Answer:
a. withdraws electrons inductively
b. donates electrons by hyperconjugation
c. donates electrons by resonance
d. withdraws electrons inductively
Explanation:
a. The bromide ion is a highly electronegative ion (in the halide series). Electronegative substituents on acids increase the acidity by inductive electron withdrawal method. The higher the electronegativity of a substance, the greater the acidity. The halogens have this order of electronegativity:
F > Cl > Br>I
b. The carboxyl groups have a stabilization of the sigma and pi bonds. This is achieved through a special delocalization of electrons. Because of the delocalization, hyperconjugation is the result effect.
c. The NHCH₃ group has a highly electonegative nitrogen atom that pulls the electron cloud towards itself. In this case, it withdraws electrons inductively. As a result, it donates electrons by resonance.
d. The OCH₃ group has a highly electonegative oxygen atom. This oxygen atom withdraws electron cloud towards itself. As a result, it withdraws electrons inductively.
There are several process in the nature, which keeps water cycling between them. By Precipitation, Earth's sphere gets water which we use in several ways, and by evaporation & sublimation, it goes back to upper spheres of the Earth's atmosphere and cycle happens again & again.
Hope this helps!
Number of moles = 5 x 10^24 / 6.02 x 10^23 = 8.305 moles. Volume= moles x 22.4 = 186.032 liters. Hope this helps!