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dybincka [34]
2 years ago
3

5.0g sample of dry ice turned into 2400cm3 of carbon dioxide gas at RTP.What is the percentage purity of the dry ice?​

Chemistry
1 answer:
MA_775_DIABLO [31]2 years ago
6 0

Answer:

\%purity=86.4\%

Explanation:

Hello,

In this case, since the dry ice is the solid phase of carbon dioxide gas, via the yielded volume we can compute the grams that were sublimated via the ideal gas equation at RTP (1 atm and 25 °C) considering the volume in liters (2.1 L):

PV=nRT\\\\n=\frac{PV}{RT}\\ \\\frac{m}{M} =\frac{PV}{RT}\\\\m=\frac{MPV}{RT}\\\\m=\frac{44g/mol*1atm*2.4L}{0.082\frac{atm*L}{mol*K}*298.15K}\\ \\m=4.32g

Those previously computed mass are the pure grams, therefore, the percentage purity is:

\% purity=\frac{m_{pure}}{m_{total}}*100\%\\ \\\%purity=\frac{4.32g}{5.0g}*100\%\\ \\\%purity=86.4\%

Best regards.

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A 60.0 mL solution of 0.112 M sulfurous acid (H2SO3) is titrated with 0.112 M NaOH. The pKa values of sulfurous acid are 1.857 (
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Answer:

a)4.51

b) 9.96

Explanation:

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NaOH = 0.112M

H2S03 = 0.112 M

V = 60 ml

H2S03 pKa1= 1.857

pKa2 = 7.172

a) to calculate pH at first equivalence point, we calculate the pH between pKa1 and pKa2 as it is in between.

Therefore, the half points will also be the middle point.

Solving, we have:

pH = (½)* pKa1 + pKa2

pH = (½) * (1.857 + 7.172)

= 4.51

Thus, pH at first equivalence point is 4.51

b) pH at second equivalence point:

We already know there is a presence of SO3-2, and it ionizes to form

SO3-2 + H2O <>HSO3- + OH-

Kb = \frac{[ HSO3-][0H-]}{SO3-2}

Kb = \frac{10^-^1^4}{10^-^7^.^1^7^2} = 1.49*10^-^7

[HSO3-] = x = [OH-]

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V of NaOh = (2 * mmol)/M

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= 120ml

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60ml + 120ml = 180ml

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= 0.056 M

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pOH = -log(OH) = -log(9.11*10^-^5)

=4.04

pH = 14- pOH

= 14 - 4.04

= 9.96

The pH at second equivalence point is 9.96

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