Answer:
a. withdraws electrons inductively
b. donates electrons by hyperconjugation
c. donates electrons by resonance
d. withdraws electrons inductively
Explanation:
a. The bromide ion is a highly electronegative ion (in the halide series). Electronegative substituents on acids increase the acidity by inductive electron withdrawal method. The higher the electronegativity of a substance, the greater the acidity. The halogens have this order of electronegativity:
F > Cl > Br>I
b. The carboxyl groups have a stabilization of the sigma and pi bonds. This is achieved through a special delocalization of electrons. Because of the delocalization, hyperconjugation is the result effect.
c. The NHCH₃ group has a highly electonegative nitrogen atom that pulls the electron cloud towards itself. In this case, it withdraws electrons inductively. As a result, it donates electrons by resonance.
d. The OCH₃ group has a highly electonegative oxygen atom. This oxygen atom withdraws electron cloud towards itself. As a result, it withdraws electrons inductively.
Hydrocarbons may vary from state to state depending on the length of the carbon chain. For methane to butane, they are usually in gas form. Starting from pentane, they are in the liquid form. For very long carbon chains, that occur as solids. Now, it depends if the pentane is in a nonpolar liquid or polar liquid. Since pentane is nonpolar, it is miscible in the liquid solvent. The movements would most likely be free flowing. But if he solvent is polar, the molecules would repel with one another. In the end, it will form two liquid phases, on for the pentane and one for the polar solvent.
Solution:
According to the Avogadro's number:
6.022 *10^23 drops per 0.050 g/ drop = 3.011 *10^22 grams per mole of drops
3.011 *10^22 grams per 1 kg / 1000 grams = 3.011 *10^19 kilograms / mole of drops
thus the answers are:
3.0 *10^22 grams per mole of drops
3.0 *10^19 kilograms per mole of drops
And,
In the calculation of how many moles of raindrops in the Pacific Ocean is:
7.08X10^20kg per 3.0 *10^19 kilograms per mole of drops = 23.5 moles of drops
This is the required solution.
When you say the solution is hypertonic, it means that the solution has a higher osmotic pressure. The formula for this is:
P = iMRT,
for strong electrolytes, i = number of ions.
for nonelectrolytes, i = 1
1. The P for sucrose solution which is a nonelectrolyte (assuming room temp):
P = (1)(1m)(8.314 J/mol-K)(298 K)
P = 2477.572 Pa
The P for NaCl solution, which is a strong electrolyte:
P = (2)(1 m)(8.314)(298 K)
P = 4955.144 Pa
<em>So, that means that NaCl is more hypertonic than the sucrose solution.</em>
2. For the second question, the P for the combination of 1 m glucose (nonelectrolyte) and 1 m sucrose is:
P = (1)(1 m)(8.314)(298 K) + (1)(1)(8.314)(298 K) = 4955.144 Pa
<em>In this case, the osmotic pressures are now equal. It is not hypertonic, but isotonic.</em>
the equation is p1 x v1 divided by T1 = p1 x v2 = T2 but since the pressure is kept constant you do not even need it so the equation would now be v1 divided by t1 = v2 divided by t2
2135 cm3 divided by 127 degrees celcius = x divided by 206
answer: 3460 cm3
