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agasfer [191]
2 years ago
11

Find the de Broglie wavelength lambda for an electron moving at a speed of 1.00 \times 10^6 \; {\rm m/s}. (Note that this speed

is low enough that the classical momentum formula p=mv is still valid.) Recall that the mass of an electron is m_{\rm e} = 9.11\times 10^{-31}\; {\rm kg}, and Planck's constant is h = 6.626 \times 10^{-34}\; {\rm J \cdot s}.
Express your answer in meters to three significant figures.
lambda =7.270×10−10 \rm m

Part B

Find the de Broglie wavelength lambda of a baseball pitched at a speed of 40.0 m/s. Assume that the mass of the baseball is 0.143 \;{\rm kg}.
Express your answer in meters to three significant figures

lambda =1.16×10−34 \rm m


As a comparison, an atomic nucleus has a diameter of around 10^{-14}\;{\rm m}. Clearly, the wavelength of a moving baseball is too small for you to hope to see diffraction or interference effects during a baseball game.

Part C

Consider a beam of electrons in a vacuum, passing through a very narrow slit of width 2.00 \;\mu{\rm m}. The electrons then head toward an array of detectors a distance 1.091 m away. These detectors indicate a diffraction pattern, with a broad maximum of electron intensity (i.e., the number of electrons received in a certain area over a certain period of time) with minima of electron intensity on either side, spaced 0.492 cm from the center of the pattern. What is the wavelength lambda of one of the electrons in this beam? Recall that the location of the first intensity minima in a single slit diffraction pattern for light is y=L \lambda /a, where L is the distance to the screen (detector) and a is the width of the slit. The derivation of this formula was based entirely upon the wave nature of light, so by de Broglie's hypothesis it will also apply to the case of electron waves.

Express your answer in meters to three significant figures.

lambda =9.02×10−9 \rm m

Part D

What is the momentum p of one of these electrons?
Express your answer in kilogram-meters per second to three significant figures.
Chemistry
1 answer:
masya89 [10]2 years ago
7 0

(A) 7.28\cdot 10^{-10} m

The De Broglie wavelength of an electron is given by

\lambda=\frac{h}{p} (1)

where

h is the Planck constant

p is the momentum of the electron

The electron in this problem has a speed of

v=1.00\cdot 10^6 m/s

and its mass is

m=9.11\cdot 10^{-31} kg

So, its momentum is

p=mv=(9.11\cdot 10^{-31} kg)(1.00\cdot 10^6 m/s)=9.11\cdot 10^{-25}kg m/s

And substituting into (1), we find its De Broglie wavelength

\lambda=\frac{6.63\cdot 10^{-34}Js}{9.11\cdot 10^{-25} kg m/s}=7.28\cdot 10^{-10} m

(B) 1.16\cdot 10^{-34}m

In this case we have:

m = 0.143 kg is the mass of the ball

v = 40.0 m/s is the speed of the ball

So, the momentum of the ball is

p=mv=(0.143 kg)(40.0 m/s)=5.72 kg m/s

And so, the De Broglie wavelength of the ball is given by

\lambda=\frac{h}{p}=\frac{6.63\cdot 10^{-34} Js}{5.72 kg m/s}=1.16\cdot 10^{-34}m

(C) 9.02\cdot 10^{-9}m

The location of the first intensity minima is given by

y=\frac{L\lambda}{a}

where in this case we have

y=0.492 cm = 4.92\cdot 10^{-3} m

L = 1.091 is the distance between the detector and the slit

a=2.00\mu m=2.00\cdot 10^{-6}m is the width of the slit

Solving the formula for \lambda, we find the wavelength of the electrons in the beam:

\lambda=\frac{ya}{L}=\frac{(4.92\cdot 10^{-3}m)(2.00\cdot 10^{-6} m)}{1.091 m}=9.02\cdot 10^{-9}m

(D) 7.35\cdot 10^{-26}kg m/s

The momentum of one of these electrons can be found by re-arranging the formula of the De Broglie wavelength:

p=\frac{h}{\lambda}

where here we have

\lambda=9.02\cdot 10^{-9}m is the wavelength

Substituting into the formula, we find

p=\frac{6.63\cdot 10^{-34}Js}{9.02\cdot 10^{-9}m}=7.35\cdot 10^{-26}kg m/s

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What mass of CaSO3 must have been present initially to produce 14.5 L of SO2 gas at a temperature of 12.5°C and a pressure of 1.
german
When the reaction equation is:

CaSO3(s) → CaO(s) + SO2(g)

we can see that the molar ratio between CaSO3 & SO2 is 1:1 so, we need to find first the moles SO2.

