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Andrews [41]
2 years ago
9

Determine the specific heat (in J/g C) for a 2.508 kilogram substance which increases its temperature from 4.051 C to 42.061 C w

hen it absorbs 3.42 kilojoules of energy.
Chemistry
1 answer:
just olya [345]2 years ago
7 0

Answer: 0.036 J/g°C

Explanation:

The quantity of heat energy (Q) required to raise the temperature of a substance depends on its Mass (M), specific heat capacity (C) and change in temperature (Φ)

Thus, Q = MCΦ

Given that,

Q = 3.42 Kilojoules

[Convert 3.42 kilojoules to joules

If 1 kilojoule = 1000 joules

3.42 kilojoules = 3.42 x 1000 = 3420J]

Mass = 2.508Kg

[Convert 2.508 kg to grams

If 1 kg = 1000 grams

2.508kg = 2.508 x 1000 = 2508g]

C = ? (let unknown value be Z)

Φ = (Final temperature - Initial temperature)

= 42.061°C - 4.051°C

= 38.01°C

Apply the formula, Q = MCΦ

3420J = 2508g x Z x 38.01°C

3420J = 95329.08g•°C x Z

Z = (3420J / 95329.08g•°C)

Z = 0.03588 J/g°C

Round the value of Z to the nearest thousandth, hence Z = 0.036 J/g°C

Thus, the specific heat of the substance is 0.036 J/g°C

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IRINA_888 [86]

To calculate the packing factor, first calculate the area and volume of unit cell.

Area is calculated as:

A=6R^{2}\sqrt{3}

Here, R is radius and is related to a as follows:

R=\frac{a}{2}

Putting the value in expression for area,

A=6(\frac{a}{2})^{2}\sqrt{3}=1.5a^{2}\sqrt{3}

The value of a is 0.4961 nm

Since, 1 nm=10^{-7}cm

Thus, 0.4961 nm=4.961\times 10^{-8} cm

Putting the value,

Area=1.5(4.961\times 10^{-8}cm)^{2}\sqrt{3}=6.39\times 10^{-15}cm^{2}

Now, volume can be calculated as follows:

V=Area\times c

The value of c is 1.360 nm or 1.360\times 10^{-7} cm

Putting the value,

V=(6.39\times 10^{-15}cm^{2})\times (1.360\times 10^{-7} cm)=8.7\times 10^{-22}cm^{3}

now, number of atom in unit cell can be calculated by using the following formula:

n=\frac{\rho N_{A}V_{c}}{A}

Here, A is atomic mass of Cr_{2}O_{3} is 151.99 g/mol.

Putting all the values,

n=\frac{(5.22 g/cm^{3})(6.023\times 10^{23} mol^{-1})(8.7\times 10^{-22}cm^{3})}{(151.99 g/mol)}\approx 18

Thus, there will be 18 Cr_{2}O_{3} units in 1 unit cell.

Since, there are 2 Cr atoms and 3 oxygen atoms thus, units of chromium and oxygen will be 2×18=36 and 3×18=54 respectively.

The atomic radii of Cr^{3+} and O^{2-} is 62 pm and 140 pm respectively.

Converting them into cm:

1 pm=10^{-10}cm

Thus,

r_{Cr^{3+}}=6.2\times 10^{-9}cm

and,

r_{O^{2-}}=1.4\times 10^{-8}cm

Volume of sphere will be sum of volume of total number of cations and anions thus,

V_{S}=V_{Cr^{3+}}+V_{O^{2-}}

Since, volume of sphere is V=\frac{4}{3}\pi r^{3},

V_{S}=36\left ( \frac{4}{3}\pi (r_{Cr^{3+})^{3}} \right )+54\left ( \frac{4}{3}\pi (r_{O^{2-})^{3}} \right )

Putting the values,

V_{S}=36\left ( \frac{4}{3}(3.14) (6.2\times 10^{-9} cm)^{3}} \right )+54\left ( \frac{4}{3}(3.14) (1.4\times 10^{-8} cm)^{3}} \right )=6.6\times 10^{-22}\times 10^{-8}cm^{3}

The atomic packing factor is ratio of volume of sphere and volume of crystal, thus,

packing factor=\frac{V_{S}}{V_{C}}=\frac{6.6\times 10^{-22}cm^{3}}{8.7\times 10^{-22}cm^{3}}=0.758

Thus, atomic packing factor is 0.758.

6 0
2 years ago
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Calculate the cell potential E at 25°C for the reaction 2 Al(s) + 3 Fe2+(aq) → 2 Al3+(aq) + 3 Fe(s) given that [Fe 2+] = 0.020 M
Elodia [21]

Answer:

1.18 V

Explanation:

The given cell is:

Al(s)/Al^{3+}(0.10M)||Fe^{2+}(0.020M)/Fe(s)

Half reactions for the given cell follows:

Oxidation half reaction: Al(s)\rightarrow Al^{3+}(0.10M)+2e^-;E^o_{Al^{3+}/Al}=-1.66V

Reduction half reaction: Fe^{2+}(0.020M)+2e^-\rightarrow Fe(s);E^o_{Fe^{2+}/Fe}=-0.45V

Multiply Oxidation half reaction by 2 and Reduction half reaction by 3

Net reaction: 2Al(s)+3Fe^{2+}(0.020M)\rightarrow 2Al^{3+}(0.10M)+3Fe(s)

Oxidation reaction occurs at anode and reduction reaction occurs at cathode.

To calculate the E^o_{cell} of the reaction, we use the equation:

E^o_{cell}=E^o_{cathode}-E^o_{anode}

Putting values in above equation, we get:

E^o_{cell}=-0.45-(-1.66)=1.21V

To calculate the EMF of the cell, we use the Nernst equation, which is:

E_{cell}=E^o_{cell}-\frac{0.059}{n}\log \frac{[Al^{3+}]^2}{[Fe^{2+}]^3}

where,

E_{cell} = electrode potential of the cell = ?V

E^o_{cell} = standard electrode potential of the cell = +1.21 V

n = number of electrons exchanged = 6

Putting values in above equation, we get:

E_{cell}=1.21-\frac{0.059}{6}\times \log(\frac{0.10^2}{0.020^3})\\\\E_{cell}=1.18V

5 0
2 years ago
Draw the condensed structural formula in the equation for the saponification of trimyristin with koh
Ludmilka [50]

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Trimyristin+3 KOH\rightarrow Glycerol+Soap

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The condensed structural formula for the equation is given in the image attached.

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2 years ago
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Answer:

b

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Vaselesa [24]

Answer:

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mass of each gas is 10.0 g

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number of moles is directly proportional to volume at constant temp and pressure

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Since, H2 has minimum molar mass then for the same mass of the gases Hydrogen will have maximum volume.

6 0
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