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AlladinOne [14]
2 years ago
13

Analyze and solve this partially completed galvanic cell puzzle. There are 4 electrodes each identified by a letter of the alpha

bet, A through D. The values in the partially completed grid are measured cell potentials for a cell consisting of electrode #1 and electrode #2. You may assume that each galvanic cell was properly constructed with the appropriate metals and solutions and that all the measured values in the grid are accurate.
electrode #1 ?

C

B

D

A

electrode #2?

Ecell(volts)

Ecell(volts)

Ecell(volts)

Ecell(volts)

C

0

0.91

0.62

0.26

B

0.91

0

1.53

D

0.62

1.53

0

0.36

0 volts

0.10 volts

0.26 volts

0.36 volts

0.55 volts

0.62 volts

0.65 volts

0.88 volts

0.98 volts

1.17 volts

1.27 volts

1.79 volts

1.89 volts

Chemistry
1 answer:
klasskru [66]2 years ago
5 0

Complete Question

The complete question is shown on the first uploaded image

Answer:

The correct option is  E_{cell}__{AC}} = 0.94

Explanation:

  From the question we are told that

          the cell voltage for AD is  E_{cell}__{AD}} = 1.56V

From the data give we can see that

               E_{cell}__{AD}} - E_{cell}__{BD}} = E_{cell}__{AB}}

i.e           1.56 - 1.53 = 0.03

   In the same way we can say that

              E_{cell}__{AD}}-E_{cell}__{CD}} = E_{cell}__{AC}}

=>        E_{cell}__{AC}}=1.56- 0.62

                       E_{cell}__{AC}} = 0.94

       

             

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Be sure to answer all parts. For each reaction, find the value of ΔSo. Report the value with the appropriate sign. (a) 3 NO2(g)
Liono4ka [1.6K]

Answer:

a. -268.13 J/K

b. -279.95 J/K

c. + 972.59 J/K

Explanation:

The value of the change in entropy (ΔS°) can be calculated by:

ΔS° = ∑n*S° products - ∑n*S° reactants, where n is the stoichiometric number of moles.

The values of S° for each substance can be found on a thermodynamic table.

a. 3NO2(g) + H2O(l) → 2HNO3(l) + NO(g)

S°, NO2(g) = 240.06 J/mol.K

S°, H2O(l) = 69.91 J/mol.K

S°, HNO3(l) = 155.60 J/mol.K

S°, NO(g) = 210.76 J/mol.K

ΔS° = (210.76 + 2*155.60) - (3*240.06 + 69.91)

ΔS° = -268.13 J/K

b. N2(g) + 3F2(g) → 2NF3(g)

S°, N2(g) = 191.61 J/mol.K

S°, F2(g) = 202.78 J/mol.K

S°, NF3(g) = 260.0 J/mol.K

ΔS° = (2*260.0 ) - (191.61 + 3*202.78)

ΔS° = -279.95 J/K

c. C6H12O6(s) + 6O2(g) → 6CO2(g) + 6H2O(g)

S°, C6H12O6(s) = 212 J/mol.K

S°, O2(g) = 205.138 J/mol.K

S°, CO2(g) = 213.74 J/mol.K

S°, H2O(g) = 188.83 J/mol.K

ΔS° = (6*213.74 + 6*188.83) - (212 + 6*205.138)

ΔS° = +972.59 J/K

3 0
2 years ago
A 0.050 M solution of AlCl3 had an observed osmotic pressure of 3.85 atmatm at 20°C.Calculate the van't Hoff factor iii for AlCl
Alja [10]

Answer:

The actual Van't Hoff factor for AlCl3 is 3.20

Explanation:

Step 1: Data given

Molarity of AlCl3 = 0.050 M

osmotic pressure = 3.85 atm

Temperature = 20 °C

Step 2: Calculate the Van't Hoff factor

AlCl3(aq) → Al^3+(aq) + 3Cl^-(aq)

The theoretical value is 4 ( because 1 Al^3+ ion + 3 Cl- ions) BUT due to the interionic atractions the actual value will be less

Osmotic pressure depends on the molar concentration of the solute but not on its identity., and is calculated by:

π = i.M.R.T

 ⇒ with π = the osmotic pressure = 3.85 atm

⇒ with i = the van't Hoff factor

⇒ with M = the molar concentration of the solution = 0.050 M

⇒ with R = the gas constant = 0.08206 L*atm/K*mol

⇒ with T = the temperature = 20 °C = 293.15 Kelvin

i = π /(M*R*T )

i = (3.85) / (0.050*0.08206*293.15)

i = 3.20

The actual Van't Hoff factor is 3.20

6 0
2 years ago
A 360. mg sample of aspirin, C9H8O4, (molar mass 180. g), is dissolved in enough water to produce 200. mL of solution. What is t
Gemiola [76]

Answer:

Molarity = 0.01 M

Explanation:

Molarity is used to measure the concentration of a solution. It will be same for the whole solution or a small amount of solution if the solution is homogeneous.

So, <u>Molarity of 200 mL of solution = Molarity of 50 mL of solution</u>

\mathbf{Molarity = \frac{number \ of \ moles \ of \ solute}{Volume \ of \ solution \ (in \ liters)}}

\mathbf{Moles = \frac{given \ mass \ of \ compound}{molar \ mass \ of \ compound}}

given mass of aspirin = 360 mg = 0.36 g

molar mass of aspirin = 180 g

Volume of solution = 200 mL = 0.2 L

\mathrm{Mole \ of \ Aspirin = \frac{0.36}{180} = \mathbf{0.002 \ moles}}

\mathrm{Molarity = \frac{0.002}{0.2} = \mathbf{0.01 \ M}}

Therefore, Molarity = 0.01 M

7 0
2 years ago
When iron pyrite (FeS2) is heated in air, the process known as "roasting" forms sulfur dioxide and iron(III) oxide. When the equ
Ronch [10]

Answer:

The coefficient of O2 is 11

Explanation:

Step 1:

The equation for the reaction:

FeS2 + O2 → SO2 + Fe2O3

Step 2:

Balancing the equation. The equation can be balance as follow:

FeS2 + O2 → SO2 + Fe2O3

There are 2 atoms of Fe on the right side and 1 atom on the left. It can be balance by putting 2 in front of FeS2 as shown below:

2FeS2 + O2 → SO2 + Fe2O3

There are 4 atoms of S on the left side and 1 atom on the right side. It can be balance by putting 4 in front of SO2 as shown below:

2FeS2 + O2 → 4SO2 + Fe2O3

Now, there are a total of 11 atoms of O on the right side and 2 atoms on the left side. It can be balance by putting 11/2 in front of O2 as shown below:

2FeS2 + 11/2O2 → 4SO2 + Fe2O3

Multiply through by 2 to clear the fraction as shown below:

4FeS2 + 11O2 → 8SO2 + 2Fe2O3

Now the equation is balanced.

The coefficient of O2 is 11

8 0
2 years ago
How many grams of nano3 would you add to 500g of h2o in order to prepare a solution that is 0.500 molal in nano3?
VARVARA [1.3K]
When the concentration is expressed in molality, it is expressed in moles of solute per kilogram of solvent. Since we are given the mass of the solvent, which is water, we can compute for the moles of solute NaNO3.

0.5 m = x mol NaNO3/0.5 kg water
x = 0.25 mol NaNO3

Since the molar mass of NaNO3 is 85 g/mol, the mass is

0.25 mol * 85 g/mol = 21.25 grams NaNO3 needed
4 0
2 years ago
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