to get the moles of SO2 we are going to use the ideal gas equation:

PV = nRT

when P is the pressure =  1.1 atm

and V is the volume = 14.5 L 

n is the moles' number (which we need to calculate)

R ideal gas constant = 0.0821

and T is the temperature in Kelvin = 12.5 + 273 = 285.5 K

so, by substitution:

1.1 * 14.5 L = n * 0.0821 * 285.5

∴ n = 1.1 * 14.5 / (0.0821*285.5)

       = 0.68 moles SO2

∴ moles CaSO3 = 0.68 moles

so we can easily get the mass of CaSO3:

when mass = moles * molar mass

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2 years ago
What pressure (in atm) would be exerted by 76 g of fluorine gas (f2) in a 1.50 liter vessel at -37oc? (a) 26 atm(b) 4.1 atm(c) 1
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<span>Let's assume that the F</span>₂ gas has ideal gas behavior. 

<span> Then we can use ideal gas formula,
PV = nRT

Where, P is the pressure of the gas (Pa), V is the volume of the gas (m³), n is the number of moles of gas (mol), R is the universal gas constant ( 8.314 J mol</span>⁻¹ K⁻<span>¹) and T is temperature in Kelvin.</span>


Moles = mass / molar mass


Molar mass of F₂ = 38 g/mol

Mass of F₂  = 76 g

Hence, moles of F₂ = 76 g / 38 g/mol = 2 mol

<span>
P = ?
V = 1.5 L = 1.5 x 10</span>⁻³ m³

n = 2 mol

R = 8.314 J mol⁻¹ K⁻<span>¹
T = -37 °C = 236 K

By substitution,
</span>

P x 1.5 x 10⁻³ m³ = 2 mol x 8.314 J mol⁻¹ K⁻¹ x 236 K

                         p = 2616138.67 Pa

                         p = 25.8 atm = 26 atm


Hence, the pressure of the gas is 26 atm.

Answer is "a".

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2 years ago
Question 2: Phase Changes (14 points) a. Rewrite each of the following equations for phase changes, to include the heat required
lilavasa [31]

Explanation:

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              H_{2}O(l) \rightleftharpoons  H_{2}O(s)

A reaction in which there will be absorption of heat energy is known as endothermic reaction.

A reaction in which there will be release of heat energy is known as exothermic reaction.

As liquid state of water is changing into solid state. So, it means that molecules of water came close to each other. Hence, there will be release of heat this means that reaction is exothermic in nature.

Hence, phase change from liquid to solid will be exothermic in nature.

Latent heat of fusion is defined as the amount of energy necessary to convert 1 gram of a solid into liquid state at its melting point.

So, when solid state of water changes into liquid state then it means energy is absorbed by the molecules of ice due to which they have gained kinetic energy. Hence, they moved away from each other leading to formation of liquid state of water.

Latent heat of freezing of liquid water is 334 J/g.

Specific heat of liquid water is 4.186 J/g ^{o}C

Specific heat of steam is 1.996 kJ/kg/^{o}K

Specific heat of ice is 2.1 kJ/kg/^{o}K

(ii)  The equilibrium reaction equation will be as follows.

              H_{2}O(l) \rightleftharpoons H_{2}O(g)

As liquid state of water is changing into gaseous or vapor state. So, it means molecules of liquid water has gained kinetic energy hence, they colloid more rapidly with each other.

As a result, heat will be absorbed by the liquid state of water. Hence, heat will be absorbed. Therefore, phase change from liquid to gas will be endothermic in nature.

Whereas when gaseous state of water will change into liquid state then heat will be released during this process of condensation. As a result, in that case reaction will be exothermic in nature.

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Answer:

The volume that this same amount of air will occupy in his lungs when he reaches a depth of 124 m is - 0.27 L.

Explanation:

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{P_1}\times {V_1}={P_2}\times {V_2}

Given ,  

V₁ = 3.6 L  

V₂ = ?

P₁ = 1.0 atm

P₂ = 13.3 atm (From correct source)

Using above equation as:

{P_1}\times {V_1}={P_2}\times {V_2}

{1.0\ atm}\times {3.6\ L}={13.3\ atm}\times {V_2}

{V_2}=\frac{{1.0}\times {3.6}}{13.3}\ L

{V_2}=0.27\ L

The volume that this same amount of air will occupy in his lungs when he reaches a depth of 124 m is - 0.27 L.

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2 years ago
Na (atomic no. 11) reacts with Cl (atomic no. 17) to become stable. In the reaction, Na will ____________, while Cl will _______
nignag [31]

Answer:

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The electronic configurations of sodium and chlorine are;

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