Answer:
The answer is "Option b and Option c".
Explanation:
This buffer is a buffer of ammonia and ammonium ion. Thus it requires the solution
.
In point 1:
The solution containing
at 1M concentration would be given by mixing the two solutions. Thus, this buffer is a legitimate route.
In point 2:
It gives the ions you want but they are not the same.
In point 3:
and 
volume would not produce the same
concentrations. Therefore, this buffer isn't a valid route.
In point 4:
Some
volume and half
. This offers the same rate as half.
Boyle's law of ideal gas: This law states that the volume of a gas is inversely proportional to its pressure at a constant temperature. Acc to this law we can write the relation of pressure and volume as:

That means:

From that equation we can calculate Volume of gas at a certain pressure:
P₁=Initial pressure
V₁=Initial volume
P₂=Final pressure
V₂= Final volume
Here P₁, initial pressure is given as 85.0 kPa
V₁, initial volume is given as 525 mL
P₂, final pressure is 65.0 kPa

so,
V_{2}=85\times 525\div 65
=686 mL
Volume of gas will be 686 mL.
1) ideal gas law: p·V = n·R·T.
p - pressure of gas.
V -volume of gas.
n - amount of substance.
R - universal gas constant.
T - temperature of gas.
n₁ = 0,04 mol, V₁ = 0,06 l.
n₂ = 0,07 mol, V₂ = 0,06 · 0,07 ÷ 0,04 = 0,105 l.
2) V₁ = 0,06 l, T₁ = 240,00 K.
T₂ = 340,00 K, V₂ = 340 · 0,06 ÷ 240 = 0,05 l.
Ferromagnesian silicate minerals (i looked it up)