Answer:
Explanation has been given below.
Explanation:
- Chloroform has three polar C-Cl bonds. Methylene chloride has two polar C-Cl bonds. So it is expected that chloroform should be more polar and posses higher dipole moment than methylene chloride.
- Two factors are liable for the opposite trend observed in dipole moments of methylene chloride and chloroform.
- First one is the number of hyperconjugative hydrogen atoms present in a molecule. Hyperconjugation occurs with vacant d-orbital of Cl atom. Hyperconjugation amplifies charge separation in a molecule resulting higher dipole moment.
- Methylene chloride has two hyperconjugative hydrogen atoms and chloroform has one hyperconjugative hydrogen atom.Therefore methylene chloride should have higher charge separation as compared to chloroform.
- Second one is induction of opposite polarity in a C-Cl bond by another C-Cl bond in a molecule. Higher the opposite induction of polarity, lower the charge separation in a molecule and hence lower the dipole moment of a molecule.
- Chloroform has three C-Cl bonds and methylene chloride has two C-Cl bonds. Therefore opposite induction is higher for chloroform resulting it's lower dipole moment.
The chemical reaction would be written as
2 AsF3<span> + 3 CCl4 = 2 AsCl3 + 3 CCl2F2
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We use the given amounts of the reactants to first find the limiting reactant. Then use the amount of the limiting reactant to proceed to further calculations.
150 g AsF3 ( 1 mol / 131.92 g) = 1.14 mol AsF3
180 g CCl4 (1 mol / 153.82 g) = 1.17 mol CCl4
Therefore, the limiting reactant would be CCl4 since it would be consumed completely. The theoretical yield would be:
1.17 mol CCl4 ( 3 mol CCl2F2 / 3 mol CCl4 ) = 1.17 mol CCl2F2
For this problem, we use the formula for sensible heat which is written below:
Q= mCpΔT
where Q is the energy
Cp is the specific heat capacity
ΔT is the temperature difference
Q = (55.5 g)(<span>0.214 cal/g</span>·°C)(48.6°C- 23°C)
<em>Q = 304.05 cal</em>
<span>Since the diploid number of mosquitoes is six, that means that there are 6 chromosomes in every somatic (non-reproductive) cell,including the cells that make up the stomach.The six chromosomes represent two three-chromosome sets the mosquito received one set of three chromosomes from the egg cell of the mother and a similar set of three chromosomes from the sperm cell of the father.</span>