<u>Answer:</u> The chemical equations and equilibrium constant expression for each ionization steps is written below.
<u>Explanation:</u>
The chemical formula of carbonic acid is
. It is a diprotic weak acid which means that it will release two hydrogen ions when dissolved in water
The chemical equation for the first dissociation of carbonic acid follows:

The expression of first equilibrium constant equation follows:
![Ka_1=\frac{[H^+][HCO_3^{-}]}{[H_2CO_3]}](https://tex.z-dn.net/?f=Ka_1%3D%5Cfrac%7B%5BH%5E%2B%5D%5BHCO_3%5E%7B-%7D%5D%7D%7B%5BH_2CO_3%5D%7D)
The chemical equation for the second dissociation of carbonic acid follows:

The expression of second equilibrium constant equation follows:
![Ka_2=\frac{[H^+][CO_3^{2-}]}{[HCO_3^-]}](https://tex.z-dn.net/?f=Ka_2%3D%5Cfrac%7B%5BH%5E%2B%5D%5BCO_3%5E%7B2-%7D%5D%7D%7B%5BHCO_3%5E-%5D%7D)
Hence, the chemical equations and equilibrium constant expression for each ionization steps is written above.
The question is missing. Here is the complete question.
Which balanced redox reaction is ocurring in the voltaic cell represented by the notation of
?
(a) 
(b) 
(c)
(d) 
Answer: (d) 
Explanation: <u>Redox</u> <u>Reaction</u> is an oxidation-reduction reaction that happens in the reagents. In this type of reaction, reagent changes its oxidation state: when it loses an electron, oxidation state increases, so it is oxidized; when receives an electron, oxidation state decreases, then it is reduced.
Redox reactions can be represented in shorthand form called <u>cell</u> <u>notation,</u> formed by: <em><u>left side</u></em> of the salt bridge (||), which is always the <em><u>anode</u></em>, i.e., its half-equation is as an <em><u>oxidation</u></em> and <em><u>right side</u></em>, which is always <em><u>the cathode</u></em>, i.e., its half-equation is always a <em><u>reduction</u></em>.
For the cell notation: 
Aluminum's half-equation is oxidation:

For Lead, half-equation is reduction:

Multiply first half-equation for 2 and second half-equation by 3:


Adding them:

The balanced redox reaction with cell notation
is

Answer: d. More than 6.5 grams of copper (II) is formed, and some copper chloride is left in the reaction mixture.
Explanation: 
As can be seen from the chemical equation, 2 moles of aluminium react with 3 moles of copper chloride.
According to mole concept, 1 mole of every substance weighs equal to its molar mass.
Aluminium is the limiting reagent as it limits the formation of product and copper chloride is the excess reagent as (14-7.5)=6.5 g is left as such.
Thus 54 g of of aluminium react with 270 g of copper chloride.
1.50 g of aluminium react with=
of copper chloride.
3 moles of copper chloride gives 3 moles of copper.
7.5 g of copper chloride gives 7.5 g of copper.