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agasfer [191]
1 year ago
11

Find the de Broglie wavelength lambda for an electron moving at a speed of 1.00 \times 10^6 \; {\rm m/s}. (Note that this speed

is low enough that the classical momentum formula p=mv is still valid.) Recall that the mass of an electron is m_{\rm e} = 9.11\times 10^{-31}\; {\rm kg}, and Planck's constant is h = 6.626 \times 10^{-34}\; {\rm J \cdot s}.
Express your answer in meters to three significant figures.
lambda =7.270×10−10 \rm m

Part B

Find the de Broglie wavelength lambda of a baseball pitched at a speed of 40.0 m/s. Assume that the mass of the baseball is 0.143 \;{\rm kg}.
Express your answer in meters to three significant figures

lambda =1.16×10−34 \rm m


As a comparison, an atomic nucleus has a diameter of around 10^{-14}\;{\rm m}. Clearly, the wavelength of a moving baseball is too small for you to hope to see diffraction or interference effects during a baseball game.

Part C

Consider a beam of electrons in a vacuum, passing through a very narrow slit of width 2.00 \;\mu{\rm m}. The electrons then head toward an array of detectors a distance 1.091 m away. These detectors indicate a diffraction pattern, with a broad maximum of electron intensity (i.e., the number of electrons received in a certain area over a certain period of time) with minima of electron intensity on either side, spaced 0.492 cm from the center of the pattern. What is the wavelength lambda of one of the electrons in this beam? Recall that the location of the first intensity minima in a single slit diffraction pattern for light is y=L \lambda /a, where L is the distance to the screen (detector) and a is the width of the slit. The derivation of this formula was based entirely upon the wave nature of light, so by de Broglie's hypothesis it will also apply to the case of electron waves.

Express your answer in meters to three significant figures.

lambda =9.02×10−9 \rm m

Part D

What is the momentum p of one of these electrons?
Express your answer in kilogram-meters per second to three significant figures.
Chemistry
1 answer:
masya89 [10]1 year ago
7 0

(A) 7.28\cdot 10^{-10} m

The De Broglie wavelength of an electron is given by

\lambda=\frac{h}{p} (1)

where

h is the Planck constant

p is the momentum of the electron

The electron in this problem has a speed of

v=1.00\cdot 10^6 m/s

and its mass is

m=9.11\cdot 10^{-31} kg

So, its momentum is

p=mv=(9.11\cdot 10^{-31} kg)(1.00\cdot 10^6 m/s)=9.11\cdot 10^{-25}kg m/s

And substituting into (1), we find its De Broglie wavelength

\lambda=\frac{6.63\cdot 10^{-34}Js}{9.11\cdot 10^{-25} kg m/s}=7.28\cdot 10^{-10} m

(B) 1.16\cdot 10^{-34}m

In this case we have:

m = 0.143 kg is the mass of the ball

v = 40.0 m/s is the speed of the ball

So, the momentum of the ball is

p=mv=(0.143 kg)(40.0 m/s)=5.72 kg m/s

And so, the De Broglie wavelength of the ball is given by

\lambda=\frac{h}{p}=\frac{6.63\cdot 10^{-34} Js}{5.72 kg m/s}=1.16\cdot 10^{-34}m

(C) 9.02\cdot 10^{-9}m

The location of the first intensity minima is given by

y=\frac{L\lambda}{a}

where in this case we have

y=0.492 cm = 4.92\cdot 10^{-3} m

L = 1.091 is the distance between the detector and the slit

a=2.00\mu m=2.00\cdot 10^{-6}m is the width of the slit

Solving the formula for \lambda, we find the wavelength of the electrons in the beam:

\lambda=\frac{ya}{L}=\frac{(4.92\cdot 10^{-3}m)(2.00\cdot 10^{-6} m)}{1.091 m}=9.02\cdot 10^{-9}m

