When the reaction equation is:
CaSO3(s) → CaO(s) + SO2(g)
we can see that the molar ratio between CaSO3 & SO2 is 1:1 so, we need to find first the moles SO2.
to get the moles of SO2 we are going to use the ideal gas equation:
PV = nRT
when P is the pressure = 1.1 atm
and V is the volume = 14.5 L
n is the moles' number (which we need to calculate)
R ideal gas constant = 0.0821
and T is the temperature in Kelvin = 12.5 + 273 = 285.5 K
so, by substitution:
1.1 * 14.5 L = n * 0.0821 * 285.5
∴ n = 1.1 * 14.5 / (0.0821*285.5)
= 0.68 moles SO2
∴ moles CaSO3 = 0.68 moles
so we can easily get the mass of CaSO3:
when mass = moles * molar mass
and we know that the molar mass of CaSO3= 40 + 32 + 16 * 3 = 120 g/mol
∴ mass = 0.68 moles* 120 g/mol = 81.6 g
Answer: pH=12.69
Explanation:
Initial 0.12 0 0
Eqm 0.12-x x x
![K_a=\frac{[H^+][F^-]}{[HF]}](https://tex.z-dn.net/?f=K_a%3D%5Cfrac%7B%5BH%5E%2B%5D%5BF%5E-%5D%7D%7B%5BHF%5D%7D)
(neglecting small value of x in comparison to 0.12)
Moles of 
0.06 moles of NaOH will give 0.06 moles of ![[OH^-]](https://tex.z-dn.net/?f=%5BOH%5E-%5D)
Now 
moles of 
will be neutralized by moles of 
and 
moles of will be left.
Molarity of 
![pOH=-\log[OH^-]=-\log[0.049]=1.31](https://tex.z-dn.net/?f=pOH%3D-%5Clog%5BOH%5E-%5D%3D-%5Clog%5B0.049%5D%3D1.31)
pH = 14 - pOH= 14 - 1.31 = 12.69
Metallic elements can bend because they have the property of being ductile. This means that a solid material stretches under tensile stress. If a material is ductile then it may be stretched into a wire. Further, the material can also be malleable.
Ideal solutions obey Raoult's law, which states that:
P_i = x_i*(P_pure)_i
where
P_i is the partial pressure of component i above a solution
x_i is the mole fraction of component i in the solution
(P_pure)_i is the vapor pressure of pure component i
In this case,
P_benzene = 0.59 * 745 torr = 439.6 torr
P_toluene = (1-0.59) * 290 torr = 118.9 torr
The total vapor pressure above the solution is the sum of the vapor pressures of the individual components:
P_total = (439.6 + 118.9) torr = 558.5 torr
Assuming the gas phase also behaves ideally, the partial pressure of each gas in the vapor phase is proportional to its molar concentration, so the mole fraction of toluene in the vapor phase is:
118.9 torr/558.5 torr = 0.213
