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LUCKY_DIMON [66]
2 years ago
11

Estimate ΔG°rxn for the following reaction at 387 K. HCN (g) + 2 H2 (g) → CH3NH2 (g) ΔH° = −158.0 kJ; ΔS° = −219.9

Chemistry
1 answer:
Lina20 [59]2 years ago
4 0

Answer:

ΔG°rxn = -72.9 kJ

Explanation:

Let's consider the following reaction.

HCN(g) + 2 H₂(g) → CH₃NH₂(g)

We can calculate the standard Gibbs free energy of the reaction (ΔG°rxn) using the following expression:

ΔG°rxn = ΔH° - T.ΔS°

where,

ΔH° is the standard enthalpy of the reaction

T is the absolute temperature

ΔS° is the standard entropy of the reaction

ΔG°rxn = -158.0 KJ - 387 K × (-219.9 × 10⁻³ J/K)

ΔG°rxn = -72.9 kJ

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Explanation:

An amphoteric substance as HSO₃⁻ is a substance that act as either an acid or a base. When acid:

HSO₃⁻(aq) + H₂O(l) ⇄ H₃O⁺(aq) + SO₃²⁻(aq)

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<h3>Ka = [H₃O⁺] [SO₃²⁻] / [HSO₃⁻]</h3><h3 />

When base:

HSO₃⁻(aq) + H₂O(l) ⇄ OH⁻(aq) + H₂SO₃(aq)

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6 0
1 year ago
If a gas has a volume of 750 mL at 25oC, what would the volume of the gas be at 55oC?
blagie [28]

Answer:

The answer to your question is     V2 = 825.5 ml

Explanation:

Data

Volume 1 = 750 ml

Temperature 1 = 25°C

Volume 2= ?

Temperature 2 = 55°C

Process

Use the Charles' law to solve this problem

                V1/T1 = V2/T2

-Solve for V2

                V2 = V1T2 / T1

-Convert temperature to °K

T1 = 25 + 273 = 298°K

T2 = 55 + 273 = 328°K

-Substitution

                V2 = (750 x 328) / 298

-Simplification

                V2 = 246000 / 298

-Result

                V2 = 825.5 ml

             

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