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agasfer [191]
2 years ago
11

Find the de Broglie wavelength lambda for an electron moving at a speed of 1.00 \times 10^6 \; {\rm m/s}. (Note that this speed

is low enough that the classical momentum formula p=mv is still valid.) Recall that the mass of an electron is m_{\rm e} = 9.11\times 10^{-31}\; {\rm kg}, and Planck's constant is h = 6.626 \times 10^{-34}\; {\rm J \cdot s}.
Express your answer in meters to three significant figures.
lambda =7.270×10−10 \rm m

Part B

Find the de Broglie wavelength lambda of a baseball pitched at a speed of 40.0 m/s. Assume that the mass of the baseball is 0.143 \;{\rm kg}.
Express your answer in meters to three significant figures

lambda =1.16×10−34 \rm m


As a comparison, an atomic nucleus has a diameter of around 10^{-14}\;{\rm m}. Clearly, the wavelength of a moving baseball is too small for you to hope to see diffraction or interference effects during a baseball game.

Part C

Consider a beam of electrons in a vacuum, passing through a very narrow slit of width 2.00 \;\mu{\rm m}. The electrons then head toward an array of detectors a distance 1.091 m away. These detectors indicate a diffraction pattern, with a broad maximum of electron intensity (i.e., the number of electrons received in a certain area over a certain period of time) with minima of electron intensity on either side, spaced 0.492 cm from the center of the pattern. What is the wavelength lambda of one of the electrons in this beam? Recall that the location of the first intensity minima in a single slit diffraction pattern for light is y=L \lambda /a, where L is the distance to the screen (detector) and a is the width of the slit. The derivation of this formula was based entirely upon the wave nature of light, so by de Broglie's hypothesis it will also apply to the case of electron waves.

Express your answer in meters to three significant figures.

lambda =9.02×10−9 \rm m

Part D

What is the momentum p of one of these electrons?
Express your answer in kilogram-meters per second to three significant figures.
Chemistry
1 answer:
masya89 [10]2 years ago
7 0

(A) 7.28\cdot 10^{-10} m

The De Broglie wavelength of an electron is given by

\lambda=\frac{h}{p} (1)

where

h is the Planck constant

p is the momentum of the electron

The electron in this problem has a speed of

v=1.00\cdot 10^6 m/s

and its mass is

m=9.11\cdot 10^{-31} kg

So, its momentum is

p=mv=(9.11\cdot 10^{-31} kg)(1.00\cdot 10^6 m/s)=9.11\cdot 10^{-25}kg m/s

And substituting into (1), we find its De Broglie wavelength

\lambda=\frac{6.63\cdot 10^{-34}Js}{9.11\cdot 10^{-25} kg m/s}=7.28\cdot 10^{-10} m

(B) 1.16\cdot 10^{-34}m

In this case we have:

m = 0.143 kg is the mass of the ball

v = 40.0 m/s is the speed of the ball

So, the momentum of the ball is

p=mv=(0.143 kg)(40.0 m/s)=5.72 kg m/s

And so, the De Broglie wavelength of the ball is given by

\lambda=\frac{h}{p}=\frac{6.63\cdot 10^{-34} Js}{5.72 kg m/s}=1.16\cdot 10^{-34}m

(C) 9.02\cdot 10^{-9}m

The location of the first intensity minima is given by

y=\frac{L\lambda}{a}

where in this case we have

y=0.492 cm = 4.92\cdot 10^{-3} m

L = 1.091 is the distance between the detector and the slit

a=2.00\mu m=2.00\cdot 10^{-6}m is the width of the slit

Solving the formula for \lambda, we find the wavelength of the electrons in the beam:

\lambda=\frac{ya}{L}=\frac{(4.92\cdot 10^{-3}m)(2.00\cdot 10^{-6} m)}{1.091 m}=9.02\cdot 10^{-9}m

(D) 7.35\cdot 10^{-26}kg m/s

The momentum of one of these electrons can be found by re-arranging the formula of the De Broglie wavelength:

p=\frac{h}{\lambda}

where here we have

\lambda=9.02\cdot 10^{-9}m is the wavelength

Substituting into the formula, we find

p=\frac{6.63\cdot 10^{-34}Js}{9.02\cdot 10^{-9}m}=7.35\cdot 10^{-26}kg m/s

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Air in a 0.3 m3 cylinder is initially at a pressure of 10 bar and a temperature of 330K. The cylinder is to be emptied by openin
sergiy2304 [10]

