answer.
Ask question
Login Signup
Ask question
All categories
  • English
  • Mathematics
  • Social Studies
  • Business
  • History
  • Health
  • Geography
  • Biology
  • Physics
  • Chemistry
  • Computers and Technology
  • Arts
  • World Languages
  • Spanish
  • French
  • German
  • Advanced Placement (AP)
  • SAT
  • Medicine
  • Law
  • Engineering
AnnyKZ [126]
2 years ago
9

A 0.1873 g sample of a pure, solid acid, H2X (a diprotic acid) was dissolved in water and titrated with 0.1052 M NaOH solution.

If the molar mass of H2X is 85.00 g/mol, calculate the volume of NaOH solution needed in the titration.
Chemistry
1 answer:
puteri [66]2 years ago
6 0

Answer:

We need 41.8 mL of NaOH

Explanation:

<u>Step 1:</u> Data given

Mass of H2X = 0.1873 grams

Molarity of NaOH solution = 0.1052 M

Molar mass of H2X = 85.00 g/mol

<u>Step 2</u>: The balanced equation

H2X (aq) +2 NaOH (aq) → Na2X (aq) + 2H2O(l)

<u>Step 3:</u> Calculate moles of H2X

Moles H2X = mass H2X / Molar mass H2X

Moles H2X = 0.1873 grams / 85.00 g/mol

Moles H2X = 0.0022 moles

<u>Step 4:</u> Calculate moles of NaOH

For 1 mol H2X we need 2 moles NaOH to produce 1 mole of Na2X and 2 moles of H2O

For 0.0022 moles of H2X we need 0.0044 moles of NaOH

<u />

<u>Step 5</u>: Calculate volume of NaOH

Volume of NaOH = moles of NaOH / molarity of NaOH

Volume of NaOH = 0.0044 moles / 0.1052 M

Volume NaOH =  0.0418 L = 41.8 mL

We need 41.8 mL of NaOH

You might be interested in
Describe how you would prepare exactly 100 mL of 0.109 M picolinate buffer, pH 5.61. Possible starting materials are pure picoli
Pepsi [2]

Answer:

1.342g of picolinic acid and 6.743mL of 1.0M NaOH diluting the mixture to 100.0mL

Explanation:

<em>The pKa of the picolinic acid is 5.4.</em>

Using Henderson-Hasselbalch formula for picolinic-picolinate buffer:

pH = pKa + log [Picolinate] / [Picolinic]

<em>Where [] could be taken as moles of each species</em>

<em />

5.61 = 5.4 + log [Picolinate] / [Picolinic]

0.21 = log [Picolinate] / [Picolinic]

1.62181 = [Picolinate] / [Picolinic] <em>(1)</em>

<em></em>

Now, both picolinate and picolinic acid will be:

0.100L * (0.109mol / L) =

0.0109 moles = [Picolinate] + [Picolinic] <em>(2)</em>

<em></em>

First, as we will start with picolinic acid, we need add:

0.0109 moles picolinic acid * (123.10g/mol) = 1.342g of picolinic acid

Now, replacing (2) in (1):

1.62181 = 0.0109 moles - [Picolinic] / [Picolinic]

1.62181 [Picolinic] = 0.0109 moles - [Picolinic]

2.62181 [Picolinic] = 0.0109 moles

[Picolinic] = 4.157x10⁻³ moles

And:

[Picolinate] = 0.0109 - 4.157x10⁻³ moles =

<h3>6.743x10⁻³ moles</h3><h3 />

To obtain these moles of picolinate ion we need to make the reaction of the picolinic acid with NaOH:

Picolinic acid + NaOH → Picolinate + Water

<em>That means to obtain 6.743x10⁻³ moles of picolinate ion we need to add 6.743x10⁻³ moles of NaOH</em>

<em />

6.743x10⁻³ moles of NaOH that is 1.0M are, in mL:

6.743x10⁻³ moles * (1L / 1mol) = 6.743x10⁻³L * 1000 =

<h3>6.743mL of the 1.0M NaOH must be added</h3><h3 />

Thus, we obtain the desire moles of picolinate and picolinic acid to obtain the buffer we want, the last step is:

