Answer:
3-methylthiophene > thiophene > benzene > 2-methylfuran
Explanation:
Primarily, five membered heterocyclic aromatic rings undergo nitration at carbon-2. This is because, nitration at carbon-2 leads to the formation of three resonance structures while attack at carbon-3 yields only two resonance structures, hence it is less stabilized.
The presence of a methyl group which donates electrons promotes the stabilization of the cation formed in the nitration of 3-methylthiophene.
2-methylfuran is the least reactive towards nitration because the 2-position has been blocked by a methyl group.
Answer:
See explanation and image attached
Explanation:
This reaction is known as mercuric ion catalyzed hydration of alkynes.
The first step in the reaction is attack of the mercuric ion on the carbon-carbon triple bond, a bridged intermediate is formed. This bridged intermediate is attacked by water molecule to give an organomercury enol. This undergoes keto-enol tautomerism, proton transfer to the keto group yields an oxonium ion, loss of the mercuric ion now gives equilibrium keto and enol forms of the compound. The keto form is favoured over the enol form.
Answer:
The answers to your questions are given below.
Explanation:
Data obtained from the question include:
Mass (M) = 420.0 g
Temperature change (ΔT) = 43.8 °C
Specific heat capacity (C) = 3.52 J/g °C
Heat needed (Q) =...?
The heat needed for the temperature change can be obtained by using the following formula:
Q = MCΔT
Where:
Q is the heat needed measured in joule (J).
M is the mass of substance measured in grams (g)
C is the specific heat capacity of the substance with unit J/g °C.
ΔT is the temperature change measured in degree celsius (°C).
Thus, we can calculate the heat needed to change the temperature as follow:
Q = MCΔT
Q = 420 x 3.52 x 43.8
Q = 64753.92 J
Therefore, the heat needed to cause the temperature change is 64753.92 J
Answer:

Explanation:
Hello,
In this case, we can compute the change in the solution enthalpy by using the following formula:

Whereas the mass of the solution is 350 g, the specific heat capacity is 4.184 J/g °C and the change in the temperature is 1.34 °C, therefore, we obtain:

It is important to notice that the mass is just 350 g that is the reacting amount and by means of the law of the conservation of mass, the total mass will remain constant, for that reason we compute the change in the enthalpy as shown above, which is positive due to the temperature raise.
Best regards.