A 37.2-g sample of lead (Pb) pellets at 20°C is mixed with a 62.7-g sample of lead pellets at the same temperature. What are th
1 answer:
Answer:
Mass of sample is 99.9 g, density of ample is 11.35 and temperature of sample is
Explanation:
Mass is an additive property. Therefore mass of combined sample is summation of masses of two pellets.
Mass of combined sample = (37.2+62.7) g = 99.9 g
Density is an intensive property. Therefore density of combined sample of lead will be same as with density of Pb.
Density of combined sample = 11.35
Temperature is an intensive property. Therefore temperature of combined sample of lead will be same as with individual pellets.
temperature of combined sample =
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Answer : The value of is, 11.2
The value of is -9.04 kJ/mol
Explanation :
The relation between the equilibrium constant and standard Gibbs free energy is:
where,
= standard Gibbs free energy = -5.980 kJ/mol = -5980 J/mol
R = gas constant = 8.314 J/K.mol
T = temperature =
= equilibrium constant = ?
Now put all the given values in the above formula, we get:
Thus, the value of is, 11.2
Now we have to calculate the .
The formula used for is:
The given reaction is:
............(1)
where,
= Gibbs free energy for the reaction = ?
= standard Gibbs free energy = -30.5 kJ/mol
R = gas constant =
T = temperature =
Q = reaction quotient
[A] = concentration of A = 1.8 M
[B] = concentration of B = 0.55 M
Now put all the given values in the above formula 1, we get:
Therefore, the value of is -9.04 kJ/mol
Answer: All of the statements are true.
Explanation:
(a) Considering the system mentioned in the equation:-
The sum of total moles in the flask will always be equal to 1 which leads to confirmation of this statement as for 60 secs= 0.16 mol A and 0.84 mol B
(b) 0<t< 20s, mole A got reduced from 1 mole to 0.54 moles while at 40s to 60s A got decreased from 0.30 moles to 0.16 moles.
0 to 20s is 0.46 (1 - 0.54 = 0.46)mol whereas,
40 to 60s is 0.14 (0.30-.16 = 0.14) mol
(0.46 > 0.14) mol leading this statement to be true as well.
(c) Average rate from t1 = 40 to t2 = 60 s is given by:
which is true as well