Answer:
Here's what I get.
Explanation:
The frequency of a vibration depends on the strength of the bond (the force constant).
The stronger the bond, the more energy is needed for the vibration, so the frequency (f) and the wavenumber increase.
Acetophenone
Resonance interactions with the aromatic ring give the C=O bond in acetophenone a mix of single- and double-bond character, and the bond frequency = 1685 cm⁻¹.
p-Aminoacetophenone
The +R effect of the amino group increases the single-bond character of the C=O bond. The bond lengthens, so it becomes weaker.
The vibrational energy decreases, so wavenumber decreases to 1652 cm⁻¹.
p-Nitroacetophenone
The nitro group puts a partial positive charge on C-1. The -I effect withdraws electrons from the acetyl group.
As electron density moves toward C-1, the double bond character of the C=O group increases.
The bond length decreases, so the bond becomes stronger, and wavenumber increases to 1693 cm¹.
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Answer:- 0.138 M
Solution:- The buffer pH is calculated using Handerson equation:
acts as a weak acid and 
as a base which is pretty conjugate base of the weak acid we have.
The acid hase two protons(hydrogen) where as the base has only one proton. So, we could write the equation as:
Phosphoric acid gives protons in three steps. So, the above equation is the second step as the acid has only two protons and the base has one proton.
So, we will use the second pKa value. The acid concentration is given as 0.10 M and we are asked to calculate the concentration of the base to make a buffer of exactly pH 7.00.
Let's plug in the values in the equation:
Taking antilog:
On cross multiply:
[base] = 1.38(0.10)
[base] = 0.138
So, the concentration of the base that is required to make the buffer is 0.138M.
Answer:
1.73 atm
Explanation:
Given data:
Initial volume of helium = 5.00 L
Final volume of helium = 12.0 L
Final pressure = 0.720 atm
Initial pressure = ?
Solution:
"The volume of given amount of gas is inversely proportional to its pressure by keeping the temperature and number of moles constant"
Mathematical expression:
P₁V₁ = P₂V₂
P₁ = Initial pressure
V₁ = initial volume
P₂ = final pressure
V₂ = final volume
Now we will put the values in formula,
P₁V₁ = P₂V₂
P₁ × 5.00 L = 0.720 atm × 12.0 L
P₁ = 8.64 atm. L/5 L
P₁ = 1.73 atm
Answer:
The MAD of city 2 is less than the MAD for city 1, which means the average monthly temperature of city 2 vary less than the average monthly temperatures for City 1.
Explanation:
For comparing the mean absolute deviations of both data sets we have to calculate the mean absolute deviation for both data sets first,
So for city 1:
Now to calculate the mean deviations mean will be subtracted from each data value. (Note: The minus sign is ignored as the deviation is the distance of value from the mean and it cannot be negative. For this purpose absolute is used)
The deviations will be added then.
So the mean absolute deviation for city 1 is 24 ..
For city 2:
Now to calculate the mean deviations mean will be subtracted from each data value. (Note: The minus sign is ignored)
The deviations will be added then.
So the MAD for city 2 is 11.33 ..
So,
The MAD of city 2 is less than the MAD for city 1, which means the average monthly temperature of city 2 vary less than the average monthly temperatures for City 1.
