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poizon [28]
2 years ago
14

Like all equilibrium constants, Kw varies somewhat with temperature. Given that Kw is 3.31 × 10−13 at some temperature, compute

the pH of a neutral aqueous solution at that temperature.
Chemistry
1 answer:
Artyom0805 [142]2 years ago
5 0
Since Kw= [H⁺][OH⁻], and the concentration of both substances are the same, the equation is now Kw=[H⁺]²
So,
3.31x10⁻¹³ = [H⁺]²
Take the square root= 5.75x10⁻⁷
Then take the negative log to find the pH:
-log(5.75x10⁻⁷) = 6.25
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What is the ph of a solution of 0.400 m k2hpo4, potassium hydrogen phosphate?
dusya [7]
When we can get Pka for K2HPO4 =6.86 so we can determine the Ka :

when Pka = - ㏒ Ka

          6.86 = -㏒ Ka 

∴Ka = 1.38 x 10^-7

by using ICE table:

               H2PO4- →  H+  + HPO4
initial      0.4 m            0         0

change     -X                +X       +X

Equ       (0.4-X)               X          X

when Ka = [H+][HPO4] / [H2PO4-]

by substitution:

1.38 X 10^-7 = X^2 / (0.4-X)   by solving for X

∴X = 2.3x 10^-4 

∴[H+] = X = 2.3 x 10^-4

∴PH = -㏒[H+]

        = -㏒ (2.3 x 10^-4)
 ∴PH  =  3.6

3 0
1 year ago
A 0.15 m solution of chloroacetic acid has a ph of 1.86. What is the value of ka for this acid?
dem82 [27]

Answer: 1.67\times 10^{-3}

Explanation:

ClCH_2COOH\rightarrow ClCH_2COO^-+H^+

   cM              0             0

c-c\alpha        c\alpha          c\alpha  

So dissociation constant will be:

K_a=\frac{(c\alpha)^{2}}{c-c\alpha}

Given:  c = 0.15 M

pH = 1.86

K_a = ?

Putting in the values we get:

Also pH=-log[H^+]

1.86=-log[H^+]

[H^+]=0.01

[H^+]=c\times \alpha

0.01=0.15\times \alpha

\alpha=0.06

As [H^+]=[ClCH_2COO^-]=0.01

K_a=\frac{(0.01)^2}{(0.15-0.15\times 0.06)}

K_a=1.67\times 10^{-3]

Thus the vale of K_a for the acid is 1.67\times 10^{-3}

4 0
2 years ago
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CaHeK987 [17]
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2 years ago
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50cm3 of sodium hydroxide solution was titrated against a solution of sulfuric acid. The concentration of the sodium hydroxide s
miskamm [114]

Answer:

49 g/L is the concentration of the acid

Explanation:

Firstly, we proceed to write the equation of reaction.

2NaOH + H2SO4 ——-> Na2SO4 + 2H2O

We can see that 1 mole of the base reacted with two moles of the acid.

kindly note that dm^3 is same as liter

Firstly, we need to get the concentration of the reacted sulphuric acid in g/L

we use the simple titration equation below;

CaVa/CbVb = Na/Nb

From the question;

Ca = ?

Va = 25 cm^3

Cb = 20 g/L

we convert this to concentration in mol/L

Mathematically, that is concentration in g/L divided by molar mass in g/mole

molar mass of NaOH = 40 g/mol

so we have; 20g/L / 40 = 0.5 mol/L

Vb = 50 cm^3

Na = 1

Nb = 2

Where C represents concentrations, V volumes and N , number of moles

Now, substitute the values;

Ca * 25/0.5 * 50 = 1/2

25Ca/25 = 0.5

So Ca = 0.5 mol/L

Now to get the concentration of H2SO4 in g/L

What we do is to multiply the concentration in mol/L by molar mass in g/mol

That would be 0.5 * 98 = 49 g/L

4 0
2 years ago
Determine the type of each chemical equation describing a precipitation reaction. C a 2 + ( a q ) + S O 4 2 − ( a q ) ⟶ C a S O
Zepler [3.9K]

Answer:

C a B r 2 ( a q ) + N a 2 S O 4 ( a q ) ⟶ 2 N a B r ( a q ) + C a S O 4 ( s )

Explanation:

A precipitation reaction is a type of displacement reaction which a precipitate forms. The precipitate would be in the solid state, different from the other products so it can be separated or removed from the reaction.

C a 2 + ( a q ) + S O 4 2 − ( a q ) ⟶ C a S O 4 ( s )

This is wrong because  C a S O 4  is the the only product formed.

C a B r 2 ( a q ) + N a 2 S O 4 ( a q ) ⟶ 2 N a B r ( a q ) + C a S O 4 ( s )

This is the correct option, The precipitate is C a S O 4.

C a 2 + ( a q ) + 2 B r − ( a q ) + 2 N a + ( a q ) + S O 4 2 − ( a q ) ⟶ 2 N a + ( a q ) + 2 B r − ( a q ) + C a S O 4 ( s )

This is the ionic equation for the precipitation reaction

8 0
1 year ago
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