(D) 7.35\cdot 10^{-26}kg m/s

The momentum of one of these electrons can be found by re-arranging the formula of the De Broglie wavelength:

p=\frac{h}{\lambda}

where here we have

\lambda=9.02\cdot 10^{-9}m is the wavelength

Substituting into the formula, we find

p=\frac{6.63\cdot 10^{-34}Js}{9.02\cdot 10^{-9}m}=7.35\cdot 10^{-26}kg m/s

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drek231 [11]

Answer:

Aluminium atoms =  4.13 *10^22 aluminium atoms

The correct answer is E

Explanation:

Step 1: Data given

Mass of Al2O3 = 3.50 grams

Molar mass of Al2O3 = 101.96 g/mol

Number of Avogadro = 6.022 * 10^23 /mol

Step 2: Calculate moles Al2O3

Moles Al2O3 = mass Al2O3 / molar mass Al2O3

Moles Al2O3 = 3.50 grams / 101.96 g/mol

Moles Al2O3 = 0.0343 moles

Step 3: Calculate moles Aluminium

In 1 mol Al2O3 we have 2 moles Al

in 0.0343 moles Al2O3 we have 2*0.0343 = 0.0686 moles Al

Step 4: Calculate aluminium atoms

Aluminium atoms =  moles aluminium * Number of Avogadro

Aluminium atoms =  0.0686 * 6.022 * 10^23

Aluminium atoms =  4.13 *10^22 aluminium atoms

The correct answer is E

3 0
2 years ago
5.00 g of hydrogen gas and 50.0g of oxygen gas are introduced into an otherwise empty 9.00L steel cylinder, and the hydrogen is
GenaCL600 [577]
1) Balanced chemical reaction:

2H2 + O2 -> 2H20

Sotoichiometry: 2 moles H2: 1 mol O2 : 2 moles H2O

2) Reactant quantities converted to moles

H2: 5.00 g / 2 g/mol = 2.5 mol

O2: 50.0 g / 32 g/mol = 1.5625 mol

Limitant reactant: H2 (because as per the stoichiometry it will be consumed with 1.25 mol of O2).

3) Products

H2 totally consumed -> 0 mol at the end

O2 = 1.25 mol consumed -> 1.5625 mol - 1.25 mol = 0.3125 mol at the end

H2O: 2.5 mol H2 produces 2.5 mol H2O -> 2.5 mol at the end.

Total number of moles: 0.3125mol + 2.5 mol = 2.8125 mol

4) Pressure

Use pV = nRT
n = 2.8125
V= 9 liters
R = 0.082 atm*lit/K*mol
T = 35 C + 273.15 = 308.15K

p = nRT/V  = 7.9 atm
3 0
1 year ago
Read 2 more answers
Green light has a frequency of about 6.00×1014s−1. What is the energy of a photon of green light?
Sindrei [870]

3.98 x 10⁻¹⁹ Joule

<h3>Further explanation</h3>

<u>Given:</u>

The green light has a frequency of about 6.00 x 10¹⁴ s⁻¹.

<u>Question:</u>

The energy of a photon of green light (in joules).

<u>The Process:</u>

The energy of a photon is given by \boxed{\boxed{ \ E = hf \ }}

  • E = energy in joules
  • h = Planck's constant 6.63 x 10⁻³⁴ Js
  • f = frequency of light in Hz (sometimes the symbol f is written as v)

Let us find out the energy of the green light emitted per photon.

\boxed{ \ E = (6.63 \times 10^{-34})(6.00 \times 10^{14}) \ }

Thus, we get a result of \boxed{\boxed{ \ E = 3.98 \times 10^{-19} \ J \ }}

- - - - - - - - - -

Notes

  • When an electron moves between energy levels it must emit or absorb energy.  
  • The energy emitted or absorbed corresponds to the difference between the two allowed energy states, i.e., as packets of light called photons.  
  • A higher energy photon corresponds to a higher frequency (shorter wavelength) of light.
<h3>Learn more</h3>
  1. The energy of the orange light emitted per photon brainly.com/question/2485282#
  2. Determine the density of our sun at the end of its lifetime brainly.com/question/5189537  
  3. Find out the kinetic energy of the emitted electrons when metal is exposed to UV rays brainly.com/question/5416146  

Keywords: green light, frequency, the energy, a photon, Planck's constant, electrons, emitted, wavelength, joules

7 0
2 years ago
) Based on the graph, determine the order of the decomposition reaction of cyclobutane at 1270 K. Justify your answer.
lidiya [134]

Answer:

- The order of the reaction based on the graph provided is first order.

