Imagine that you are given the mass spectra of these two compounds, but the spectra are missing the compound names.
1 answer:
The structures of the isomers and the m/z values of their peaks are not given in the question. The complete question is provided in the attachment
Answer:
Compound 2 (2,5-dimethylhexane) will not have the peaks at 29 and 85 m/z
Explanation:
The fragmentation of molecules by electron ionization of mass spectrometer occurs according to Stevenson's Rule, which states that "The most probable fragmentation is the one that leaves the positive charge on the fragment with the lowest ionization energy". This is much like the Markovnikov's Rule in organic chemistry which has predicted the formation of most stable carbocation and the addition of hydrogen halide to it.
The mass spectra of compound 1 (2,4-dimethylhexane) will contain all the m/z values mentioned in the question. Each peak indicate towards homologous series of fragmentation product of the compound 1. The first peak can be attributed to ethyl carbocation (m/z = 29), with the increase of 14 units the next peak indicates towards propyl carbocation (m/z = 43) and onwards until molecular ion peak of 114 m/z.
Compound 2 (2,5-dimethylhexane) structure shows that the cleavage of C-C bond will not yield a stable ethyl and hexyl carbocation. Hence, no peaks will be observed at 29 and 85 m/z. The absence of these two peaks can be used to distinguish one isomer from the other.
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Answer:
As you haven't explained what measurements you took before solving this problem, I will explain the general procedure to evaluate the efficiency of a kettle. I hope it helps you. I´ll send an attachement file with the full answer, since I couldn't write it here.
I assume that the material that is going to be heated in the kettle is water.
1- You have to boil water in it and take the time it takes to its boiling point (in seconds).
2- You have to evaluate the amount of energy the water absorbed Q with the efficiency formula which I explain in the attachement file.
3- Divide Q by the time it took to bring the water to boiling so you can have the power it consumed.
4- You divide the last value you obtained by the Kettles's power rating.
5- Multiply the last value by 100 to obtain a percentage value of efficiency.
Explanation:
Efficiency is the ration of a machine's useful work, in this case how much energy the water absorbed to get to its boiling point divided by the time it took to get to this point, and the total energy expended, in this case the kettles's power rating.