<h3>Dilute the mixture to 100mL, the volume we need to prepare</h3>
3 0
2 years ago
Small quantities of h2 gas can be collected by adding hcl to zn. a sample of 195 ml of h2 gas was collected over water at 25 c a
Umnica [9.8K]
<span>15.4 milligrams The ideal gas law is PV = nRT where P = pressure of the gas V = volume of the gas n = number of moles of gas R = Ideal gas constant (8.3144598 L*kPa/(K*mol) ) T = absolute temperature. So let's determine how many moles of gas has been collected. Converting temperature from C to K 273.15 + 25 = 298.15 K Converting pressure from mmHg to kPa 753 mmHg * 0.133322387415 kPa/mmHg = 100.3917577 kPa Taking idea gas equation and solving for n PV = nRT PV/RT = n n = PV/RT Substituting known values n = PV/RT n = (100.3917577 kPa 0.195 L) / (8.3144598 L*kPa/(K*mol) 298.15 K) n = (19.57639275 L*kPa) / (2478.956189 L*kPa/(mol) ) n = 0.007897031 mol So we have a total of 0.007897031 moles of gas particles. Now let's get rid of that percentage that's water vapor. The percentage of water vapor is the vapor pressure of water divided by the total pressure. So 24/753 = 0.03187251 The portion of hydrogen is 1 minus the portion of water vapor. So 1 - 0.03187251 = 0.96812749 So the number of moles of hydrogen is 0.96812749 * 0.007897031 mol = 0.007645332 mol Now just multiple the number of moles by the molar mass of hydrogen gas. Start with the atomic weight. Atomic weight hydrogen = 1.00794 Molar mass H2 = 1.00794 * 2 = 2.01588 g/mol Mass H2 = 2.01588 g/mol * 0.007645332 mol = 0.015412073 g Rounding to 3 significant figures gives 0.0154 g = 15.4 mg</span>
7 0
2 years ago
Read 2 more answers
Which of the following statements, if true, would support the claim that the NO3− ion, represented above, has three resonance st
tester [92]

Answer:

One of the bonds in nitrate is shorter than the other two.

Explanation:

We would firstly need to draw the Lewis structure for nitrate anion. To do this, let's follow the standard steps:

  • calculate the total number of valence electrons: five from nitrogen, each oxygen contributes 6, so a total of 18 from oxygen atoms, as well as one from the negative charge, we have a total of 24 valence electrons;
  • assign the central atom, usually this is the atom which is single; in this case, we have nitrogen as our central atom;
  • assign single bonds to all the terminal atoms (oxygen atoms);
  • assign octets to the terminal atoms and calculate the number of electrons assigned;
  • the number of electrons assigned is 24, so no lone pairs are present on nitrogen;
  • calculate the formal charges: each oxygen has a formal charge of -1 (formal charge is calculated subtracting the sum of lone pair electrons and bonds from the number of valence electrons of that atom); nitrogen has a formal charge of +2;
  • nitrogen doesn't have an octet as well, so we'll both minimize its formal charge and make it obtain an octet if we make one double bond N=O.

Therefore, we may have 3 resonance structures, as this double bond might be formed with any of the 3 oxygen atoms.

By definition, double bonds are shorter than single ones, so one of the bonds is shorter than the other two.

7 0
2 years ago
Do carbon dioxide and water have the same molecular geometry? if not, what attributes cause these molecules with similar formula
tester [92]
No, they do not.
Carbon dioxide has a linear geometry because the lone pair and bond pair repulsion cancels out; however, water has a bent structure because only the oxygen atom possesses a lone pair which brings the bonding electron pairs closer.
6 0
1 year ago
Read 2 more answers
How many pints of a 30% sugar solution must be added to a 5 pint of a 5% sugar solution to obtain a 20% sugar solution?
ser-zykov [4K]

You must add 7.5 pt of the 30 % sugar to the 5 % sugar to get a 20 % solution.

You can use a modified dilution formula to calculate the volume of 30 % sugar.

<em>V</em>_1×<em>C</em>_1 + <em>V</em>_2×<em>C</em>_2 = <em>V</em>_3×<em>C</em>_3

Let the volume of 30 % sugar = <em>x</em> pt. Then the volume of the final 20 % sugar = (5 + <em>x</em> ) pt

(<em>x</em> pt×30 % sugar) + (5 pt×5 % sugar) = (<em>x</em> + 5) pt × 20 % sugar

30<em>x</em> + 25 = 20x + 100

10<em>x</em> = 75

<em>x</em> = 75/10 = 7.5

5 0
2 years ago
Other questions:
  • The solubility of acetanilide in hot water (5.5 g/100 ml at 100 C) is not very great, and it has some solubility in cold water (
    11·2 answers
  • If 455-ml of 6.0 M HNO3 is used to make 2.5 L dilution, what is the molarity of the dilution
    6·1 answer
  • Why does blowing carbon dioxide gas into aqueous barium hydroxide reduce?
    8·2 answers
  • A 0.100 M solution of K2SO4 would contain the same total ion concentration as which of the following solutions?0.0800 M Na2CO3 0
    10·1 answer
  • Excess aqueous copper(II) nitrate reacts with aqueous sodium sulfide to produce aqueous sodium nitrate and copper(II) sulfide as
    9·2 answers
  • HELP IN AN EXAM I WILL MAKE BRAINLIEST!!!!!!To study for a test, Gerald made this table summarizing the functions of flower stru
    15·1 answer
  • A student has two samples of NaCl, each one from a different source. Assume that the only potential contaminant in each sample i
    9·1 answer
  • How many Ca2+ ions are in a sample of CaSO4 having a total mass of 68.07 g?
    14·1 answer
  • Selena is learning about how engineers choose metals for spacecraft. She discovers that spacecraft engineers often mix other met
    14·1 answer
  • A drug suspension decomposes by zero-order kinetics with a rate constant of 2 mg mL-1month-1. If the initial concentration is 10
    9·1 answer
Add answer
Login
Not registered? Fast signup
Signup
Login Signup
Ask question!