Answer:
Here's what I get.
Explanation:
The frequency of a vibration depends on the strength of the bond (the force constant).
The stronger the bond, the more energy is needed for the vibration, so the frequency (f) and the wavenumber increase.
Acetophenone
Resonance interactions with the aromatic ring give the C=O bond in acetophenone a mix of single- and double-bond character, and the bond frequency = 1685 cm⁻¹.
p-Aminoacetophenone
The +R effect of the amino group increases the single-bond character of the C=O bond. The bond lengthens, so it becomes weaker.
The vibrational energy decreases, so wavenumber decreases to 1652 cm⁻¹.
p-Nitroacetophenone
The nitro group puts a partial positive charge on C-1. The -I effect withdraws electrons from the acetyl group.
As electron density moves toward C-1, the double bond character of the C=O group increases.
The bond length decreases, so the bond becomes stronger, and wavenumber increases to 1693 cm¹.
In given data:
maximum absorption wavelength λ = 580 nm = 580 x 10⁻⁹ m
write the equation to find the crystal field splitting energy:
E = hC / λ
Here, E is the crystal field splitting energy, h = 6.63 x 10⁻³⁴ J.sec is Planck's constant and C = 3 x 10⁸ m/sec is speed of light.
substitute in the equation above:
E = (6.64 x 10⁻³⁴ x 3 x 10⁸) / (580 x 10⁻⁹) = 3.43 x 10⁻¹⁹J
This crystal field splitting energy is for 1 ion.
Number of atoms in one mole, NA = 6.023 x 10²³
to calculate the crystal field splitting energy for one mole:
E(total) = E x NA
= (3.43 x 10⁻¹⁹) x (6.023 x 10²³) = 206 kJ/ mole
A, nonpoint souce pollution is "a main problem with water quality."
Answer;
The total pressure is 1.107 atm.
Explanation;
The total pressure is the sum of the pressures of the three gases in the flask
Pressure (total) = 0.215 atm + 0.066 atm + 0.826 atm = 1.107 atm
= 1.107 atm.
Answer:
Molar concentration of the weak acid solution is 0.0932
Explanation:
Using the formula: 
Where Ca = molarity of acid
Cb = molarity of base = 0.0981 M
Va = volume of acid = 25.0 mL
Vb = volume of base = 23.74 mL
na = mole of acid
nb = mole of base
Since the acid is monopromatic, 1 mole of the acid will require 1 mole of NaOH. Hence, na = nb = 1
Therefore, 
Ca = 0.0981 x 23.74/25.0
= 0.093155 M
To 4 significant figure = 0.0932 M
