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allsm [11]
2 years ago
12

A drinking water supply is suspected of being contaminated with lead. Samples of water aspirated directly into an air-acetylene

flame gave an absorbance of 0.68 at 283.3nm. Standard solutions containing 0.5 and 1.0 ppm were found to exhibit absorbances of 0.43 and 0.86 respectively. Assuming the Beer-Lambert law is obeyed calculate the concentration of lead within the water sample. A. 79. Oppm B. 0.79ppm C. 0.43ppm D. 0.96ppm E. 0.92ppm noeullib noilgoeps noods Whaooah
Chemistry
1 answer:
kifflom [539]2 years ago
3 0

Answer:

B. 0.79ppm

Explanation:

According to the Beer-Lambert law, there is a linear relationship between the absorbance (A) of an analyte and its concentration (c). We can represent it through the following expression.

A = k . c

where

k is a proportionality constant, and the slope of the equation.

Let's consider the ordered-pairs (0.5 ppm, 0.43) and (1.0 ppm, 0.86). The slope is:

k = ΔA / Δc = 0.86 - 0.43 / 1.0 ppm - 0.5 ppm = 0.86 ppm⁻¹

When A = 0.68

0.68 = 0.86 ppm⁻¹ c

c = 0.79 ppm

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Hydrogen peroxide, H2O2, is common in many households and is used as a bleaching agent. It usually comes in a dark, opaque bottl
sergij07 [2.7K]

Answer:

Hydrogen peroxide should be stored in

1) a cool environment

2) with amber bottles away from sunlight

3) with little drops of sodium phosphate

Explanation:

It has been confirmed that heat and light aids in the decomposition of hydrogen peroxide according to the equation; 2H2O2→2 H2O + O2.

This means that hydrogen peroxide must be stored in a cool place. This will reduce its rate of decomposition. Secondly, it should be stored in amber bottles away from light since light also aids in its decomposition.

Thirdly, drops of sodium phosphate may be added to prevent its catalytic decomposition during storage.

8 0
2 years ago
5. A Dumas bulb is filled with chlorine gas at the ambient pressure and is found to contain 7.1 g of chlorine when the temperatu
kati45 [8]

Answer:

a. The original temperature of the gas is 2743K.

b. 20atm.

Explanation:

a. As a result of the gas laws, you can know that the temperature is inversely proportional to moles of a gas when pressure and volume remains constant. The equation could be:

T₁n₁ = T₂n₂

<em>Where T is absolute temperature and n amount of gas at 1, initial state and 2, final states.</em>

<em />

<em>Replacing with values of the problem:</em>

T₁n₁ = T₂n₂

X*7.1g = (X+300)*6.4g

7.1X = 6.4X + 1920

0.7X = 1920

X = 2743K

<h3>The original temperature of the gas is 2743K</h3><h3 />

b. Using general gas law:

PV = nRT

<em>Where P is pressure (Our unknown)</em>

<em>V is volume = 2.24L</em>

<em>n are moles of gas (7.1g / 35.45g/mol = 0.20 moles)</em>

R is gas constant = 0.082atmL/molK

And T is absolute temperature (2743K)

P*2.24L = 0.20mol*0.082atmL/molK*2743K

<h3>P = 20atm</h3>

<em />

7 0
2 years ago
Partitioning of toxic chemicals in the environment refers to:
shtirl [24]

Answer:

The correct answer is b movement between different compartments(Such as between water and air).

Explanation:

The partitioning of a particular substance refers to the distribution of that substance into different compartments.

   By the same way partitioning of toxic compounds in the environment refers to movement of toxic substances between different compartments of environment which includes air,water etc.

3 0
2 years ago
(a) The mass density of a gaseous compound was found to be 1.23 kg m^−3 at 330 K and 20 kPa. What is the molar mass of the compo
Luden [163]

Answer:

The molar mass of the compound is:- 168.82 g/mol

The molar mass of the gas is:- 16.38 g/mol

Explanation:

(a)

Using ideal gas equation as:

PV=nRT

where,  

P is the pressure

V is the volume

n is the number of moles

T is the temperature  

R is Gas constant having value = 0.0821 L.atm/K.mol

Also,  

Moles = mass (m) / Molar mass (M)

Density (d)  = Mass (m) / Volume (V)

So, the ideal gas equation can be written as:

PM=dRt

Given that:-

Pressure = 20 kPa = 20000 Pa

The expression for the conversion of pressure in Pascal to pressure in atm is shown below:

P (Pa) = \frac {1}{101325} P (atm)

20000 Pa = \frac {20000}{101325} atm

Pressure = 0.1974 atm

Temperature = 330 K

d = 1.23 kg/m³ = 1.23 g/L

Molar mass = ?

Applying the equation as:

0.1974 atm × M = 1.23 g/L × 0.0821 L.atm/K.mol × 330 K

⇒M = 168.82 g/mol

<u>The molar mass of the compound is:- 168.82 g/mol</u>

(b)

Given that:

Pressure = 152 Torr

Temperature = 298 K

Volume = 250 cm³ = 0.25 L

Using ideal gas equation as:

PV=nRT

R = 62.3637\text{torr}mol^{-1}K^{-1}

Applying the equation as:

152 Torr × 0.25 L = n × 62.3637 L.torr/K.mol × 298 K

⇒n = 0.002045 moles

Given that :  

Mass of the gas = 33.5 mg = 0.0335 g

Molar mass = ?

The formula for the calculation of moles is shown below:

moles = \frac{Mass\ taken}{Molar\ mass}

Thus,

0.002045\ moles&#10;= \frac{0.0335\ g}{Molar\ mass}

<u>The molar mass of the gas is:- 16.38 g/mol</u>

5 0
2 years ago
Question 2 The metal molybdenum becomes superconducting at temperatures below 0.90K. Calculate the temperature at which molybden
LenKa [72]

Answer:

Temperature at which molybdenum becomes superconducting is-272.25°C

Explanation:

Conductor are those hard substances which allows path of electric current through them. And super conductors are those hard substances which have resistance against the flow of electric current through them.

As given, molybdenum becomes superconducting at temperatures below 0.90 K.

Temperature in Kelvins can be converted in °C by relation:

T(°C)=273.15-T(K)

Molybdenum becomes superconducting in degrees Celsius.

T(°C)=273.15-0.90= -272.25 °C

Temperature at which molybdenum becomes superconducting is -272.25 °C

5 0
2 years ago
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