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Ipatiy [6.2K]
2 years ago
15

In a closed system, how will a decrease in pressure affect the following reaction: 2A(g) +2B(g) ⇌ 2C(g) + 2D(g)?

Chemistry
2 answers:
LekaFEV [45]2 years ago
6 0

Answer:

B. No change will occur.

Explanation:

Notice that the two moles of gas on the side of the reactants also reflects on the side of the products (i.e. there are also two moles of gas on the side of the products).

This translates to there won't be any change in the equilibrium if the pressure is increased.

The only important factor to take note of is that altering the pressure can only result in a significant change for equilibrium reactions between gases, when the reaction features a change in the number of moles of gas.

DochEvi [55]2 years ago
3 0

As number of gaseous moles in reactant and prodict are same that is 4

So No change will occur

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2 years ago
Calculate the cell potential E at 25°C for the reaction 2 Al(s) + 3 Fe2+(aq) → 2 Al3+(aq) + 3 Fe(s) given that [Fe 2+] = 0.020 M
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1.18 V

Explanation:

The given cell is:

Al(s)/Al^{3+}(0.10M)||Fe^{2+}(0.020M)/Fe(s)

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Oxidation half reaction: Al(s)\rightarrow Al^{3+}(0.10M)+2e^-;E^o_{Al^{3+}/Al}=-1.66V

Reduction half reaction: Fe^{2+}(0.020M)+2e^-\rightarrow Fe(s);E^o_{Fe^{2+}/Fe}=-0.45V

Multiply Oxidation half reaction by 2 and Reduction half reaction by 3

Net reaction: 2Al(s)+3Fe^{2+}(0.020M)\rightarrow 2Al^{3+}(0.10M)+3Fe(s)

Oxidation reaction occurs at anode and reduction reaction occurs at cathode.

To calculate the E^o_{cell} of the reaction, we use the equation:

E^o_{cell}=E^o_{cathode}-E^o_{anode}

Putting values in above equation, we get:

E^o_{cell}=-0.45-(-1.66)=1.21V

To calculate the EMF of the cell, we use the Nernst equation, which is:

E_{cell}=E^o_{cell}-\frac{0.059}{n}\log \frac{[Al^{3+}]^2}{[Fe^{2+}]^3}

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E_{cell} = electrode potential of the cell = ?V

E^o_{cell} = standard electrode potential of the cell = +1.21 V

n = number of electrons exchanged = 6

Putting values in above equation, we get:

E_{cell}=1.21-\frac{0.059}{6}\times \log(\frac{0.10^2}{0.020^3})\\\\E_{cell}=1.18V

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