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Leni [432]
2 years ago
13

[Cu(NH3)4]^+2 solutions exhibit a deep blue-violet color. How can you use spectrophotometry to confirm that this reaction has oc

curred and that the product formed is in fact tetraamminecopper (ll) sulfate? would you expect the wavelength of maximum absorbance (lambda max) for Cu(NH3)4^+2 to be greater than or less than lambda max for Cu(H20)6^+2? explain
Chemistry
2 answers:
Tems11 [23]2 years ago
8 0

Answer : Use of spectrophotometry to study the absorbance changes during the course of reaction which can confirm that tetraamine copper(II) sulfate is formed or not is by comparing the absorbance of the solution with the literature absorbance value of tetraamine copper(II) sulfate. After comparison if both are found to be almost similar then it can be confirmed that tetraamine copper(II) sulfate is the product formed.

The wavelength of[Cu (NH_{3})_{4}]^{2+} is less than λ max for Cu_{2+} because it absorbs in the range of shorter wavelength of yellow light. Therefore, the solution appears to be deep blue-violet color.

11Alexandr11 [23.1K]2 years ago
6 0
One would record the UV-Visible absorption spectrum of teh solution and compare it with the literature spectrum of [Cu(NH3)4]2+. 
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How many sodium ions are in the initial 50.00-mL solution of Na2CO3
tresset_1 [31]
From other sources, the given mass of the solute that is being dissolved here is 7.15 g Na2CO3 - 10H2O. We use this amount to convert it to moles of Na2CO3 by converting it to moles using the molar mass then relating the ratio of the unhydrated salt with the number of water molecules. And by the dissociation of the unhydrated salt in the solution, we can calculate the moles of Na+ ions that are present in the solution.

Na2CO3 = 2Na+ + CO3^2-

7.15 g Na2CO3 - 10H2O (1 mol / 402.9319 g) (1 mol Na2CO3 / 1 mol Na2CO3 - 10H2O) ( 1 mol Na2CO3 / 1 mol Na2CO3-10H2O ) ( 2 mol Na+ / 1 mol Na2CO3) = 0.04 mol Na+ ions present
8 0
2 years ago
A sample of the chiral molecule limonene is 79% enantiopure. what percentage of each enantiomer is present? what is the percent
Degger [83]

Answer :  The % of (+) limonene isomer = 79%


                The % of (-) limonene isomer = 0%


                The % of enantiomeric excess = 58%


Explanation :   Enantiomeric excess (ee) is the measurement of purity used for chiral substances.


Given,


% of pure limonene enantiomer = The % of (+) limonene isomer = 79%


Therefore, The % of (-) limonene isomer = 0%


Formula used :  

\%(+)\text{ isomer}=\frac{ee}{2}+50\%


Where,         ee → enantiomeric excess


Now, put all the values in above formula, we get the value of enantiomeric excess (ee).


     {ee}=\frac{\%(+)-50\%}{2}


            =\frac{79\%-50\%}{2}


              = 58%



7 0
2 years ago
Read 2 more answers
Be sure to answer all parts. There are three different dichloroethylenes (molecular formula C2H2Cl2), which we can designate X,
sertanlavr [38]

Answer:

Explanation:Since the compound X has no net-dipole moment so we can ascertain that this compound is not associated with any polarity.

hence the compound must be overall non-polar. The net dipole moment of compound is zero means that the vector sum of individual dipoles are zero and hence the two individual bond dipoles associated with C-Cl bond  must be oriented in  the opposite directions with respect to each other.]

So we can propose that compound X must be trans alkene as only in trans compounds the individual bond dipoles cancel each other.

If one isomer of the alkene is trans then the other two isomers may be cis .

Since the two alkenes give the same molecular formula on hydrogenation which means they are quite similar and only slightly different.

The two possibility of cis structures are possible:

in the first way it is possible the one carbon has two chlorine substituents and the carbon has two hydrogens.

Or the other way could be that two  chlorine atoms are present on the two carbon atoms in cis manner that is on the same side and two hydrogens are also present on the different carbon atoms in the same manner.

Kindly refer the attachments for the structure of compounds:

7 0
2 years ago
A 1.0-gram sample of solid iodine is placed in a tube and the tube is sealed after all of the air is removed. The tube and the s
yKpoI14uk [10]

Answer:

27.0

Explanation:

Because Mass can neither be created nor be destroyed hence total mass of sample of iodine and tube remain equal as it is sealed.

7 0
2 years ago
What is the mass of 0.921 moles of sulfur dioxide gas (SO2)?
Serhud [2]

Answer:

mass = 58.944 g

Explanation:

Given data:

Number of moles of SO₂ = 0.921 mol

Mass of SO₂ = ?

Solution:

Formula:

Number of moles = mass/ molar mass

First of all we will calculate the molar mass.

SO₂ = 32 + 16×2 = 64 g/mol

Now we will put the values in formula.

Number of moles = mass/ molar mass

0.921 mol = mass /64 g/mol

mass = 0.921 mol × 64 g/mol

mass = 58.944 g

8 0
2 years ago
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