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bekas [8.4K]
1 year ago
11

Consider the chemical reaction: N2 3H2 yields 2NH3. If the concentration of the reactant H2 was increased from 1.0 x 10-2 M to 2

.5 x 10-1 M, calculate the reaction quotient (Q) and determine which way the chemical system would shift by comparing the value of Q to K.
Chemistry
1 answer:
Brilliant_brown [7]1 year ago
8 0

The equilibrium constant of a reaction is defined as:

"The ratio between equilibrium concentrations of products powered to their reaction quotient and  equilibrium concentration of reactants powered to thier reaction quotient".

The reaction quotient, Q, has the same algebraic expressions but use the actual concentrations of reactants.

To solve this question we need this additional information:

<em>For this reaction, K = 6.0x10⁻² and the initial concentrations of the reactants are:</em>

<em>[N₂] = 4.0M; [NH₃] = 1.0x10⁻⁴M and [H₂] = 1.0x10⁻²M</em>

<em />

Thus, for the reaction:

N₂ + 3H₂ ⇄ 2NH₃

The equilibrium constant, K, of this reaction, is defined as:

K = 6.0x10^{-2} = \frac{[NH_3]^2}{[N_2][H_2]^3}

And Q, is:

Q = \frac{[NH_3]^2}{[N_2][H_2]^3}

Where actual concentrations are:

[NH₃] = 1.0x10⁻⁴M

[N₂] = 4.0M

[H₂] = 2.5x10⁻¹M

Replacing:

Q = \frac{[1.0x10^{-4}]^2}{[4.0][2.5x10^{-1}]^3}

<h3>Q = 1.6x10⁻⁷</h3>

As Q < K,

<h3>The chemical system will shift to the right in order to produce more NH₃</h3>

Learn more about chemical equililbrium in:

brainly.com/question/24301138

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How many moles of lead, Pb, are in 1.50 x 1012 atoms of lead?
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2.49*10⁻¹² mol

Explanation:

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COCl2(g) decomposes according to the equation above. When pure COCl2(g) is injected into a rigid, previously evacuated flask at
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<u>Answer:</u> The value of K_p for the reaction at 690 K is 0.05

<u>Explanation:</u>

We are given:

Initial pressure of COCl_2 = 1.0 atm

Total pressure at equilibrium = 1.2 atm

The chemical equation for the decomposition of phosgene follows:

                  COCl_2(g)\rightleftharpoons CO(g)+Cl_2(g)

Initial:            1                    -         -

At eqllm:       1-x                 x        x

We are given:

Total pressure at equilibrium = [(1 - x) + x+ x]

So, the equation becomes:

[(1 - x) + x+ x]=1.2\\\\x=0.2atm

The expression for K_p for above equation follows:

K_p=\frac{p_{CO}\times p_{Cl_2}}{p_{COCl_2}}

p_{CO}=0.2atm\\p_{Cl_2}=0.2atm\\p_{COCl_2}=(1-0.2)=0.8atm

Putting values in above equation, we get:

K_p=\frac{0.2\times 0.2}{0.8}\\\\K_p=0.05

Hence, the value of K_p for the reaction at 690 K is 0.05

3 0
1 year ago
A box has a volume of 45m3 and is filled with air held at 25∘C and 3.65atm. What will be the pressure (in atmospheres) if the sa
Marina CMI [18]

Answer:

Given:

  • Initial pressure: 3.65\; \rm atm.
  • Volume was reduced from 45\; \rm m^{3} to 5.0\; \rm m^{3}.
  • Temperature was raised from 25\; ^\circ \rm C to 35\; ^\circ \rm C.

New pressure: approximately 3.4\times 10\; \rm atm (34\; \rm atm.) (Assuming that the gas is an ideal gas.)

Explanation:

Both the volume and the temperature of this gas has changed. Consider the two changes in two separate steps:

  • Reduce the volume of the gas from 45\; \rm m^{3} to 5.0\; \rm m^{3}. Calculate the new pressure, P_1.
  • Raise the temperature of the gas from 25\; ^\circ \rm C to 35\; ^\circ \rm C. Calculate the final pressure, P_2.

By Boyle's Law, the pressure of an ideal gas is inversely proportional to the volume of this gas (assuming constant temperature and that no gas particles escaped or was added.)

For this gas, V_0 = 45\; \rm m^{3} while V_1 = 5.0\; \rm m^{3}.

Let P_0 denote the pressure of this gas before the volume change (P_0 = 3.65\; \rm atm.) Let P_1 denote the pressure of this gas after the volume change (but before changing the temperature.) Apply Boyle's Law to find the ratio between P_1\! and P_0\!:

\displaystyle \frac{P_1}{P_0} = \frac{V_0}{V_1} = \frac{45\; \rm m^{3}}{5.0\; \rm m^{3}} = 9.0.

In other words, because the final volume is (1/9) of the initial volume, the final pressure is 9 times the initial pressure. Therefore:

\displaystyle P_1 = 9.0\times P_0 = 32.85\; \rm atm.

On the other hand, by Amonton's Law, the pressure of an ideal gas is directly proportional to the temperature (in degrees Kelvins) of this gas (assuming constant volume and that no gas particle escaped or was added.)

Convert the unit of the temperature of this gas to degrees Kelvins:

T_1 = (25 + 273.15)\; \rm K = 298.15\; \rm K.

T_2 = (35 + 273.15)\; \rm K = 308.15\; \rm K.

Let P_1 denote the pressure of this gas before this temperature change (P_1 = 32.85\; \rm atm.) Let P_2 denote the pressure of this gas after the temperature change. The volume of this gas is kept constant at V_2 = V_1 = 5.0\; \rm m^{3}.

Apply Amonton's Law to find the ratio between P_2 and P_1:

\displaystyle \frac{P_2}{P_1} = \frac{T_2}{T_1} = \frac{308.16\; \rm K}{298.15\; \rm K}.

Calculate P_2, the final pressure of this gas:

\begin{aligned} P_2 &= \frac{308.15\; \rm K}{298.15\; \rm K} \times P_1 \\ &= \frac{308.15\; \rm K}{298.15\; \rm K} \times 32.85\; \rm atm \approx 3.4 \times 10\; \rm atm\end{aligned}.

In other words, the pressure of this gas after the volume and the temperature changes would be approximately 3.4\times 10\; \rm atm.

8 0
1 year ago
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