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Igoryamba
2 years ago
13

A vessel of volume 22.4 dm3 contains 2.0 mol h2 and 1.0 mol n2 at 273.15 k initially. all the h2 reacted with sufficient n2 to f

orm nh3. calculate the partial pressures and the total pressure of the final mixture.
Chemistry
1 answer:
yanalaym [24]2 years ago
7 0
Volume = 22.4 dm3
n = 2 mol of H2
n = 1 mol of N2
Temperature = 273.15
All H2 reacts
reaction
N2 + 3H2 = 2NH3
1:3 ratio
Calculation:
N2 initial - N2 reacted = Final N2
1 - 2*(1/3) = 0.3333 mol of N2 left
H2 = 0 left
NH3 formed = 2/3*1 = 2/3 = 0.666
Total mol:
0.3333 + 0.666 = 1 mol
Apply the equation : 
PV = nRT
P = nRT/V = 1*0.0082*(273.15)/(22.4) = 0.0999924 atm
PH2 = 0
PN2 = 1/3*0.0999924 = 0.0333308 atm
PNH3 = 2/3*0.0999924 = 0.0666616 atm
Answer is 0.0666616 atm
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Answer:

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Explanation:

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We can start with the "CH_3" part. We can put 3 hydrogen bond arroun the carbon. We can use this same logic with  "CH_2". Finally for oxygens, we can put it one bond with CH_2 and a bond between oxygens with a final bond with hydrogen to obtain <u>hydroperoxyethane</u>.

See figure 1 for further explanations.

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Formal charge on Oxygen (Highlighted Red);

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2 years ago
Which of the following reactions will not occur as written? Which of the following reactions will not occur as written? Sn (s) +
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The unit cell for cr2o3 has hexagonal symmetry with lattice parameters a = 0.4961 nm and c = 1.360 nm. If the density of this ma
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To calculate the packing factor, first calculate the area and volume of unit cell.

Area is calculated as:

A=6R^{2}\sqrt{3}

Here, R is radius and is related to a as follows:

R=\frac{a}{2}

Putting the value in expression for area,

A=6(\frac{a}{2})^{2}\sqrt{3}=1.5a^{2}\sqrt{3}

The value of a is 0.4961 nm

Since, 1 nm=10^{-7}cm

Thus, 0.4961 nm=4.961\times 10^{-8} cm

Putting the value,

Area=1.5(4.961\times 10^{-8}cm)^{2}\sqrt{3}=6.39\times 10^{-15}cm^{2}

Now, volume can be calculated as follows:

V=Area\times c

The value of c is 1.360 nm or 1.360\times 10^{-7} cm

Putting the value,

V=(6.39\times 10^{-15}cm^{2})\times (1.360\times 10^{-7} cm)=8.7\times 10^{-22}cm^{3}

now, number of atom in unit cell can be calculated by using the following formula:

n=\frac{\rho N_{A}V_{c}}{A}

Here, A is atomic mass of Cr_{2}O_{3} is 151.99 g/mol.

Putting all the values,

n=\frac{(5.22 g/cm^{3})(6.023\times 10^{23} mol^{-1})(8.7\times 10^{-22}cm^{3})}{(151.99 g/mol)}\approx 18

Thus, there will be 18 Cr_{2}O_{3} units in 1 unit cell.

Since, there are 2 Cr atoms and 3 oxygen atoms thus, units of chromium and oxygen will be 2×18=36 and 3×18=54 respectively.

The atomic radii of Cr^{3+} and O^{2-} is 62 pm and 140 pm respectively.

Converting them into cm:

1 pm=10^{-10}cm

Thus,

r_{Cr^{3+}}=6.2\times 10^{-9}cm

and,

r_{O^{2-}}=1.4\times 10^{-8}cm

Volume of sphere will be sum of volume of total number of cations and anions thus,

V_{S}=V_{Cr^{3+}}+V_{O^{2-}}

Since, volume of sphere is V=\frac{4}{3}\pi r^{3},

V_{S}=36\left ( \frac{4}{3}\pi (r_{Cr^{3+})^{3}} \right )+54\left ( \frac{4}{3}\pi (r_{O^{2-})^{3}} \right )

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The atomic packing factor is ratio of volume of sphere and volume of crystal, thus,

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