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Sedbober [7]
1 year ago
9

Electrons in __________ bonds remain localized between two atoms. electrons in __________ bonds can become delocalized between m

ore than two atoms.
Chemistry
1 answer:
dsp731 year ago
7 0

Electrons in sigma <span>bonds remain localized between two atoms. Sigma </span><span>bond results from the formation of </span><span>a molecular orbital </span><span>by the end to </span><span>end overlap of atomic </span>orbitals. Electrons<span> in pi</span> bonds can become delocalized between more than two atoms. Pi bonds result from the formation of molecular orbital by side to side overlap of atomic orbitals. 

 

<span> </span>

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(2 pts) The solubility of InF3 is 4.0 x 10-2 g/100 mL. a) What is the Ksp? Include the chemical equation and Ksp expression. MW
Aleonysh [2.5K]

Answer:

a) Ksp = 7.9x10⁻¹⁰

b) Solubility is 6.31x10⁻⁶M

Explanation:

a) InF₃ in water produce:

InF₃ ⇄ In⁺³ + 3F⁻

And Ksp is defined as:

Ksp = [In⁺³] [F⁻]³

4.0x10⁻²g / 100mL of InF₃ are:

4.0x10⁻²g / 100mL ₓ (1mol / 172g) ₓ (100mL / 0.1L) = <em>2.3x10⁻³M  InF₃. </em>Thus:

[In⁺³] = 2.3x10⁻³M  InF₃ × (1 mol In⁺³ / mol InF₃) = 2.3x10⁻³M  In⁺³

[F⁻] = 2.3x10⁻³M  InF₃ × (3 mol F⁻ / mol InF₃) = 7.0x10⁻³M F⁻

Replacing these values in Ksp formula:

Ksp = [2.3x10⁻³M  In⁺³] × [7.0x10⁻³M F⁻]³ = <em>7.9x10⁻¹⁰</em>

<em></em>

b) 0.05 moles of F⁻ produce solubility of InF₃ decrease to:

7.9x10⁻¹⁰ = [x] [0.05 + 3x]³

Where x are moles of In⁺³ produced from solid InF₃ and 3x are moles of F⁻ produced from the same source. That means x is solubility in mol / L

Solving from x:

x = -0.018 → False solution, there is no negative concentrations.

x = 6.31x10⁻⁶M → Right answer.

Thus, <em>solubility is 6.31x10⁻⁶M</em>

3 0
2 years ago
What is the final temperature of the solution formed when 1.52 g of NaOH is added to 35.5 g of water at 20.1 °C in a calorimeter
Inessa [10]

Answer : The final temperature of the solution in the calorimeter is, 31.0^oC

Explanation :

First we have to calculate the heat produced.

\Delta H=\frac{q}{n}

where,

\Delta H = enthalpy change = -44.5 kJ/mol

q = heat released = ?

m = mass of NaOH = 1.52 g

Molar mass of NaOH = 40 g/mol

\text{Moles of }NaOH=\frac{\text{Mass of }NaOH}{\text{Molar mass of }NaOH}=\frac{1.52g}{40g/mole}=0.038mole

Now put all the given values in the above formula, we get:

44.5kJ/mol=\frac{q}{0.038mol}

q=1.691kJ

Now we have to calculate the final temperature of solution in the calorimeter.

q=m\times c\times (T_2-T_1)

where,

q = heat produced = 1.691 kJ = 1691 J

m = mass of solution = 1.52 + 35.5 = 37.02 g

c = specific heat capacity of water = 4.18J/g^oC

T_1 = initial temperature = 20.1^oC

T_2 = final temperature = ?

Now put all the given values in the above formula, we get:

1691J=37.02g\times 4.18J/g^oC\times (T_2-20.1)

T_2=31.0^oC

Thus, the final temperature of the solution in the calorimeter is, 31.0^oC

4 0
2 years ago
0.9775 grams of an unknown compound is dissolved in 50.0 ml of water. Initially the water temperature is 22.3 degrees Celsius. A
elena-14-01-66 [18.8K]

Answer:

The enthlapy of solution is -55.23 kJ/mol.

Explanation:

Mass of water = m

Density of water = 1 g/mL

Volume of water = 50.0 mL

m = Density of water × Volume of water = 1 g/mL × 50.0 mL=50.0 g

Change in temperature of the water ,ΔT= 27.0°C - 22.3°C = 4.7°C

Heat capacity of water,c =4.186 J/g°C

Heat gained by the water when an unknown compound is dissolved be Q

Q= mcΔT

Q=50.0 g\times 4.186 J/g^oC\times 4.7^oC=983.71 J

heat released when 0.9775 grams of an unknown compound is dissolved in water will be same as that heat gained by water.

Q'=-Q

Q'= -983.71 J =-0.98371 kJ

Moles of unknown compound = \frac{0.9975 g}{56 g/mol}=0.01781 mol

The enthlapy of solution :

\frac{Q'}{moles}

=\frac{-0.98371 kJ}{0.01781 mol}=-55.23 kJ/mol

The enthlapy of solution is -55.23 kJ/mol.

8 0
2 years ago
Tell whether the following pairs of compounds are identical, constitutional isomers, stereoisomers, or unrelated. (a) cis-1,3-Di
Aleks04 [339]

Answer:

     (a) Constitutional Isomers

     (b) Constitutional Isomers

Explanation:

Constitutional isomers are also known with the name Structural Isomers. These are the compounds which have same chemical formula but differ in arrangement of atoms i.e. structure.

Both the compounds <em>cis-1,3-dibromocyclohexane</em> and <em>trans-1,4-dibromocyclohexane</em> have the same chemical formula C_{6} H_{10} Br_{2} but have different structure as shown in the image below.

In the second case the compounds <em>2,3-dimethylhexane</em> and <em>2,3,3-trimethylpentane</em>, both have same chemical formula C_{8} H_{18} but have different structures which is shown in the image below.

Thus it is clear that in both the groups (a) and (b) the given compounds are Constitutional Isomers.

7 0
1 year ago
Consider the formation of nitryl fluoride: 2NO2(g)+F2(g)⇌2NO2F(g) The reaction is first order in F2 and second order overall. Wh
Dahasolnce [82]

Answer:

Rate = k[NO_{2}][F_{2}]

Explanation:

  • Two reactants are present in this reaction which are NO_{2}and F_{2}
  • We know overall order of a reaction is summation of individual order with respect to reactants present in rate law equation.
  • Here, overall order of reaction is 2 including first order with respect to F_{2}
  • So, rate of reaction should also be first order with respect to another reactant i.e. first order with respect to NO_{2}
  • So, rate law: rate = k[NO_{2}][F_{2}]
7 0
1 year ago
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