Answer:
ΔS° = -268.13 J/K
Explanation:
Let's consider the following balanced equation.
3 NO₂(g) + H₂O(l) → 2 HNO₃(l) + NO(g)
We can calculate the standard entropy change of a reaction (ΔS°) using the following expression:
ΔS° = ∑np.Sp° - ∑nr.Sr°
where,
ni are the moles of reactants and products
Si are the standard molar entropies of reactants and products
ΔS° = [2 mol × S°(HNO₃(l)) + 1 mol × S°(NO(g))] - [3 mol × S°(NO₂(g)) + 1 mol × S°(H₂O(l))]
ΔS° = [2 mol × 155.6 J/K.mol + 1 mol × 210.76 J/K.mol] - [3 mol × 240.06 J/K.mol + 1 mol × 69.91 J/k.mol]
ΔS° = -268.13 J/K
The molar masses of H2S and NH3 are 34 and 17 g/mol, respectively. The equation that would best represent the given is,
Rate A/Rate B = √(molar mass B/molar mass A)
Substituting,
x/77 = √(17 /34 )
x = 54.4
Thus, it will take 54.4 seconds for NH3 to travel through the container.
Answer:
45.0 L is the volume of gas will the balloon contain at 1.35 atm and 253 K.
Explanation:
Using Ideal gas equation for same mole of gas as
Given ,
V₁ = 25.0 L
V₂ = ?
P₁ = 2575 mm Hg
Also, P (atm) = P (mm Hg) / 760
P₁ = 2575 / 760 atm = 3.39 atm
P₂ = 1.35 atm
T₁ = 353 K
T₂ = 253 K
Using above equation as:

Solving for V₂ , we get:
<u>V₂ = 45.0 L</u>
45.0 L is the volume of gas will the balloon contain at 1.35 atm and 253 K.
Answer : The half-life at this temperature is, 3.28 s
Explanation :
To calculate the half-life for second order the expression will be:
![t_{1/2}=\frac{1}{k\times [A_o]}](https://tex.z-dn.net/?f=t_%7B1%2F2%7D%3D%5Cfrac%7B1%7D%7Bk%5Ctimes%20%5BA_o%5D%7D)
When,
= half-life = ?
= initial concentration = 0.45 M
k = rate constant = 
Now put all the given values in the above formula, we get:


Therefore, the half-life at this temperature is, 3.28 s