Answer:

(a) Temperature = 330 K, and mass = 0.321 kg

(b) T₂ = 171.56 K, mass = 0.32223 kg

Explanation:

For a constant temperature process we have

p₁v₁ = p₂v₂

Where p₁ = initial pressure = 10 bar = 1000000 Pa

p₂ = final pressure = 1 atm = 101325 Pa

v₁ initial volume = 0.3 m³

v₂ = final volume = unknown

From the relation we have v₂ = 2.96 m³

Therefore at constant temperature 2.93 m³ - 0.3 m³ or 2.66 m³ will be expelled from the container

Temperature = 330 K, and mass =

Also from the relation p1v1 = mRT1

We have, (1000000×0.3)/(8314×330) = 109..337 mole

For air mass

Mass = 3.171 kg

After opening we have

p2v2/(RT1) = n2 = 11.07 mol or 0.321 kg

or

(b) This is said to be adiabatic condition hence

Here

But cp = 29 (J/mol K).

and p₁v₁ = RT₁ therefore R = 1000000*0.3/330 = 909.1 J/mol·K

And For perfect gas γ = 1.4

Hence T₂ = 171.56 K

γ =cp/cv therefore cv=cp/γ = 29/1.4 = 20.714 (J/mol K). and R =cp-cv = 8.29 J/mol·K

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p2v2/(R×T2) = 11.11 mole left

For air that is 0.32223 kg

5 0
2 years ago
Which statements accurately describe the polarity and electronegativity of water?
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<span>The statement that most accurately and effectively described the polarity and electronegativity in water is that the covalent bonds within these water molecules bind with the single oxygen atom in the molecule, as well as the two hydrogen atoms that it holds as well.</span>
5 0
1 year ago
3.00 moles of NO2 have a mass of
ExtremeBDS [4]
When solving for the mass of a compound when you’re given the number of moles present, you need to know the molar mass (how many grams there are in a mole of that compound).

In this case, we can make the following equation:

3.00(14.01 + 2(16.00))

In Nitrogen, the molar mass is 14.01 grams per mole, and Oxygen is 16.01 grams per mole.

However, because there are 2 oxygen atoms present per molecule, you must multiply it by two in order to solve for the molar mass.

Anyway:
3.00(14.01 + 2(16.00))

Simplify:
3.00(14.01 + 32.00)
3.00(46.01)

Multiply:
3.00(46.01) = 138.03

3.00 moles of NO2 has a mass of 138.03 grams.
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6 0
2 years ago
For many purposes we can treat methane (CH) as an ideal gas at temperatures above its boiling point of - 161. °C. Suppose the te
AysviL [449]

Answer:

Explanation:

T₁ = 100 + 273 = 373K

T₂ = 273 + 119 = 392 K

V₁ = initial volume

V₂ = Final volume

P₁ = P₁

P₂ = .85P₁

Using gas law equation

\frac{P_1\times V_1}{T_1} =\frac{P_2\times V_2}{T_2}

= \frac{P_1\times V_1}{373} =\frac{.85P_1\times V_2}{392}

V₂ = 1.236 V₁

% increase in volume

= V₂-V₁ / V₁  x 100

= (1.236 V₁ - V₁ / V₁)x 100

= .236 x 100

= 23.6 % .

5 0
2 years ago
To neutralize 1.65g LiOH, how much .150 M HCl would be needed?
CaHeK987 [17]
The reaction between LiOH and HCl is;   
LiOH + HCl → LiCl + H₂O

The stoichiometric ratio between LiOH and HCl is 1 : 1
moles of LiOH added = moles of HCl needed to neutralize.

Molar mass of LiOH = 24 g/mol

moles = mass / molar mass
LIOH moles  = 1.65 / 24 = 0.06875 mol
Hence needed HCl moles = 0.06875 mol

Molarity = moles (mol) / Volume (L)
Hence needed HCl volume = moles / molarity                                           
                                            = 0.06875 mol / 0.150 mol/L                                           
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4 0
2 years ago
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