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anygoal [31]
2 years ago
10

Suppose that there are two components, A and B, in a mixture. The chemical affinity of A for the stationary phase is less than t

hat of B and the chemical affinity of A for the mobile phase is greater than that of B. If the mixture is subjected to paper chromatography, which substance will have traveled further at the completion of the experiment?Which substance will have the largest Rf value?
Chemistry
1 answer:
kherson [118]2 years ago
8 0

Answer: Substance A will travel further at the end of the experiment and also it will have larger Rf value compared to substance B.

Explanation:

The affinity of substance towards the stationary or mobile phase means how much the substance binds to a phase. Because component B has greater affinity for the stationary phase, it binds more to stationary phase; while component A binds more to a mobile phase. Due to differences in their affinity, component A and B can be separated using chromatography. Stationary phase, as its name says, stays fixed, while the mobile phase is moving. Together with the mobile phase travels component A because of its greater affinity, while component B stays fixed due to its greater affinity for the stationary phase. In conclusion , substance A will travel further at the end of the experiment.

Rf value (Retention Factor) can be defined as the ratio of the distance traveled by a substance in the mobile phase (solute) compared with the distance traveled by the front of the mobile phase itself (solvent front).

Rf = Migration distance of substance / Migration distance of solvent front

Because the solvent front is always larger from the distance traveled by the solute, Rf values are always between 0 and 1. The farther a compound traveled, the larger its Rf value will be. In this example, substance A will have larger Rf value compared to substance B.

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For the reaction PCl5(g) <--> PCl3(g) Cl2(g) at equilibrium, which statement correctly describes the effects of increasing
xenn [34]

The given question is incomplete. The complete question is :

For the reaction PCl_5(g)\rightleftharpoons PCl_3(g)+Cl_2(g) at equilibrium, which statement correctly describes the effects of increasing pressure and adding PCl_5, respectively

a) Increasing pressure causes shift to reactants, adding PCl_5 causes shift to products.

b) Increasing pressure causes shift to products ,adding PCl_5 causes shift to reactants.

c) Increasing pressure causes shift to products, adding PCl_5 causes shift to products.

d) Increasing pressure causes shift to reactants,adding PCl_5 causes shift to reactants

Answer: Increasing pressure causes shift to reactants, adding PCl_5 causes shift to products.

Explanation:

Any change in the equilibrium is studied on the basis of Le-Chatelier's principle.

This principle states that if there is any change in the variables of the reaction, the equilibrium will shift in the direction to minimize the effect.

For the given equation:

PCl_5(g)\rightleftharpoons PCl_3(g)+Cl_2(g)

a)  If the pressure is increased, the volume will decrease according to Boyle's Law. Now, according to the Le-Chatlier's principle, the equilibrium will shift in the direction where decrease in pressure is taking place. As the number of moles of gas molecules is lesser at the reactant side. So, the equilibrium will shift in the left direction. i.e. towards reactants.

b) If PCl_5 is added, the equilibrium will shift in the direction where PCl_5 is decreasing. So, the equilibrium will shift in the right direction. i.e. towards products.

8 0
2 years ago
You are presented with a mystery as part of your practical experiment. You have a solution of Pb(NO3)2 that has a worn label mak
Orlov [11]

Answer:

Minimum volume of H₂SO₄ required for H₂SO₄ to be in excess = 0.0556 mL

Explanation:

Pb(NO₃)₂ + H₂SO₄ -----> PbSO₄ + 2HNO₃

For this reaction, we know that the max concentration of Pb(NO₃) according to the bottle is 0.999M and to ensure the other reactant in the reaction is in excess, we'll do the calculation with a Pb(NO₃) that's a bit higher, that is, 1.0M.

Knowing that Concentration in mol/L = (number of moles)/(volume in L)

Number of moles of Pb(NO₃) added = concentration in mol/L × volume in L = 1 × 0.001 = 0.001 mole

According to the reaction,

1 mole of Pb(NO₃) reacts with 1 mole of H₂SO₄

0.001 mole of Pb(NO₃) will react with 0.001×1/1 mole of H₂SO₄

Therefore number of H₂SO₄ required for the reaction and for the H₂SO₄ to be in excess is 0.001 mole of H₂SO₄

So, the concentration of commercial H₂SO₄ is usually 18.0M, using this as the assumed value.

Volume of H₂SO₄ = (number of H₂SO₄ required for it to be in excess)/(concentration of H₂SO₄)

Volume of H₂SO₄ = 0.001/18 = 0.0000556 L = 0.0556 mL.

QED!!!

5 0
2 years ago
Liquid X is known to have a higher surface tension and higher viscosity than Liquid Y Use these facts to predict the result of b
creativ13 [48]

Answer:

O FX will be greater than FY

Explanation:

<em>Surface tension</em> can be defined as the force required to stretch one film of a given fase (usually with liquids).

This required force is proportional to the liquid's surface tension. This means that the higher the surface tension, the higher the required force to stretch it is.

5 0
2 years ago
Which of these elements are you least likely to find in nature as a pure element (that is, not combined with any other elements
Delvig [45]
The answer is sodium (Na)

<em>Let me know if u have anymore questions ☺</em>
7 0
2 years ago
Read 2 more answers
A farmer had an accident and spilled a chemical into his pond. Several days later, he notices many dead frogs around the pond. T
andrezito [222]
B. the frogs are a limiting factor for the gnats
the frogs limit the reproduction of the gnats, and therefore with less frogs the gnat population can increase
3 0
2 years ago
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