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1 year ago

Differences between allotropy and isotopy

Chemistry

1 answer:

raketka [301]1 year ago

3 0

Answer:

Property of an element by virtue of which it exists in two or more forms which differ only in their physical properties is known as allotropy. Allotropes are the different physical forms in which the element can exist. Allotropes are different physical forms of the same element.

Also-

Allotropes are different forms of the same element in the molecular level. Isotopes are different forms of atoms of the same chemical element. The key difference between allotropes and isotopes is that allotropes are considered at the molecular level, whereas isotopes are considered at the atomic leve

Explanation:

~Hope this helps~

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If a 0.4856 gram sample of khp is dissolved in sufficient water to prepare 250 ml of solution, and 25 ml of the solution require

dangina [55]

Mass of potassium hydrogen pthalate KHP is 0.4856 g, its molar mass is 204.22 g/mol, number of moles of KHP can be calculated as follows:

$n=\frac{m}{M}$

Here, m is mass and M is molar mass, putting the values,

$n=\frac{0.4856 g}{204.22 g/mol}=0.00237 mol$

This will be number of moles of NaOH at equivalent point.

Detailed calculations:

Molarity is defined as number of moles in 1 L of solution, for 250 mL of solution, molarity will be:

$M=\frac{0.00237 mol}{250 \times 10^{-3}L}=0.009511 M$

For 25 mL, apply dilution law as follows:

$M_{1}V_{1}=M_{2}V_{2}$

Putting the values,

$0.009511\times 250=M_{2}\times 25 mL$

On rearranging,

$M_{2}=\frac{0.009511\times 250}{25}=0.09511 M$

Convert molarity into number of moles,

$n=M\times V=0.09511 mol/L\times 25\times 10^{-3}L=0.00237 mol$

At equivalent point, number of moles of KHP will be equal to NaOH, thus, number of moles of NaOH will be 0.00237 mol.

Calculation for molarity:

Volume of NaOH is 18.75 mL, thus, molarity can be calculated as follows:

$M=\frac{n}{V}$

Putting the values,

$M=\frac{0.00237 mol}{18.75\times 10^{-3}L}=0.1264 M$

Therefore, molarity of NaOH is 0.1264 M

7 0

2 years ago

A precipitate of zinc hydroxide can be formed using the reaction below.

worty [1.4K]

Answer:

Option B is correct. KOH is the limiting reagent, and 0.27 mole of Zn(OH)2 precipitate is produced.

Explanation:

Step 1: Data given

Number of moles ZnCl2 = 0.36 moles

Number of moles KOH = 0.54 moles

Step 2: The balanced equations

ZnCl2(aq) + 2 KOH(aq) → Zn(OH)2(s) + 2 KCl(aq)

For 1 mol ZnCl2 we need 2 moles KOH to produce 1 mol Zn(OH)2 and 2 moles KCl

Step 3: Calculate the limiting reactant.

KOH is the limiting reactant. It will completely be consumed (0.54 moles). ZnCl2 is in excess. There will react 0.54/2 = 0.27 moles

There will remain 0.36 - 0.27 = 0.09 moles.

Step 4: The products

There will be produced 2 moles KCl and 1 mol Zn(OH)2. Zn(OH)2 is the precipitate produced.

For 1 mol ZnCl2 we need 2 moles KOH to produce 1 mol Zn(OH)2 and 2 moles KCl

For 0.54 moles KOH, we will produce 0.27 moles precipitate (Zn(OH)2)

Option A is not correct because 0.27 mol of Zn(OH)2 will precipitate, not 0.54 mol

Option B is correct

Option C is not correct because ZnCl2 is not the limiting reactant, but the excess reactant

Option D is not correct because ZnCl2 is not the limiting reactant, but the excess reactant

7 0

2 years ago

Examine the block from the periodic table for the element nitrogen, chemical symbol N. Using your knowledge of the periodic tabl

vodka [1.7K]

I believe that the answer is A) All Nitrogen atoms have 7 protons

4 0

2 years ago

Read 2 more answers

During a lab experiment performed at STP conditions, you prepare HCl by reacting 100. ml of Cl2 gas with an excess of H2 gas.

Brrunno [24]

Answer: 19.4 mL Ba(OH)2

Explanation:

H2(g) + Cl2(g) --> 2HCl(aq) (make sure this equation is balanced first)

At STP, 1 mol gas = 22.4 L gas. Use this conversion factor to convert the 100. mL of Cl2 to moles.

0.100 L Cl2 • (1 mol / 22.4 L) = 0.00446 mol Cl2

Use the mole ratio of 2 mol HCl for every 1 mol Cl2 to find moles of HCl produced.

