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irina [24]
2 years ago
8

If a 1.00 mL sample of the reaction mixture for the equilibrium constant experiment required 32.40 mL of 0.258 M NaOH to titrate

it, what is the acetic acid concentration in the mixture
Chemistry
1 answer:
andrey2020 [161]2 years ago
6 0

Answer:

The concentration of acetic acid is 8.36 M

Explanation:

Step 1: Data given

Volume of acetic acid = 1.00 mL = 0.001 L

Volume of NaOH = 32.40 mL = 0.03240 L

Molarity of NaOH = 0.258 M

Step 2: The balanced equation

CH3COOH + NaOH → CH3COONa + H2O

Step 3: Calculate the concentration of the acetic acid

b*Ca*Va = a*Cb*Vb

⇒with b = the coefficient of NaOH = 1

⇒with Ca = the concentration of CH3COOH = TO BE DETERMINED

⇒with Va = the volume of CH3COOH = 1.00 mL = 0.001L

⇒with a = the coefficient of CH3COOH = 1

⇒with Cb = the concentration of NaOH = 0.258 M

⇒with Vb = the volume of NaOH = 32.40 mL = 0.03240 L

Ca * 0.001 L = 0.258 * 0.03240

Ca = 8.36 M

The concentration of acetic acid is 8.36 M

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The equation for the enthalpy change of the above reaction is:

\Delta H^o_{rxn}=[(3\times \Delta H^o_f_{(CO_2(g))})+(4\times \Delta H^o_f_{(H_2O(g))})]-[(1\times \Delta H^o_f_{(C_2H_2(g))})+(5\times \Delta H^o_f_{(O_2(g))})]

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Putting values in above equation, we get:

\Delta H^o_{rxn}=[(4\times (-393.5))+(2\times (-241.8))]-[(2\times (227.4)+(5\times (0))]\\\\\Delta H^o_{rxn}=-2512.4kJ

Therefore, the value of \Delta H^o for the reaction is, -2512.4 kJ

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