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lions [1.4K]
2 years ago
15

A rigid, 28-L steam cooker is arranged with a pressure relief valve set to release vapor and maintain the pressure once the pres

sure inside the cooker reaches 150 kPa. Initially, this cooker is filled with water at 175 kPa with a quality of 10 percent. Heat is now added until the quality inside the cooker is 40 percent. The water is stirred at the same time that it is being heated. Determine the minimum entropy change of the heat-supplying source if 100 kJ of work is done on the water as it is being heated. Use steam tables.
Chemistry
1 answer:
MaRussiya [10]2 years ago
3 0

Answer:

\Delta S_{source}>-1.204\frac{kJ}{K}

Explanation:

Hello!

In this case, given the initial conditions, we first use the 10-% quality to compute the initial entropy:

s_1=s_{f,175kPa}+q*s_{fg,175kPa}\\\\s_1=1.4850\frac{kJ}{kg*K} +0.1*5.6865\frac{kJ}{kg*K}=2.0537\frac{kJ}{kg*K}

Now the entropy at the final state given the new 40-% quality:

s_2=s_{f,150kPa}+q*s_{fg,150kPa}\\\\s_2=1.4337\frac{kJ}{kg*K} +0.4*5.7894\frac{kJ}{kg*K}=3.7495\frac{kJ}{kg*K}

Next step is to compute the mass of steam given the specific volume of steam at 175 kPa and the 10% quality:

m_1=\frac{0.028m^3}{(0.001057+0.1*1.002643)\frac{m^3}{kg} } =0.274kg\\\\m_2=\frac{0.028m^3}{(0.001053+0.4*1.158347)\frac{m^3}{kg} } =0.0603kg

Then, we can write the entropy balance:

\Delta S_{source}+\frac{Q}{T_1} -\frac{Q}{T_2} +s_2m_2-s_1m_1-s_{fg}(m_2-m_1)>0

Whereas sfg stands for the entropy of the leaving steam to hold the pressure at 150 kPa and must be greater than 0; thus we plug in:

Which is such minimum entropy change of the heat-supplying source.

Best regards!

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Answer:

In none of the reactions ΔH°rxn equal to ΔH°f of the product.

Explanation:

The standard enthalpy of formation (ΔH°f) is the enthalpy change when 1 mole of a product is formed from its constituent elements in the standard states.

1/2 O₂(g) + H₂O(g) ⟶ H₂O₂(g)

ΔH°rxn is NOT equal to ΔH°f of the product because H₂O(g) is not an element but a compound.

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ΔH°rxn is NOT equal to ΔH°f of the product because Na and F are not in their standard states (Na(s); F₂(g)).

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ΔH°rxn is NOT equal to ΔH°f of the product because K is not in its standard state (K(s)).

O₂(g) + 2 N₂(g) ⟶ 2 N₂O(g)

ΔH°rxn is NOT equal to ΔH°f of the product because 2 moles of N₂O are formed.

In none of the above ΔHrxn equal to ΔHf of the product.

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When 0.270 mol of a nondissociating solute is dissolved in 410.0 mL of CS2, the solution boils at 47.52 ∘C. What is the molal bo
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Answer:

Kb = 0.428 m/°C

Explanation:

To solve this problem we need to use the <em>boiling-point elevation formula</em>:

  • <em>Tsolution</em> - <em>Tpure solvent</em> = Kb * m

Where <em>Tsolution</em> and <em>Tpure solvent</em> are the boiling point of the CS₂ solution (47.52 °C) and of pure CS₂ (46.3 °C), respectively. Kb is the constant asked by the problem, and m is the molality of the solution.

So in order to use that equation and solve for Kb, first we <em>calculate the molality of the solution</em>.

molality = mol solute / kg solvent

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molality = 0.270 mol / 0.5166 kg = 0.5226 m

Now we <u>solve for Kb</u>:

<em>Tsolution</em> - <em>Tpure solvent</em> = Kb * m

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and     </span>AgNO3 →   Ag + (aq)  +  NO3- (aq)
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