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Mandarinka [93]
2 years ago
9

Small beads of iridium-192 are sealed in a plastic tube and inserted through a needle into breast tumors. If an Ir-192 sample ha

s an initial activity of 560 dpm, how much time is required for the activity to drop to 35 dpm (t1/2 = 74 days)?
Chemistry
1 answer:
Stells [14]2 years ago
5 0

Answer:

296.1 day.

Explanation:

  • The decay of radioactive elements obeys first-order kinetics.
  • For a first-order reaction: k = ln2/(t1/2) = 0.693/(t1/2).

Where, k is the rate constant of the reaction.

t1/2 is the half-life time of the reaction (t1/2 = 1620 years).

∴ k = ln2/(t1/2) = 0.693/(74.0 days) = 9.365 x 10⁻³ day⁻¹.

  • For first-order reaction: <em>kt = lna/(a-x).</em>

where, k is the rate constant of the reaction (k = 9.365 x 10⁻³ day⁻¹).

t is the time of the reaction (t = ??? day).

a is the initial concentration of Ir-192 (a = 560.0 dpm).

(a-x) is the remaining concentration of Ir-192 (a -x = 35.0 dpm).

<em>∴ kt = lna/(a-x)</em>

(9.365 x 10⁻³ day⁻¹)(t) = ln(560.0 dpm)/(35.0 dpm).

(9.365 x 10⁻³ day⁻¹)(t) = 2.773.

<em>∴ t </em>= (2.773)/(9.365 x 10⁻³ day⁻¹) =<em> 296.1 day.</em>

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5. How many mm are equal to 4.75 x 10-2 m?
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Answer:

47.5 mm are equal to 4.75 × 10⁻² m.

Explanation:

Meter and millimeter both are units of length. Millimeter is smaller unit while meter is larger unit. The one meter consist of thousand millimeter or we can say that one thousand millimeters are equal to one meter. In order to convert the meter value into millimeter we have to multiply the values with thousand.

we know that one meter is equal to 1000 millimeter.

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47.5 mm are equal to 4.75 × 10⁻² m.

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The equilibrium 2NO(g)+Cl2(g)⇌2NOCl(g) is established at 500 K. An equilibrium mixture of the three gases has partial pressures
QveST [7]

<u>Answer:</u>

<u>For A:</u> The K_p for the given reaction is 4.0\times 10^1

<u>For B:</u> The K_c for the given reaction is 1642.

<u>Explanation:</u>

The given chemical reaction follows:

2NO(g)+Cl_2(g)\rightleftharpoons 2NOCl(g)

  • <u>For A:</u>

The expression of K_p for the above reaction follows:

K_p=\frac{(p_{NOCl})^2}{(p_{NO})^2\times p_{Cl_2}}

We are given:

p_{NOCl}=0.24 atm\\p_{NO}=9.10\times 10^{-2}atm=0.0910atm\\p_{Cl_2}=0.174atm

Putting values in above equation, we get:

K_p=\frac{(0.24)^2}{(0.0910)^2\times 0.174}\\\\K_p=4.0\times 10^1

Hence, the K_p for the given reaction is 4.0\times 10^1

  • <u>For B:</u>

Relation of K_p with K_c is given by the formula:

K_p=K_c(RT)^{\Delta ng}

where,

K_p = equilibrium constant in terms of partial pressure = 4.0\times 10^1

K_c = equilibrium constant in terms of concentration = ?

R = Gas constant = 0.0821\text{ L atm }mol^{-1}K^{-1}

T = temperature = 500 K

\Delta ng = change in number of moles of gas particles = n_{products}-n_{reactants}=2-3=-1

Putting values in above equation, we get:

4.0\times 10^1=K_c\times (0.0821\times 500)^{-1}\\\\K_c=\frac{4.0\times 10^1}{(0.0821\times 500)^{-1})}=1642

Hence, the K_c for the given reaction is 1642.

7 0
2 years ago
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