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2 years ago

The light produced by signs using neon gas results from electrons that are

1 answer:

3 0

Name:NeonSymbol:NeNumber:10Catagory:Noble GasesGroup:18Period:2Block:pStandard Atomic Weight:20.1797 g/molElectron Configuration:[He] 2s2 2p6Electrons Per Shell:2, 8Year Discovered:1898Discovered By:Sir William Ramsay
Morris W. Travers

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What is the composition, in atom percent, of an alloy that consists of a) 5.5 wt% Pb and b) 94.5 wt% of Sn? Assume that the atom

Anastaziya [24]

Answer : The percent composition of Pb and Sn in atom is, 3.21 % and 96.8 % respectively.

Explanation :

First we have to calculate the number of atoms in 5.5 wt% Pb and 94.5 wt% of Sn.

As, 207.2 g of lead contains $6.022\times 10^{23}$ atoms

So, 5.5 g of lead contains $\frac{5.5}{207.2}\times 6.022\times 10^{23}=1.59\times 10^{22}$ atoms

and,

As, 118.71 g of lead contains $6.022\times 10^{23}$ atoms

So, 94.5 g of lead contains $\frac{94.5}{118.71}\times 6.022\times 10^{23}=4.79\times 10^{23}$ atoms

Now we have to calculate the percent composition of Pb and Sn in atom.

$\% \text{Composition of Pb}=\frac{\text{Atoms of Pb}}{\text{Atoms of Pb}+\text{Atoms of Sn}}\times 100$

$\% \text{Composition of Pb}=\frac{1.59\times 10^{22}}{(1.59\times 10^{22})+(4.79\times 10^{23})}\times 100=3.21\%$

and,

$\% \text{Composition of Sn}=\frac{\text{Atoms of Sn}}{\text{Atoms of Pb}+\text{Atoms of Sn}}\times 100$

$\% \text{Composition of Sn}=\frac{4.79\times 10^{23}}{(1.59\times 10^{22})+(4.79\times 10^{23})}\times 100=96.8\%$

Thus, the percent composition of Pb and Sn in atom is, 3.21 % and 96.8 % respectively.

6 0

2 years ago

Calculate ΔH and ΔStot when two copper blocks, each of mass 10.0 kg, one at 100°C and the other at 0°C, are placed in contact in

ira [324]

Explanation:

The given data is as follows.

m = 10.0 kg = 10,000 g (as 1 kg = 1000 g)

Initial temp. of block 1, $T_{1} = 100^{o}C$ = (100 + 273) K = 373 K

Initial temp. of block 2, $T_{2} = 0^{o}C$ = (0 + 273) K = 273 K

So, heat released by block 1 = heat gained by block 2

$mC \Delta T = mC \times \Delta T$

$10000 g \times 0.385 \times (T_{f} - 100)^{o}C = 10000 g \times 0.385 \times (0 - T_{f})^{o}C$

$T_{f} - 100^{o}C = 0^{o}C - T_{f}$

$2T_{f} = 100^{o}C$

$T_{f} = 50^{o}C$

Convert temperature into kelvin as (50 + 273) K = 323 K.

Also, we know that the relation between enthalpy and temperature change is as follows.

$\Delta H = mC \Delta T$

= $10000 g \times 0.385 J/K g \times 323 K$

= 1243550 J

or, = 1243.5 kJ

Now, calculate entropy change for block 1 as follows.

$\Delta S_{1} = mC ln \frac{T_{f}}{T_{i}}$

= $10000 g \times 0.385 J/K g \times ln \frac{323}{373}$

= $10000 g \times 0.385 J/K g \times -0.143$

= -554.12 J/K

Now, entropy change for block 2 is as follows.

$\Delta S_{2} = mC ln \frac{T_{f}}{T_{i}}$

= $10000 g \times 0.385 J/K g \times ln \frac{323}{273}$

= $10000 g \times 0.385 J/K g \times 0.168$

= 647.49 J/K

Hence, total entropy will be sum of entropy change of both the blocks.

$\Delta S_{total} = \Delta S_{1} + \Delta S_{2}$

= -554.12 J/K + 647.49 J/K

= 93.37 J/K

Thus, we can conclude that for the given reaction $\Delta H$ is 1243.5 kJ and $\Delta S_{total}$ is 93.37 J/K.

6 0

2 years ago

A sample of sodium reacts completely with 0.355 kg of chlorine, forming 585 g of sodium chloride. What mass of sodium reacted?

