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mestny [16]
2 years ago
5

A new potential heart medicine, code-named X-281, is being tested by a pharmaceutical company, Pharma-pill. As a research techni

cian at Pharma-pill, you are told that X-281 is a monoprotic weak acid, but because of security concerns, the actual chemical formula must remain top secret. The company is interested in the drug's Ka value because only the dissociated form of the chemical is active in preventing cholesterol buildup in arteries. To find the pKa of X-281, you prepare a 0.086 M test solution of X-281 at 25.0 ∘C. The pH of the solution is determined to be 2.40. What is the pKa of X-281?
Chemistry
1 answer:
iogann1982 [59]2 years ago
8 0

Answer:

pKa X-281 = 3.714

Explanation:

  • pKa = - log Ka

∴ HA ↔ H3O+  +  A-

⇒ Ka = [H3O+].[A-] / [HA]

∴ <em>C</em> X-281 = 0.086 M

∴ pH = 2.40 = - Log [H3O+]

⇒ [H3O+] = 3.981 E-3 M

mass blance:

⇒ <em>C</em> X-281 = 0.086 M = [HA] + [A-]

charge balance:

⇒ [H3O+] = [A-] + [OH-].......[OH-], its comes from water.

⇒ [H3O+] = [A-]

⇒ [HA] = 0.086 - [H3O+]

⇒ [HA] = 0.086 M - 3.981 E-3 M = 0.082 M

⇒ Ka = [H3O+]²/[HA]

⇒ Ka = (3.981 E-3)² / 0.082 = 1.9323 E-4

⇒ pKa = - Log Ka = - Log ( 1.9323 E-4)

⇒ pKa = 3.714  

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How many liters of 3.0 M NaOH solution will react with 2.4 mol H2SO4? (Remember to balance the equation.)
timurjin [86]

Answer:

1.6 L is the volume of NaOH that has reacted

Explanation:

The balanced reaction is:

H₂SO₄ + 2NaOH → Na₂SO₄  + 2H₂O

This is a neutralization reaction between a strong acid and a strong base. The products are the correspond salt and water.

We propose this rule of three:

1 mol of sulfuric acid needs 2 mol of NaOH to react to react

Then, 2.4 moles of H₂SO₄  will react with (2.4 . 2) / 1 = 4.8 moles of NaOH

As molarity is 3M, we can determine the volume of our solution

Molarity (M) = mol / volume(L) → Volume(L) = mol / Molarity

Volume(L) = 4.8 mol / 3 M = 1.6 L

3 0
2 years ago
Name one manufactured device or natural phenomenon that emits electromagnetic radiation in each of the following wavelengths: ra
Bas_tet [7]
Radio - Radio station transmits radio wavelength which is received by the
Radio. 
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7 0
2 years ago
Hydrogen sulfide (H2S) is a common and troublesome pollutant in industrial wastewaters. One way to remove H2S is to treat the wa
Kryger [21]

Explanation:

As the given reaction is as follows.

     H_{2}S(aq) + Cl_{2}(aq) \rightarrow S(s) + 2H^{+}(aq) + 2Cl^{-}(aq)

So, according to the balanced equation, it can be seen that rate of formation of Cl^{-} will be twice the rate of disappearance of H_{2}S .

And, it is known that rate of disappearance of reactant will be negative and rate of formation of products will be positive value.

This means that,

Rate of the reaction = -Rate of disappearance of H_{2}S

                 = k[H_{2}S][Cl_{2}]

                 = (3.5 \times 10^{-2}) \times (2 \times 10^{-4}) \times (2.8 x 10^{-2})

                 = 1.96 \times 10^{-7} M/s

Therefore, calculate the rate of formation of Cl^{-} as follows.

Rate of formation of Cl^{-} = 2 \times 1.96 \times 10^{-7}

                                        = 3.92 \times 10^{-7} M/s

Thus, we can conclude that the rate of formation of Cl^{-} is 3.92 \times 10^{-7} M/s.

5 0
2 years ago
An unknown solid is entirely soluble in water. On addition of dilute HCl, a precipitate forms. After the precipitate is filtered
Karo-lina-s [1.5K]

Answer:

Pb(NO3)2

Cd(NO3)2

Na2SO4

Explanation:

In the first part, addition of HCl leads to the formation of PbCl2 which is poorly soluble in water. This is the first precipitate that is filtered off.

When the pH is adjusted to 1 and H2S is bubbled in, CdS is formed. This is the second precipitate that is filtered off.

After this precipitate has been filtered off and the pH is adjusted to 8, addition of H2S and (NH4)2HPO4 does not lead to the formation of any other precipitate.

The yellow flame colour indicates the presence of Na^+ which must come from the presence of Na2SO4.

5 0
1 year ago
When of benzamide are dissolved in of a certain mystery liquid , the freezing point of the solution is less than the freezing po
SOVA2 [1]

The given question is incomplete. The complete question is as follows.

When 70.4 g of benzamide (C_{7}H_{7}NO) are dissolved in 850 g of a certain mystery liquid X, the freezing point of the solution is 2.7^{o}C lower than the freezing point of pure X. On the other hand, when 70.4 g of ammonium chloride (NH_{4}Cl) are dissolved in the same mass of X, the freezing point of the solution is 9.9^{o}C lower than the freezing point of pure X.

Calculate the Van't Hoff factor for ammonium chloride in X.

Explanation:

First, we will calculate the moles of benzamide as follows.

    Moles of benzamide = \frac{mass}{\text{Molar mass of benzamide}}

                    = \frac{70.4 g}{121.14 g/mol}

                    = 0.58 mol

Now, we will calculate the molality as follows.

     Molality = \frac{\text{moles of solute (benzamide)}}{\text{solvent mass in kg}}

                   = \frac{0.58 mol}{0.85 kg}

                   = 0.6837

It is known that relation between change in temperature, Van't Hoff factor and molality is as follows.

      dT = i \times K_{f} \times m,

where,      dT = change in freezing point = 2.7^{o}C

                  i = van't Hoff factor = 1 for non dissociable solutes

      K_{f} = freezing point constant of solvent

                m = 0.6837

Therefore, putting the given values into the above formula as follows.

             dT = i \times K_{f} \times m,

            2.7^{o}C = 1 \times K_{f} \times 0.6837 m

            K_{f} = 3.949 C/m

Now, we use this K_{f} value for calculating i for NH_{4}Cl

So, moles of ammonium chloride are calculated as follows.

 Moles of NH_{4}Cl = \frac{70.4 g}{53.491 g/mol}

                            = 1.316 mol

Hence, calculate the molality as follows.

    Molality = \frac{1.316 mol}{0.85 kg}

                  = 1.5484

It is given that value of change in temperature (dT) = 9.9^{o}C. Thus, calculate the value of Van't Hoff factor as follows.

              dT = i \times K_{f} \times m

   9.9^{o}C = i \times 3.949 C/m \times 1.5484 m

                     i = 1.62

Thus, we can conclude that the value of van't Hoff factor for ammonium chloride is 1.62.

5 0
2 years ago
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