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Agata [3.3K]
2 years ago
3

Calculate the value of % t for an absorbance value a = 1.5. using this result, explain why absorbance measurements >1 may not

be accurate.
Chemistry
1 answer:
eimsori [14]2 years ago
5 0
<span>logT=1.5 > logT=¬1.5 > T= 10^(¬1.5)=0.316 > %T= (T)(100)=31.6 If we use this answer as a basis, we can see that the absorbance measurements >1 have the possibility of not being accurate. This is because the percent transmittance will be close to 100.</span>
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A 0.72-mol sample of PCl5 is put into a 1.00-L vessel and heated. At equilibrium, the vessel contains 0.40 mol of PCl3(g) and 0.
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Answer:

Equilibrium constant for PCl_5 is 0.5

Equilibrium constant for decomposition of NO_2 is 1.79 \times 10^{-14}

Explanation:

PCl_5 dissociates as follows:

                    PCl_5 \rightleftharpoons PCl_3+Cl_2

initial          0.72 mol     0         0

at eq.     0.72 - 0.40   0.40      0.40

Expression for the equilibrium constant is as follows:

k=\frac{[PCl_3][Cl_2]}{[PCl_5]}

Substitute the values in the above formula to calculate equilibrium constant as follows:

k=\frac{[0.40/1][0.40/1]}{0.32/1} \\=\frac{0.40 \times 0.40}{0.32} \\=0.5

Therefore, equilibrium constant for PCl_5 is 0.5

Now calculate the equilibrium constant for decomposition of  NO_2

It is given that 3.3 \times 10^{-3} \% is decomposed.

NO_2 decomposes as follows:

                                  2NO_2 \rightleftharpoons 2NO + O_2

initial                            1.0 M       0           0

at eq. concentration of  NO_2   is:

[NO_2]_{eq}=1-(0.000066) = 0.999934\ M

[NO]_{eq}=6.6 \times 10^{-5}\ M

[O_2]_{eq}=3.3\times 10^{-5} = 3.3\times 10^{-5}\ M      

Expression for equilibrium constant is as follows:

K=\frac{[NO]^2[O_2]}{[NO_2]^2}

Substitute the values in the above expression

K=\frac{[6.6\times 10^{-5}]^2[3.3 \times 10^{-5}]}{[0.999934]^2} \\=1.79\times 10^{-14}

Equilibrium constant for decomposition of NO_2 is 1.79 \times 10^{-14}

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2 years ago
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Answer:

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The color changed

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If 0.25 mol of HClO2 is added to enough water to prepare a 0.25 M HClO2 aqueous solution, what is the concentration of H3O+(aq)
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Answer:

The concentration of H3O+= 0.15M

Explanation:

From The equation of reaction

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