- 99% of the cyclobutane would have decomposed in 53.15 milliseconds.

d) Rate = K [Cl₂]

K = rate constant

The justification is presented in the Explanation provided below.

e) A catalyst is a substance that alters the rate of a reaction without participating or being used up in the reaction.

Cl₂ is one of the reactants in the reaction, hence, it participates actively and is used up in the process of the reaction, hence, it cannot be termed as a catalyst for the reaction.

So, this shows why the student's claim is false.

Explanation:

To investigate the order of a reaction, a method of trial and error is usually employed as the general equations for the amount of reactant left for various orders are known.

So, the behaviour of the plot of maybe the concentration of reactant with time, or the plot of the natural logarithm of the concentration of reactant with time.

The graph given is evidently an exponential function. It is a graph of the concentration of cyclobutane declining exponentially with time. This aligns with the gemeral expression of the concentration of reactants for a first order reaction.

C(t) = C₀ e⁻ᵏᵗ

where C(t) = concentration of the reactant at any time

C₀ = Initial concentration of cyclobutane = 1.60 mol/L

k = rate constant

The rate constant for a first order reaction is given

k = (In 2)/T

where T = half life of the reaction. It is the time taken for the concentration of the reactant to fall to half of its initial concentration.

From the graph, when the concentration of reactant reaches half of its initial concentration, that is, when C(t) = 0.80 mol/L, time = 8.0 milliseconds = 0.008 s

k = (In 2)/0.008 = (0.693/0.008) = 86.64 /s

Calculate the time, in milliseconds, that it would take for 99 percent of the original cyclobutane at 1270 K to decompose

C(t) = C₀ e⁻ᵏᵗ

when 99% of the cyclobutane has decomposed, there only 1% left

C(t) = 0.01C₀

k = 86.64 /s

t = ?

0.01C₀ = C₀ e⁻ᵏᵗ

e⁻ᵏᵗ = 0.01

In e⁻ᵏᵗ = In 0.01 = -4.605

-kt = -4.605

t = (4.605/k) = (4.605/86.64) = 0.05315 s = 53.15 milliseconds.

d) The reaction mechanism for the reaction of cyclopentane and chlorine gas is given as

Cl₂ → 2Cl (slow)

Cl + C₅H₁₀ → HCl + C₅H₉ (fast)

C₅H₉ + Cl → C₅H₉Cl (fast)

The rate law for a reaction is obtained from the slow step amongst the the elementary reactions or reaction mechanism for the reaction. After writing the rate law from the slow step, any intermediates that appear in the rate law is then substituted for, using the other reaction steps.

For This reaction, the slow step is the first elementary reaction where Chlorine gas dissociates into 2 Chlorine atoms. Hence, the rate law is

Rate = K [Cl₂]

K = rate constant

Since, no intermediates appear in this rate law, no further simplification is necessary.

The obtained rate law indicates that the reaction is first order with respect to the concentration of the Chlorine gas and zero order with respect to cyclopentane.

e) A catalyst is a substance that alters the rate of a reaction without participating or being used up in the reaction.

Cl₂ is one of the reactants in the reaction, hence, it participates actively and is used up in the process of the reaction, hence, it cannot be termed as a catalyst for the reaction.

So, this shows why the student's claim is false.

Hope this Helps!!!

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1 year ago
Match each situation below to a letter on the illustration.
Mnenie [13.5K]

Answer:a

Explanation:

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