Answer:
Explanation:
Hello,
In this case, the undergoing chemical reaction is:
Next, we identify the limiting reactant by computing the moles of magnesium oxide yielded by 3.86 g of magnesium and 155 mL of oxygen at the given conditions via their 2:1:2 mole ratios and the ideal gas equation:
It means that the limiting reactant is the oxygen as it yields the smallest amount of magnesium oxide. Next, we compute the mass of magnesium consumed the oxygen only:
Thus, the mass in excess is:
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Answer:
a. electrophilic aromatic substitution
b. nucleophilic aromatic substitution
c. nucleophilic aromatic substitution
d. electrophilic aromatic substitution
e. nucleophilic aromatic substitution
f. electrophilic aromatic substitution
Explanation:
Electrophilic aromatic substitution is a type of chemical reaction where a hydrogen atom or a functional group that is attached to the aromatic ring is replaced by an electrophile. Electrophilic aromatic substitutions can be classified into five classes: 1-Halogenation: is the replacement of one or more hydrogen (H) atoms in an organic compound by a halogen such as, for example, bromine (bromination), chlorine (chlorination), etc; 2- Nitration: the replacement of H with a nitrate group (NO2); 3-Sulfonation: the replacement of H with a bisulfite (SO3H); 4-Friedel-CraftsAlkylation: the replacement of H with an alkyl group (R), and 5-Friedel-Crafts Acylation: the replacement of H with an acyl group (RCO). For example, the Benzene undergoes electrophilic substitution to produce a wide range of chemical compounds (chlorobenzene, nitrobenzene, benzene sulfonic acid, etc).
A nucleophilic aromatic substitution is a type of chemical reaction where an electron-rich nucleophile displaces a leaving group (for example, a halide on the aromatic ring). There are six types of nucleophilic substitution mechanisms: 1-the SNAr (addition-elimination) mechanism, whose name is due to the Hughes-Ingold symbol ''SN' and a unimolecular mechanism; 2-the SN1 reaction that produces diazonium salts 3-the benzyne mechanism that produce highly reactive species (including benzyne) derived from the aromatic ring by the replacement of two substituents; 4-the free radical SRN1 mechanism where a substituent on the aromatic ring is displaced by a nucleophile with the formation of intermediary free radical species; 5-the ANRORC (Addition of the Nucleophile, Ring Opening, and Ring Closure) mechanism, involved in reactions of metal amide nucleophiles and substituted pyrimidines; and 6-the Vicarious nucleophilic substitution, where a nucleophile displaces an H atom on the aromatic ring but without leaving groups (such as, for example, halogen substituents).
First calculate the moles of N2 and H2 reacted.
moles N2 = 27.7 g / (28 g/mol) = 0.9893 mol
moles H2 = 4.45 g / (2 g/mol) = 2.225 mol
We can see that N2 is the limiting reactant, therefore we
base our calculation from that.
Calculating for mass of N2H4 formed:
mass N2H4 = 0.9893 mol N2 * (1 mole N2H4 / 1 mole N2) * 32
g / mol * 0.775
<span>mass N2H4 = 24.53 grams</span>
To determine the Keq, we need the chemical reaction in the system. In this case it would be:
CO + 2H2 = CH3OH
The Keq is the ration of the amount of the product and the reactant. We use the ICE table for this. We do as follows:
CO H2 CH3OH
I .42 .42 0
C -0.13 -2(0.13) 0.13
-----------------------------------------------
E = .29 0.16 0.13
Therefore,
Keq = [CH3OH] / [CO2] [H2]^2 = 0.13 / 0.29 (0.16^2)
Keq = 17.51
