the height of a column of mercury in barometer is 754.3mm. what us the atmospheric pressure in atm. in kPa.

Which of the compounds above are strong enough acids to react almost completely with a hydroxide ion (pka of h2o = 15.74) or wit

luda_lava [24]

The compounds can react with OH⁻ and HCO₃⁻ only C₅H₆N pyridinium

<h3><em>Further explanation </em></h3>

In an acid-base reaction, it can be determined whether or not a reaction occurs by knowing the value of pKa or Ka from acid and conjugate acid (acid from the reaction)

Acids and bases according to Bronsted-Lowry

Acid = donor (donor) proton (H + ion)

Base = proton (receiver) acceptor (H + ion)

If the acid gives (H +), then the remaining acid is a conjugate base because it accepts protons. Conversely, if a base receives (H +), then the base formed can release protons and is called the conjugate acid from the original base.

From this, it can be seen whether the acid in the product can give its proton to a base (or acid which has a lower Ka value) so that the reaction can go to the right to produce the product.

The step that needs to be done is to know the pKa value of the two acids (one on the left side and one on the right side of the arrow), then just determine the value of the equilibrium constant

Can be formulated:

K acid-base reaction = Ka acid on the left : K acid on the right.

or:

pK = acid pKa on the left - pKa acid on the right

K = equilibrium constant for acid-base reactions

pK = -log K;

$K~=~10^{-pK}$

K value> 1 indicates the reaction can take place, or the position of equilibrium to the right.

There is some data that we need to complete from the problem above, which is the pKa value of some compounds that will react, namely:

pyridinium pKa = 5.25

acetone pKa = 19.3

butan-2-one pKa = 19

Let's look at the K value of each possible reaction:

pka H₂O = 15.74, pka of H₂CO₃ = 6.37)

1. C₅H₆N pyridinium

* with OH⁻

C₅H₆N + OH- ---> C₅H₅N- + H₂O

pK = pKa pyridinium - pKa H₂O

pK = 5.25 - 15.74

pK = -10.49

$K~=~10^{4.9}$

K values> 1 indicate the reaction can take place

* with HCO3⁻

C₅H₆N + HCO₃⁻-- ---> C₅H₅N⁻ + H₂CO₃

pK = 5.25 - 6.37

pK = -1.12

$K`=~10^{1.12]$

Reaction can take place

2. Acetone C₃H₆O

* with OH-

C₃H₆O + OH⁻ ---> C₃H₅O- + H₂O

pK = 19.3 - 15.74

pK = 3.56

$K~=~10^{ -3.56}$

Reaction does not happen

* with HCO₃-

C₃H₆O + HCO₃⁻ ----> C₃H₅O⁻ + H₂CO₃

pK = 19.3 - 6.37

pK = 12.93

$K`=~10 ^{-12.93}$

Reaction does not happen

3. butan-2-one C₄H₇O

* with OH-

C₄H₇O + OH- ---> C₄H₆O- + H₂O

pK = 19 - 15.74

pK = 3.26

$K~=~10^{-3.26}$

Reaction does not happen

* with HCO₃⁻

C₄H₇O + HCO₃⁻ ---> C₄H₆O⁻ + H₂CO₃

pK = 19 - 6.37

pK = 12.63

$K~=~ 10^{-12.63}$

Reaction does not happen

So that can react with OH⁻ and HCO₃⁻ only C₅H₆N pyridinium

<h3><em>Learn more </em></h3>

the lowest ph

brainly.com/question/9875355

the concentrations at equilibrium.

brainly.com/question/8918040

the ph of a solution

brainly.com/question/9560687

Keywords : acid base reaction, the equilibrium constant

5 0

2 years ago

Read 2 more answers

A vessel contains Ar(g) at a high pressure. Which of the following statements best helps to explain why the measured pressure is

Luda [366]

Answer:

4. The combined volume of the Ar atoms is too large to be negligible compared with the total volume of the container.

Explanation:

Deviations from ideality are due to intermolecular forces and to the nonzero volume of the molecules themselves. At infinite volume, the volume of the molecules themselves is negligible compared with the infinite volume the gas occupies.

However, the volume occupied by the gas molecules must be taken into account. Each <u>molecule does occupy a finite, although small, intrinsic volume.</u>

The non-zero volume of the molecules implies that instead of moving in a given volume V they are limited to doing so in a smaller volume. Thus, the molecules will be closer to each other and repulsive forces will dominate, resulting in greater pressure than the one calculated with the ideal gas law, that means, without considering the volume occupied by the molecules.

5 0

2 years ago

Ion arrangements of three general salts are represented below. h5sil917 h5sil917021 h5sil91703 which ion arrangement has the hig

vovangra [49]

This question is incomplete. Luckily, I found the same problem which is shown in the attached picture. To answer the question, we must know how the size and charge affect the lattice energy. The answer is: lattice energy increases with the increasing charge of the ions, and decreasing radius of the atoms. <em>Therefore, the ranking would be: A < B < C</em>.

4 0

2 years ago

How much heat in kJ is produced by the oxidation of 18.6 g of Mn?

soldier1979 [14.2K]

32’ns()3 jsjsusiiaaiaoaoididudud

8 0

2 years ago

In a car piston shown above, the pressure of the compressed gas (red) is 5.00 atm. If the area of the piston is 0.0760 m^2. What

Shkiper50 [21]

Answer:

38503.5N

Explanation:

Data obtained from the question include:

P (pressure) = 5.00 atm

Now, we need to convert 5atm to a number in N/m2 in order to obtain the desired result of force in Newton (N). This is illustrated below:

1 atm = 101325N/m2

5 atm = 5 x 101325 = 506625N/m^2

A (area of piston) = 0.0760 m^2

Pressure is force per unit area. Mathematically it is written as

P = F/A

F = P x A

F = 506625 x 0.0760

F = 38503.5N

Therefore, the force exerted on the piston is 38503.5N

6 0

2 years ago