In this question we need to find the new volume of the gas. Since we have been given the pressure and temperature change, we can used to combined gas law equation.

the parameters for 1st instance are given on the left side and parameters for the second instance are given on the right side of the equation
(319 mmHg x 0.558 L)/ 115 K = (215 mmHg x V)/387 K
V = 2.79 L
The first step in the reaction is the double bond of the Alkene going after the H of HBr. This protonates the Alkene via Markovnikov's rule, and forms a carbocation. The stability of this carbocation dictates the rate of the reaction.
<span>So to solve your problem, protonate all your Alkenes following Markovnikov's rule, and then compare the relative stability of your resulting carbocations. Tertiary is more stable than secondary, so an Alkene that produces a tertiary carbocation reacts faster than an Alkene that produces a secondary carbocation.
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Reduction. B is the correct answer