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artcher [175]
2 years ago
5

What type of orbitals overlap to provide stability to the tert-butyl carbocation by hyperconjugation

Chemistry
1 answer:
larisa86 [58]2 years ago
7 0

Explanation:

The - 3 degree C( carbon atom) 2p atomic orbital + methyl C-H sigma molecular orbital because one C-H bond has to dissolve its bond and provide the H that is sigma molecular orbital and the carbonation is type 3 degree sp2 carbon.

Hyperconjugation is the stabilizing effect arising from the electrons ' engagement in a π-bond (usually C-H or C-C) with a neighboring empty or partly filled p-orbital or π-orbital to provide an expanded molecular orbital that enhances system stability.

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Why did you blank with the 0.0020 M Fe(NO3)3 solution as opposed to just DI water? What does it do to your spectrum? What chemic
Vlad1618 [11]

Answer:

The cuvette was blank with the solution so that the spectrometer will only read the solute absorbance. This also ensures that the spectrometer will ignore other absorbance fluctuations that normally occur due to the chemical make-up of water. The spectrometer only considered the absorbance of FeNCS^{2+} as indicated on the spectrum. The reaction between the Fe^{3+} and the SCN^{-} are both clear liquids that form the orange liquid product  FeNCS^{2+} which creates the absorbance spectrum. Because the color of the solution is orange, it reflects this and similar colors while absorbing blueish hues. We can find the absorption of only the FeNCS^{2+} by pre-rinsing the cuvette with each solution we intend to measure before placing it in the spectrometer. Also, wipe each cuvette with a kimwipe to remove all fingerprints that could effect the data collection.

Explanation:

The cuvette was blank with the solution so that the spectrometer will only read the solute absorbance. This also ensures that the spectrometer will ignore other absorbance fluctuations that normally occur due to the chemical make-up of water. The spectrometer only considered the absorbance of FeNCS^{2+} as indicated on the spectrum.

3 0
1 year ago
Check 0/1 ptRetries 5 Element R has three isotopes. The isotopes are present in 0.0825, 0.2671, and 0.6504 relative abundance. I
Tcecarenko [31]

Answer:

Atomic mass = 127.198 amu

Explanation:

The average atomic mass is obtained by summing the masses of the isotopes each multiplied by its abundance.

Atomic mass = (97.62 * 0.0825) + (109.3 * 0.2671) + (138.3 * 0.6504)

Atomic mass = 8.05365 +  29.19403 + 89.95032

Atomic mass = 127.198 amu

7 0
2 years ago
Acetaldehyde decomposes at 750 K: CH3CHO → CO + CH4. The reaction is first order in acetaldehyde and the half-life of the reacti
Degger [83]

Answer:

k = 1.3 x 10⁻³ s⁻¹

Explanation:

For a first order reaction the integrated rate law is

Ln [A]t/[A]₀ = - kt

where [A] are the concentrations of acetaldehyde in this case, t is the time and k is the rate constant.

We are given the half life for the concentration of acetaldehyde to fall to one half its original value, thus

Ln [A]t/[A]₀ = Ln 1/2[A]₀/[A]₀= Ln 1/2 = - kt

- 0.693 = - k(530s) ⇒ k = 1.3 x 10⁻³ s⁻¹

4 0
1 year ago
A lab director asks two students, Lydia and Damien, to each select a bottle of a concentrated weak base. When they reach the
Hunter-Best [27]

Answer:

First one is 5.0 M ammonia and the Second one ?

Explanation:

6 0
2 years ago
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Suggest why sodium and hydrogen ions do not diffuse at the same rate
Troyanec [42]

Answer:

sodium has got ionic bonds that are weak

compared to hydrogen covalent bonds that are strong

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