<u>Answer:</u>
P2 = 778.05 mm Hg = 1.02 atm
<u>Explanation:</u>
We are to find the final pressure (expressed in atm) of a 3.05 liter system initially at 724 mm hg and 298 K which is compressed to a final volume of 2.60 liter at 273 K.
For this, we would use the equation:

where P1 = 724 mm hg
V1 = 3.05 L
T1 = 298 K
P2 = ?
V2 = 2.6 L
T2 = 173 K
Substituting the given values in the equation to get:

P2 = 778.05 mm Hg = 1.02 atm
Answer:
0.3023 M
Explanation:
Let Picric acid = 
So,
+
⇄
+ 
The ICE table can be given as:
+
⇄
+ 
Initial: 0.52 0 0
Change: - x + x + x
Equilibrium: 0.52 - x + x + x
Given that;
acid dissociation constant (
) = 0.42
![K_a = \frac{[H_3O^+][Picric^-]}{H_{picric}}](https://tex.z-dn.net/?f=K_a%20%3D%20%5Cfrac%7B%5BH_3O%5E%2B%5D%5BPicric%5E-%5D%7D%7BH_%7Bpicric%7D%7D)
![0.42 = \frac{[x][x]}{0.52-x}}](https://tex.z-dn.net/?f=0.42%20%3D%20%5Cfrac%7B%5Bx%5D%5Bx%5D%7D%7B0.52-x%7D%7D)
![0.42 = \frac{[x]^2}{0.52-x}}](https://tex.z-dn.net/?f=0.42%20%3D%20%5Cfrac%7B%5Bx%5D%5E2%7D%7B0.52-x%7D%7D)
0.42(0.52-x) = x²
0.2184 - 0.42x = x²
x² + 0.42x - 0.2184 = 0 -------------------- (quadratic equation)
Using the quadratic formula;
; ( where +/- represent ± )
= 
= 
=
OR 
=
OR 
=
OR 
= 0.30225 OR - 0.72225
So, we go by the +ve integer that says:
x = 0.30225
x = [
] = [
] = 0.3023 M
∴ the value of [H3O+] for an 0.52 M solution of picric acid = 0.3023 M (to 4 decimal places).
The final temperature of the water is the equilibrium temperature, or the also the final temperature of the iron after a long period of time. Applying the conservation of energy:
m,iron*C,iron*ΔT = - m,water*C,water*ΔT
The density of water is 1000 g/mL.
(25 g)(0.449 J/g·°C)(T - 398 K) = - (25 mL)(1000 g/mL)(4.18 J/g·°C)(T - 298)
Solving for T,
<em>T = 298.01 K</em>
Answer:
0.74 grams of methane
Explanation:
The balanced equation of the combustion reaction of methane with oxygen is:
it is clear that 1 mol of CH₄ reacts with 2 mol of O₂.
firstly, we need to calculate the number of moles of both
for CH₄:
number of moles = mass / molar mass = (3.00 g) / (16.00 g/mol) = 0.1875 mol.
for O₂:
number of moles = mass / molar mass = (9.00 g) / (32.00 g/mol) = 0.2812 mol.
- it is clear that O₂ is the limiting reactant and methane will leftover.
using cross multiplication
1 mol of CH₄ needs → 2 mol of O₂
??? mol of CH₄ needs → 0.2812 mol of O₂
∴ the number of mol of CH₄ needed = (0.2812 * 1) / 2 = 0.1406 mol
so 0.14 mol will react and the remaining CH₄
mol of CH₄ left over = 0.1875 -0.1406 = 0.0469 mol
now we convert moles into grams
mass of CH₄ left over = no. of mol of CH₄ left over * molar mass
= 0.0469 mol * 16 g/mol = 0.7504 g
So, the right choice is 0.74 grams of methane