putting values in above equation, we get:

0.364mol=\frac{\text{Mass of sodium acetate}}{83.06g/mol}\\\\\text{Mass of sodium acetate}=(0.364mol\times 83.06g/mol)=30.23g

Hence, the mass of sodium acetate that must be added is 30.23 grams

7 0
2 years ago
How much volume (in cm3) is gained by a person who gains 11.1 lbs of pure fat?
kirill [66]

The density of human fat is 0.918 g/cm^{3}. The mass of the pure fat is 11.1 lbs.

First convert mass from lb to g as follows:

1 lb=453.592 g

Thus,

11.1 lb\rightarrow 11.1\times 453.592 g=5034.875 g

Density of a substance is defined as mass per unit volume, thus volume can be calculated as:

V=\frac{m}{d}

Putting the values,

V=\frac{5034.875 g}{0.918 g/cm^{3}}=5484.61 cm^{3}

Therefore, volume gained by person will be 5484.61 cm^{3}.

6 0
2 years ago
When the solutes are evenly distributed throughout a solution, we say the solution has reached _______. when the solutes are eve
german
If the solutes are dispersed evenly in their particular solvent we say that the solution has reached diffusion I believe.
5 0
2 years ago
Synthesis of disubstituted benzenes involves two steps, each introducing one of the functional groups. For the synthesis of p-ch
Setler79 [48]

Answer:

The synthesis of p-chlorobenzenesulfonic acid with the reagents for each step and the structure of the monosubstituted intermediate compound is shown in the drawing below.

Explanation:

Benzenesulfonic acid is obtained from the sulfonation of benzene, using concentrated smoking sulfuric acid.

Chlorination of benzenesulfonic acid with chlorine without catalyst requires a polar solvent, such as acetic acid to obtain the selectivity in the position for and the ortho derivative in a low proportion.

7 0
2 years ago
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