Here we will use the general formula of Nernst equation:
Ecell = E°Cell - [(RT/nF)] *㏑Q
when E cell is cell potential at non - standard state conditions
E°Cell is standard state cell potential = - 0.87 V
and R is a constant = 8.314 J/mol K
and T is the temperature in Kelvin = 73 + 273 = 346 K
and F is Faraday's constant = 96485 C/mole
and n is the number of moles of electron transferred in the reaction=2
and Q is the reaction quotient for the reaction
SO42-2(aq) + 4H+(aq) +2Br-(aq) ↔ Br2(aq) + SO2(g) +2H2O(l)
so by substitution :
0 = -0.87 - [(8.314*346K)/(2* 96485)*㏑Q → solve for Q
∴ Q = 4.5 x 10^-26
Mass of the gas m = 1.66
The calculated temperature T = 273 + 20 = 293
We have to calculate molar mass to determine the gas
Molar Mass = mRT / PV
M = (1.66 x 8.314 x 293) / (101.3 x 1000 x 0.001)
M = 4043.76 / 101.3 = 39.92 g/mol
So this gas has to be Argon Ar based on the molar mass.
Answer: the HCO3- to act as a base and remove excess H by the formation of H2CO3
Explanation:
H2CO3 in an aqueous solution is a buffer. This means the reaction is the following:
H2CO3 ------ HCO3- + H+
Then, the HCO3- that was formed acts as a base (absorbing a proton) like this
HCO3- + H+ ------- H2CO3
If there was an increase in H+, there would be an increase in the second reaction in an effort to neutralize that acid, thus making the H2CO3 more concentrated
Answer: 0.0007 moles of 
is released when temperature is raised.
Explanation:
To calculate the number of moles, we use the ideal gas equation, which is:
where,
P = pressure of the gas = 1.01 bar
V = Volume of the gas = 1L
R = Gas constant = 
- Number of moles when T = 20° C
Temperature of the gas = 20° C = (273 + 20)K = 293K
Putting values in above equation, we get:
- Number of moles when T = 25° C
Temperature of the gas = 25° C = (273 + 25)K = 298K
Putting values in above equation, we get:
- Number of moles released =
Hence, 0.0007 moles of is released when temperature is raised from 20° C to 25° C
<u>Answer:</u> The 
for the reaction is 72 kJ.
<u>Explanation:</u>
Hess’s law of constant heat summation states that the amount of heat absorbed or evolved in a given chemical equation remains the same whether the process occurs in one step or several steps.
According to this law, the chemical equation is treated as ordinary algebraic expressions and can be added or subtracted to yield the required equation. This means that the enthalpy change of the overall reaction is equal to the sum of the enthalpy changes of the intermediate reactions.
The given chemical reaction follows:
The intermediate balanced chemical reaction are:
(1) 
(2) 
( × 2)
(3) 
( × 2)
The expression for enthalpy of the reaction follows:
![\Delta H^o_{rxn}=[1\times (\Delta H_1)]+[2\times (-\Delta H_2)]+[2\times (\Delta H_3)]](https://tex.z-dn.net/?f=%5CDelta%20H%5Eo_%7Brxn%7D%3D%5B1%5Ctimes%20%28%5CDelta%20H_1%29%5D%2B%5B2%5Ctimes%20%28-%5CDelta%20H_2%29%5D%2B%5B2%5Ctimes%20%28%5CDelta%20H_3%29%5D)
Putting values in above equation, we get:
![\Delta H^o_{rxn}=[(1\times (-1184))+(2\times -(-234))+(2\times (394))]=72kJ](https://tex.z-dn.net/?f=%5CDelta%20H%5Eo_%7Brxn%7D%3D%5B%281%5Ctimes%20%28-1184%29%29%2B%282%5Ctimes%20-%28-234%29%29%2B%282%5Ctimes%20%28394%29%29%5D%3D72kJ)
Hence, the for the reaction is 72 kJ.
