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If PbI2(s) is dissolved in 1.0MNaI(aq) , is the maximum possible concentration of Pb2+(aq) in the solution greater than, less th

fredd [130]

Answer:

$\mathbf{s =\sqrt [3]{\dfrac{K_{sp}}{4}}}$

Less than the concentration of Pb2+(aq) in the solution in part ( a )

Explanation:

From the question:

A)

We assume that s to be the solubility of PbI₂.

The equation of the reaction is given as :

PbI₂(s) ⇌ Pb²⁺(aq) + 2I⁻(aq); Ksp = 7 × 10⁻⁹

[Pb²⁺] = s

Then [I⁻] = 2s

$K_{sp} =\text{[Pb$^{2+}$][I$^{-}$]}^{2} = s\times (2s)^{2} = 4s^{3}\\s^{3} = \dfrac{K_{sp}}{4}\\\\s =\mathbf{ \sqrt [3]{\dfrac{K_{sp}}{4}}}\\\\\text{The mathematical expressionthat can be used to determine the value of }\mathbf{s =\sqrt [3]{\dfrac{K_{sp}}{4}}}$

B)

The Concentration of Pb²⁺ in water is calculated as :

$\mathbf{s =\sqrt [3]{\dfrac{K_{sp}}{4}}}$

$\mathbf{s =\sqrt [3]{\dfrac{7*10^{-9}}{4}}}$

$\mathbf{s} =\sqrt[3]{1.75*10^{-9}}$

$\mathbf{s} =\mathbf{1.21*10^{-3} \ mol/L }$

The Concentration of Pb²⁺ in 1.0 mol·L⁻¹ NaI

$\mathbf{PbCl{_2}} \leftrightharpoons \ \ \ \ \ \ \ \mathbf{Pb^{2+}} \ \ \ \ \ + \ \ \ \ \ \ \ \mathbf{2 I^-}$

$\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \mathbf0} \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \mathbf{1.0}$

$\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \mathbf{+x} \ \ \ \ \ \ \ \ \ \ \ \ \mathbf{+2x}$

$\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \mathbf{+x} \ \ \ \ \ \ \ \ \ \ \ \ \mathbf{1.0+2x}$

The equilibrium constant:

$K_{sp} =[Pb^{2+}}][I^-]^2 \\ \\ K_{sp} = s*(1.0*2s)^2 =7*1.0^{-9} \\ \\ s = 7*10^{-9} \ \ m/L$

It is now clear that maximum possible concentration of Pb²⁺ in the solution is less than that in the solution in part (A). This happens due to the common ion effect. The added iodide ion forces the position of equilibrium to shift to the left, reducing the concentration of Pb²⁺.

3 0

2 years ago

The four rows of data below show the boiling points for a solution with no solute, sucrose (C12H22O11), sodium chloride (NaCl),

skad [1K]

The following are the answers to the different questions:
<span>The four rows of data below show the boiling points for a solution with no solute, sucrose (C12H22O11), sodium chloride (NaCl), and calcium chloride (CaCl2) (not in that order). Which boiling point corresponds to calcium chloride?

A. 101.53° C

Which of the following solutions will have the lowest freezing point?

D. 1.0 mol/kg magnesium fluoride (MgF2)

Which of the following compounds will be most effective in melting the ice on the roads when the air temperature is below zero?

A. sodium iodide (NaI)

Four different solutions have the following vapor pressures at 100°C. Which solution will have the greatest boiling point?

B. 96.3 kPa

Four different solutions have the following boiling points. Which boiling point corresponds to a solution with the lowest freezing point?

D. 108.1°C</span>

4 0

2 years ago

Read 2 more answers

n the diagram shown, when an object ‘X’ is brought near the ring shaped magnet, the magnet moves away from it. Four friends are

kati45 [8]

Answer:

Akash

Explanation:

it could be a magnet with the same poles facing eachoher

6 0

2 years ago

Question 21 (2 points)

m_a_m_a [10]

Answer:

i would say sensory memory, aka muscle memory.

Explanation:

8 0

2 years ago

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The pH of an aqueous solution is 4.32. What is the [OH–]?

Molodets [167]

2.10 x 10^-10 M. Ans

pH + pOH = 14
Where, pOH is the power of hydroxide ion concentration and pH is the power of concetration of the H+ ion.
Now, pOH = 14 - 4.32
= 9.68
Now, the concentration of [H+] is 10-7 M, then pH is 7 and for [OH-] = 10-7 M, the pOH is also 7.

Now, pOH = -log[OH-]
[OH-] = 10^- pOH
= 10^-9.68
= 2.10 x 10^-10 M

8 0

2 years ago