Answer:
Answer is explained below.
Explanation:
As (+) menthol and (-) menthol are enantiomers whose physical properties are same except optical activity so we can expect they have similar Rf values.
Whereas diastereomers have different physical properties and different Rf values.
For example when the (+) menthol , (-) menthol, isomenthol and neomenthol undergo TLC (thin layer chromatography) the
Rf values of.(+menthol) = .447
Rf (+isomenthol) = .395
Rf (+neomenthol)= .487
Rf (-menthol) = .434
The above data shows that (+) menthol and (-) menthol have almost same Rf values and vary a little i.e 0.447 and 0.437. So we can conclude them as enantiomers
Whereas (+) menthol or (+) neomenthol or (+) isomenthol i.e 0.447 , 0.395 and 0.487 have different Rf values. We can conclude them as diasteromers.
(+) menthol and (-) menthol - enantiomers
(+) menthol and (+) neomenthol- diastereomers
(-) menthol and (+) isomenthol - diastereomers
1) ideal gas law: p·V = n·R·T.
p - pressure of gas.
V -volume of gas.
n - amount of substance.
R - universal gas constant.
T - temperature of gas.
n₁ = 0,04 mol, V₁ = 0,06 l.
n₂ = 0,07 mol, V₂ = 0,06 · 0,07 ÷ 0,04 = 0,105 l.
2) V₁ = 0,06 l, T₁ = 240,00 K.
T₂ = 340,00 K, V₂ = 340 · 0,06 ÷ 240 = 0,05 l.
Answer:
ΔH of solution is expected to be close to zero.
Explanation:
When we mix two non polar organic liquids like hexane and heptane,the resulting mixture formed is an ideal solution.An ideal solution is formed when the force of attraction between the molecules of the two liquids is equal to the force of attraction between the molecules of the same type.
For instance if liquids A and B are mixed,
= 
= 
Hence the condition before and after mixing remains unchanged.
Since enthalpy change is associated with inter molecular force of attraction the enthalpy change for ideal solution is zero.
More examples of ideal solutions are:
1. Ethanol and Methanol
2. Benzene and Toluene
3. Ethyl bromide and Ethyl iodide
Answer:
The cell reaction reaches equilibrium quickly and the cell emf becomes zero.
Explanation:
The purpose of a salt bridge is not to move electrons from the electrolyte, its main function is to maintain charge balance because the electrons are moving from one-half cell to the other.
A solution of a salt that dissociates easily is normally used. Water is ineffective at functioning as a salt bridge. Hence the effect stated in the answer.
