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IRINA_888 [86]
2 years ago
5

Which of these ions will spontaneously react with ni(s) in solution? which of these ions will spontaneously react with in soluti

on? cr3+(aq) ba2+(aq) pb2+(aq) li+(aq)?

Chemistry
1 answer:
pickupchik [31]2 years ago
6 0
Nickel metal will react spontaneously with the aqueous lead solution [Pb2+(aq)]. 

Oxidation is a chemical reaction involving the loss of electrons. In the reactivity series of metals, chromium, barium, and lithium are more reactive or more easily oxidized than nickel. 

In the given problem, because nickel is in its elemental (solid metal) form, for it to react with the solution, it will have to be converted into its cationic form (which is positively-charged) by losing electrons. However, if the solution that nickel is reacted with is more easily oxidized compared to nickel, then the reaction will not be spontaneous because nickel is stable in this case. 

On the other hand, if nickel is immersed in a solution of a metal which is more stable than it is, such as lead, nickel will be oxidized and lose its electrons to the more stable metal. The more stable metal in solution will accept the lost electrons of nickel and form a solid deposit, while nickel will be in its ionic form in solution. 

Below is a reaction between nickel metal and aqueous lead nitrate solution. 


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You want to determine ΔH o for the reaction Zn(s) + 2HCl(aq) → ZnCl2(aq) + H2(g) To do so, you first determine the heat capacity
Assoli18 [71]

Answer:

(A) The heat capacity of the calorimeter is therefore = −2.1428KJ÷13.5°C

= −0.1587KJ/°C

 

(B) ΔHo for the reaction Zn(s) + 2HCl(aq) → ZnCl2(aq) + H2(g) = –15.42KJ

Explanation:

Solution

 

Calculate the heat actually evolved.

                 q = mcΔt

 

Finding the mass of the reactants in grams we have.

 

Use density. (50 mL + 50 mL ) = 100 mL of solution.

 

100 mL X 1.04g/mL     = 104 grams of solution. (mass = Volume X Density)

                       

 

Find the temperature change.

 

       Δt =tfinal - tinitial = 30.4°C – 16.9°C = 13.5°C

 

    q = mcΔt

       = 104grams × 3.93J/g°C  × 13.5°C = 5.51772×103J

                                         

 

       = 5.51772 × 103 J

 

This is the heat lost in the reaction between HCl and NaOH, therefore q = -5.52 × 103 J.

 

this is an exothermic heat producing reaction.

 To calculate the total heat of the reaction or heat per mole we have

  

50.0 mL of HCl X 2.00 mol HCl /(1000 mL HCl ) = 0.100 mol HCl

                            

 

The same quantity of base, 0.100 mole NaOH, was used.

The energy per unit mole is given by

  

i.e. molar enthalpy = J/mol = -5.52 × 103J / 0.100 mol

            = -5.52 × 104 J/mol

            = -55177.2 J/mol

            = -55.177 kJ/mol

 

Therefore, the enthalpy change for the neutralization of HCl and NaOH, that is the enthalpy, heat, of reaction is ΔH = -55.177 kJ/mol

Heat absorbed by the calorimeter = −57.32kJ − 55.177 kJ = −2.1428KJ

The heat capacity of the calorimeter is therefore = −2.1428KJ÷13.5°C

= −0.1587KJ/°C

 

(B) For the ZnCl we have

 

Calculate the heat actually evolved.

                            q = mcΔt

 

Finding the mass of the reactants in grams we have.

 

Use density.  100 mL of solution of HCl

 

100 mL X 1.015g/mL        = 101.5 grams of solution. (mass = Volume X Density)

                       

 

Find the temperature change.

 

       Δt =tfinal - tinitial = 20.5°C – 16.8°C = 3.7 °C

 

    q = mcΔt

       = 101.5grams × 3.95J/g°C  × 3.7°C = 1483.422×103J

                                         

 

       = -1483.422×103J

 

This is the heat lost in the reaction between HCl and NaOH, therefore q = -1.483 × 103 J.

 

this is an exothermic heat producing reaction.

 To calculate the total heat of the reaction or heat per mole we have

  

100.0 mL of HCl X 1.00 mol HCl /(1000 mL HCl ) = 0.100 mol HCl

                            

 

 

The energy per unit mole is given by

  

i.e. molar enthalpy = J/mol = -1.483 × 103J / 0.100 mol

                                         = -1.483 × 104 J/mol

                                         = -14834.22 J/mol

                                         = -14.834 kJ/mol

 

Therefore, the enthalpy change for the neutralization of HCl and NaOH, that is the enthalpy, heat, of reaction is ΔH = -14.834 kJ/mol

ΔHo for the reaction Zn(s) + 2HCl(aq) → ZnCl2(aq) + H2(g)

= -14.834 kJ –(0.1587KJ/°C×3.7°C) = -15.42KJ

ΔHo for the reaction Zn(s) + 2HCl(aq) → ZnCl2(aq) + H2(g) = –15.42KJ

5 0
2 years ago
A sample of an unknown substance has a mass of .158 kg if 2,510 J of heat is required to heat the substance from 32°C to 61°C wh
ziro4ka [17]

Answer: 0.548J/g°C

Explanation:

Q = s × m × DeltaT

Q = Heat (J)

S = Specific Heat Capacity

M = mass (g)

DeltaT = Change in temperature (°C)

0.158Kg x 1000 = 158g

2.510J = s x 158g x (61°C-32°C)

2.510J/(158g x 29°C) = s

S = 0.54779.... J/g°C

S = 0.548 J/g°C

7 0
2 years ago
An experiment was conducted to measure the effect of equal amounts of fertilizer on the growth of bean plants and corn plants. T
ss7ja [257]

Answer:

b

Explanation:

3 0
2 years ago
Read 2 more answers
Why couldn't you substitute 3m H2SO4 for concentrated HNO3 when oxidizing copper?
schepotkina [342]

This question seems to be an essay question from experiment. Different solution of oxidizing agent will have different strength.  Sulfuric acid or H2SO4 is weaker oxidizing agent when compared to nitric acid (HNO3). In this case, if you subtitute the H2SO4 you wouldn't be able to get the same result for the experiment.



5 0
2 years ago
Read 2 more answers
Albus Dumbledore provides his students with a sample of 19.3 g of sodium sulfate. How many oxygen atoms are in this sample
Dimas [21]

Answer:

<em>3.27·10²³ atoms of O</em>

Explanation:

To figure out the amount of oxygen atoms in this sample, we must first evaluate the sample.

The chemical formula for sodium sulfate is <em>Na₂SO₄, </em>and its molar mass is approximately 142.05\frac{g}{mol}.

We will use stoichiometry to convert from our mass of <em>Na₂SO₄ </em>to moles of <em>Na₂SO₄</em>, and then from moles of <em>Na₂SO₄ </em>to moles of <em>O </em>using the mole ratio; then finally, we will convert from moles of <em>O </em>to atoms of <em>O </em>using Avogadro's constant.

19.3g <em>Na₂SO₄</em> · \frac{1 mol Na^2SO^4}{142.05g Na^2SO^4} · \frac{4 mol O}{1 mol Na^2SO^4} ·\frac{6.022x10^2^3}{1 mol O}

After doing the math for this dimensional analysis, you should get a quantity of approximately <em>3.27·10²³ atoms of O</em>.

3 0
2 years ago
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