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pychu [463]
2 years ago
6

95. Using the standard enthalpy of formation data in Appendix G, calculate the bond energy of the carbon-sulfur double bond in C

S2.
Chemistry
1 answer:
prohojiy [21]2 years ago
8 0

Answer:

+523 kJ.

Explanation:

The following data will be used to calculate the average C-S bond energy in CS2(l).

S(s) ---> S(g)

ΔH = 223 kJ/mol

C(s) ---> C(g)

ΔH = 715 kJ/mol

Enthalpy of formation of CS2(l)

ΔH = 88 kJ/mol

CS2(l) ---> CS2(g)

ΔH = 27 kJ/mol

CS2(g) --> C(g) + 2S(g)

So we must construct it stepwise.

1: C(s) ---> C(g) ΔH = 715 kJ

2: 2S(s) ---> 2S(g) ΔH = 446 kJ

adding 1 + 2 = 3

ΔH = 715 + 446

= 1161 kJ

3: C(s) + 2S(s) --> C(g) + 2S(g) ΔH = 1161 kJ

4: C(s) + 2S(s) --> CS2(l) ΔH = 88 kJ

adding (reversed 3) from 4 = 5

ΔH = -1161 + 88

= -1073 kJ

5: C(g) + 2S(g) --> CS2(l) ΔH = -1073 kJ

6: CS2(l) ---> CS2(g) ΔH = 27 kJ

adding 5 + 6 = 7

ΔH = -1073 + 27

= -1046 kJ

7. C(g) + 2S(g) --> CS2(g) ΔH = -1046 kJ

Reverse and divide by 2 for C-S bond enthalpy

= -(-1046)/2

= +523 kJ.

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when the metal  is lost heat and the calorimeter of water is gained the heat 

and when the heat lost = the heat gained so,

(M*C*ΔT)m =  (M*C*ΔT)w

when Mm= mass of the metal = 30 g 

Δ Tm = (80-25) = 55 °C

and Mw = mass of water = 100 g  

Cw is the specific heat of water = 4.181 J/g.°C

ΔTw = (25-20) = 5 °C

so by substitution:

∴ 30* Cm*55 = 100 * 4.181 * 5 

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3 0
2 years ago
Read 2 more answers
0.9775 grams of an unknown compound is dissolved in 50.0 ml of water. Initially the water temperature is 22.3 degrees Celsius. A
elena-14-01-66 [18.8K]

Answer:

The enthlapy of solution is -55.23 kJ/mol.

Explanation:

Mass of water = m

Density of water = 1 g/mL

Volume of water = 50.0 mL

m = Density of water × Volume of water = 1 g/mL × 50.0 mL=50.0 g

Change in temperature of the water ,ΔT= 27.0°C - 22.3°C = 4.7°C

Heat capacity of water,c =4.186 J/g°C

Heat gained by the water when an unknown compound is dissolved be Q

Q= mcΔT

Q=50.0 g\times 4.186 J/g^oC\times 4.7^oC=983.71 J

heat released when 0.9775 grams of an unknown compound is dissolved in water will be same as that heat gained by water.

Q'=-Q

Q'= -983.71 J =-0.98371 kJ

Moles of unknown compound = \frac{0.9975 g}{56 g/mol}=0.01781 mol

The enthlapy of solution :

\frac{Q'}{moles}

=\frac{-0.98371 kJ}{0.01781 mol}=-55.23 kJ/mol

The enthlapy of solution is -55.23 kJ/mol.

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2 years ago
Analyze: The first shell can hold a maximum of two electrons. How does this explain the valence of hydrogen
chubhunter [2.5K]

Answer:

See explanation

Explanation:

Hydrogen has a valency of +1 or -1. Its electronic configuration is 1s1.

The 1s sub-level (first shell) is known to hold two electrons. This means that hydrogen may either loose this one electron in the 1s level to yield H^+ or accept another electron into this 1s level to form H^- (the hydride ion).

The formation of the hydride ion completes the 1s orbital.

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2 years ago
In 200 g of a concentrated solution of 70.4 wt% nitric acid (r = 1.41 g/mL, FW(HNO3) = 63.01 g/mol), how many grams of water are
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Answer:

59.2 grams

Explanation:

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<span>H2C=O---------H-OH </span>

<span>But you should remember that the H2O molecule will be exchanging constantly with others in the solvation shell of the formaldehyde molecule and these in turn will be exchanging with other H2O molecules in the bulk solution. </span>

<span>Formaldehyde in aqueous solution is in equilibrium with its hydrate. </span>

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