Answer:
3-methylthiophene > thiophene > benzene > 2-methylfuran
Explanation:
Primarily, five membered heterocyclic aromatic rings undergo nitration at carbon-2. This is because, nitration at carbon-2 leads to the formation of three resonance structures while attack at carbon-3 yields only two resonance structures, hence it is less stabilized.
The presence of a methyl group which donates electrons promotes the stabilization of the cation formed in the nitration of 3-methylthiophene.
2-methylfuran is the least reactive towards nitration because the 2-position has been blocked by a methyl group.
Answer:
20 kJ/mol
Explanation:
From ∆G°= -RTlnK
But
Ag2SO4(s)<----------->2Ag+(aq) + SO4^2-(aq)
Ksp= [2Ag+]^2 [SO4^2-]
But Ag+ = 0.032M
Ksp= (2×0.032)^2 (0.032)
Ksp= 1.31072×10^-4
∆G°= -RTlnK
∆G°= -(8.314× 298×(-8.93976))= 20KJmol-1( to the nearest KJ)
Answer:
59.2 grams
Explanation:
We are given that 70.4% of the weight of the total 200 g of the concentration is made up of nitric acid, the remaining information is not required to solve the problem. Since water and nitric acid are the only components of the solution, the total weight of water is given by:
There are 59.2 grams of water in this solution.
Answer:p-hydroxybenzaldehyde is stronger acid to phenol
para-cyanophenol is stronger acid to meta-cyanophenol
o-fluorophenol is stronger acid to p-fluorophenol.
Explanation:
The PKa tool relative to Ph are used to contrast the pairs.
The pKa of phenol is 10. The pKa of p-hydroxybenzaldehyde is 9.24
The pKa for meta-cyanophenol is 8.61 and the pKa for para-cyanophenol is 7.95.
The pKa value of o-fluorophenol is 8.7, while that of the p-fluorophenol is 9.9. It's obvious that the inductive effect is more dominant at ortho-position, which results in a more acidic nature
The pKa is the pH value at which a chemical species will accept or donate a proton. The lower the pKa, the stronger the acid and the greater the ability to donate a proton in aqueous solution.
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