0.00446 mol Cl2 • (2 mol HCl / 1 mol Cl2) = 0.00892 mol HCl

HCl is a strong acid and Ba(OH)2 is a strong base so both will completely ionize to release H+ and OH- respectively. You need 0.00892 mol OH- to neutralize all of the HCl. Note that one mole of Ba(OH)2 contains 2 moles of OH-.

0.00892 mol OH- • (1 mol Ba(OH)2 / 2 mol OH-) • (1 L Ba(OH)2 / 0.230 M Ba(OH)2) = 0.0194 L = 19.4 mL Ba(OH)2

3 0

2 years ago

Phosphorous acid, H3PO3(aq), is a diprotic oxyacid that is an important compound in industry and agriculture. K pKa1 K pKa2 1.30

FrozenT [24]

Answer:

* Before addition of any KOH:

pH = 0,0301

*After addition of 25.0 mL KOH:

pH = 1,30

*After addition of 50.0 mL KOH:

pH = 2,87

*After addition of 75.0 mL KOH:

pH = 6,70

*After addition of 100.0 mL KOH:

pH = 10,7

Explanation:

H₃PO₃ has the following equilibriums:

H₃PO₃ ⇄ H₂PO₃⁻ H⁺

k = [H₂PO₃⁻] [H⁺] / [H₃PO₃] k = 10^-(1,30) (1)

H₂PO₃⁻ ⇄ HPO₃²⁻ + H⁺

k = [HPO₃²⁻] [H⁺] / [H₂PO₃⁻] k = 10^-(6,70) (2)

Moles of H₃PO₃ are:

0,0500L×(1,8mol/L) = 0,09 moles of H₃PO₃

* Before addition of any KOH:

Using (1), moles in equilibrium are:

H₃PO₃: 0,09-x

H₂PO₃⁻: x

H⁺: x

Replacing:

$10^{-1.30} = \frac{x^2}{0.09-x}$

4.51x10⁻³ - 0.050x -x² = 0

The right solution of x is:

x = 0.0466589

As volume is 0,050L

[H⁺] = 0.0466589moles / 0,050L = 0,933M

As pH = -log [H⁺]

pH = 0,0301

*After addition of 25.0 mL KOH:

0,025L×1,8M = 0,045 moles of KOH that reacts with H₃PO₃ thus:

KOH + H₃PO₃ → H₂PO₃⁻ + H₂O

That means moles of KOH will be the same of H₂PO₃⁻ and moles of H₃PO₃ are 0,09moles - 0,045moles = 0,045moles

Henderson-Hasselbalch formula is:

pH = pka + log₁₀ [A⁻] /[HA]

Where A⁻ is H₂PO₃⁻ and HA is H₃PO₃.

Replacing:

pH = 1,30 + log₁₀ [0,045mol] / [0,045mol]

pH = 1,30

*After addition of 50.0 mL KOH:

The addition of 50.0 mL KOH consume all H₃PO₃. Thus, in the solution you will have just H₂PO₃⁻. Thus, moles in solution for the equilibrium will be:

H₂PO₃⁻: 0,09-x

HPO₃²⁻: x

H⁺: x

Replacing:

$10^{-6.70} = \frac{x^2}{0.09-x}$

1.8x10⁻⁸ - 2x10⁻⁷x - x² = 0

The right solution of x is:

x = 0.000134064

As volume is 50,0mL + 50,0mL = 100,0mL

[H⁺] = 0.000134064moles / 0,100L = 1.34x10⁻³M

As pH = -log [H⁺]

pH = 2,87

*After addition of 75.0 mL KOH:

Applying Henderson-Hasselbalch formula you will have 0,045 moles of both H₂PO₃⁻ HPO₃²⁻ and pka: 6,70:

pH = 6,70 + log₁₀ [0,045mol] / [0,045mol]

pH = 6,70

*After addition of 100.0 mL KOH:

You will have just 0,09moles of HPO₃²⁻, the equilibrium will be:

HPO₃²⁻ + H₂O ⇄ H₂PO₃⁻ + OH⁻ with kb = kw/ka = 1x10⁻¹⁴/10^-(6,70) = 5,01x10⁻⁸

kb = [H₂PO₃⁻] [OH⁻] / [HPO₃²⁻]

Moles are:

H₂PO₃⁻: x

OH⁻: x

HPO₃²⁻: 0,09-x

Replacing:

$5.01x10^{-8} = \frac{x^2}{0.09-x}$

4.5x10⁻⁹ - 5.01x10⁻⁸x - x² = 0

The right solution of x is:

x = 0.000067057

As volume is 50,0mL + 100,0mL = 150,0mL

[OH⁻] = 0.000067057moles / 0,150L = 4.47x10⁻⁴M

As pH = 14-pOH; pOH = -log [OH⁻]

pH = 10,7

I hope it helps!

6 0

2 years ago

Differences between allotropy and isotopy​

Differences between allotropy and isotopy