Answer:
Zn(OH)₂
<em>Explanation:
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Zn is above Fe in the activity series, so it is more readily oxidized:
Zn(s) ⟶ Zn²⁺(aq) + 2e⁻
The zinc ions go into solution.
The electrons travel from the Zn to the surface of the iron nail, where they reduce the water to hydrogen and hydroxide ions.
2H₂O(ℓ) + 2e⁻ ⟶ H₂(g) + 2OH⁻(aq)
Neither the zinc ions nor the hydroxide ions can move far through the gel.
Their concentration builds up around the hail. The ions find each other and form a precipitate.
Zn²⁺(aq) + 2OH⁻(aq) ⟶ Zn(OH)₂(s)
Answer:
(A) pH < 1 the predominant form is the cation: H3C-C(H)(NH3+)-COOH
(B) pH = pl the predominant form is the zwitterion H3C-C(H)(NH3+)-COO-
(C) pH > 11 the predominant form is the anion: H3C-C(H)(NH2)-COO-
(D) Does not occurs in any significant pH: H3C-C(H)(NH2)-COOH
Explanation:
Amino acids are bifunctional because they have an amine group and a carboxyl group. The amine group is a weak base and the carboxyl group is a weak acid, but the pKa of both groups will depend on the whole structure of the amino acid. Also, every amino acid has an isoelectric point (pI), which means the pH were the predominant form of the amino acid is the zwitterion. The structure of the alanine (CH3CH2NH2COOH) shows it has the carboxyl group at C1 with a pKa1 of 2.3 and the amino group at C2 whit the pKa2 of 9.7. The isoelectric poin (pI) of Alanine is 6. Consequently, the protonation of the molecule will depend on the pH of the solution. There are three possibilities:
1) If the pH is under the pKa of the carboxyl group (2.3) the predominant form will be with the amino group protonated, forming a cation (CH3CH(NH3+)COOH).
2) If the pH is between pKa1 (2.3) and pKa2 (9.7) the predominant form will be the zwitterion (CH3CH(NH3+)(COO-)).
3) If the pH is upper the pKa2 of the amino group (9.7) the predominant form will be with the carboxyl group deprotonated, forming an anion (CH3CHNH2(COO-)).
Answer:
pHe = 3.2 × 10⁻³ atm
pNe = 2.5 × 10⁻³ atm
P = 5.7 × 10⁻³ atm
Explanation:
Given data
Volume = 1.00 L
Temperature = 25°C + 273 = 298 K
mHe = 0.52 mg = 0.52 × 10⁻³ g
mNe = 2.05 mg = 2.05 × 10⁻³ g
The molar mass of He is 4.00 g/mol. The moles of He are:
0.52 × 10⁻³ g × (1 mol / 4.00 g) = 1.3 × 10⁻⁴ mol
We can find the partial pressure of He using the ideal gas equation.
P × V = n × R × T
P × 1.00 L = 1.3 × 10⁻⁴ mol × (0.082 atm.L/mol.K) × 298 K
P = 3.2 × 10⁻³ atm
The molar mass of Ne is 20.18 g/mol. The moles of Ne are:
2.05 × 10⁻³ g × (1 mol / 20.18 g) = 1.02 × 10⁻⁴ mol
We can find the partial pressure of Ne using the ideal gas equation.
P × V = n × R × T
P × 1.00 L = 1.02 × 10⁻⁴ mol × (0.082 atm.L/mol.K) × 298 K
P = 2.5 × 10⁻³ atm
The total pressure is the sum of the partial pressures.
P = 3.2 × 10⁻³ atm + 2.5 × 10⁻³ atm = 5.7 × 10⁻³ atm
Answer:
The boiling point of water at 550 torr will be 91 °C or 364 Kelvin
Explanation:
Step 1: Data given
Pressure = 550 torr
The heat of vaporization of water is 40.7 kJ/mol.
Step 2: Calculate boiling point
⇒ We'll use the Clausius-Clapeyron equation
ln(P2/P1) = (ΔHvap/R)*(1/T1-1/T2)
ln(P2/P1) = (40.7*10^3 / 8.314)*(1/T1 - 1/T2)
⇒ with P1 = 760 torr = 1 atm
⇒ with P2 = 550 torr
⇒ with T1 = the boiling point of water at 760 torr = 373.15 Kelvin
⇒ with T2 = the boiling point of water at 550 torr = TO BE DETERMINED
ln(550/760) = 4895.4*(1/373.15 - 1/T2)
-0.3234 = 13.119 - 4895.4/T2
-13.4424= -4895.4/T2
T2 = 364.2 Kelvin = 91 °C
The boiling point of water at 550 torr will be 91 °C or 364 Kelvin