Kay [80]

Answer:

The mass of sodium that reacted is 230 grams

Explanation:

The balance equation of the reaction is first written .

sodium = Na

Chlorine = Cl2

sodium chloride = NaCl

2Na + Cl2 → 2NaCl

from the balance equation we calculate the molar mass involve in the reaction

Molar mass of sodium from the equation = 23(2) = 46 g

molar mass of sodium chloride from the eqaution = 23 × 2 + 35.5 × 2 = 46 + 71 = 117 g

If 46g of sodium is in 117 g of sodium chloride

? gram will be in 585 g of sodium chloride

cross multiply

46 × 585/117 = 26910/117 = 230 g

The mass of sodium that reacted is 230 grams

5 0

2 years ago

Determine Z and V for steam at 250°C and 1800 kPa by the following: (a) The truncated virial equation [Eq. (3.38)] with the foll

makvit [3.9K]

Answer:

Explanation:

Given that:

the temperature $T_1$ = 250 °C= ( 250+ 273.15 ) K = 523.15 K

Pressure = 1800 kPa

The truncated viral equation is expressed as:

$\frac{PV}{RT} = 1 + \frac{B}{V} + \frac{C}{V^2}$

where; B = - $152.5 \ cm^3 /mol$ C = -5800 $cm^6/mol^2$

R = 8.314 × 10³ cm³ kPa. K⁻¹.mol⁻¹

Plugging all our values; we have

$\frac{1800*V}{8.314*10^3*523.15} = 1+ \frac{-152.5}{V} + \frac{-5800}{V^2}$

$4.138*10^{-4} \ V= 1+ \frac{-152.5}{V} + \frac{-5800}{V^2}$

Multiplying through with V² ; we have

$4.138*10^4 \ V ^3 = V^2 - 152.5 V - 5800 = 0$

$4.138*10^4 \ V ^3 - V^2 + 152.5 V + 5800 = 0$

V = 2250.06 cm³ mol⁻¹

Z = $\frac{PV}{RT}$

Z = $\frac{1800*2250.06}{8.314*10^3*523.15}$

Z = 0.931

b) The truncated virial equation [Eq. (3.36)], with a value of B from the generalized Pitzer correlation [Eqs. (3.58)–(3.62)].

The generalized Pitzer correlation is :

$T_c = 647.1 \ K \\ \\ P_c = 22055 \ kPa \\ \\ \omega = 0.345$

$T__{\gamma}} = \frac{T}{T_c}$

$T__{\gamma}} = \frac{523.15}{647.1}$

$T__{\gamma}} = 0.808$

$P__{\gamma}} = \frac{P}{P_c}$

$P__{\gamma}} = \frac{1800}{22055}$

$P__{\gamma}} = 0.0816$

$B_o = 0.083 - \frac{0.422}{T__{\gamma}}^{1.6}}$

$B_o = 0.083 - \frac{0.422}{0.808^{1.6}}$

$B_o = 0.51$

$B_1 = 0.139 - \frac{0.172}{T__{\gamma}}^{ \ 4.2}}$

$B_1 = -0.282$

The compressibility is calculated as:

$Z = 1+ (B_o + \omega B_1 ) \frac{P__{\gamma}}{T__{\gamma}}$

$Z = 1+ (-0.51 +(0.345* - 0.282) ) \frac{0.0816}{0.808}$

Z = 0.9386

$V= \frac{ZRT}{P}$

$V= \frac{0.9386*8.314*10^3*523.15}{1800}$

V = 2268.01 cm³ mol⁻¹

c) From the steam tables (App. E).

At $T_1 = 523.15 \ K \ and \ P = 1800 \ k Pa$

V = 0.1249 m³/ kg

M (molecular weight) = 18.015 gm/mol

V = 0.1249 × 10³ × 18.015

V = 2250.07 cm³/mol⁻¹

R = 729.77 J/kg.K

Z = $\frac{PV}{RT}$

Z = $\frac{1800*10^3 *0.1249}{729.77*523.15}$

Z = 0.588

3 0

2 years ago

Calculate the empirical formula for each of the following substances. (Express answer as a chemical formula) 1) 2.90 g of Ag and

exis [7]

Answer:

1) Ag3N

2)Na2S

3)NaHSO4

4) KNO3

Explanation:

We divide each mass by the element's relative atomic mass

1) 2.90/108-Ag, 0.125/14-N

0.027-Ag, 0.0089-N

Divide by the lowest ratio

0.027/0.0089-Ag, 0.0089/0.0089 N

3-Ag, 1-N

Empirical formula- Ag3N

2)2.22/23-Na, 1.55/32-S

0.097-Na, 0.048-S

Divide by the lowest ratio

0.097/0.048-Na, 0.048/0.048-S

2-Na, 1-S

Empirical formula- Na2S

3) 2.11/23-Na, 0.0900/1-H, 2.94/32-S,5.86/16-O

0.09-Na, 0.09-H, 0.09-S,0.366-O

Divide by the lowest ratio

0.09/0.09-Na, 0.09/0.09-H, 0.09/0.09-S, 0.366/0.09-O

1-Na, 1-H, 1-S, 4-O

Empirical formula- NaHSO4

4)1.84/39, 0.657/14-N, 2.25/16-O

0.047-K, 0.047-N, 0.14-O

Divide through by the lowest ratio

0.047/0.047-K, 0.047/0.047-N, 0.14/0.047-O

1-K, 1-N, O-3

Empirical formula- KNO3

4 0

2 years ago