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algol [13]
1 year ago
14

certain alcohol contains only three elements, carbon, hydrogen, and oxygen. Combustion of a 40.00 gram sample of the alcohol pro

duced 76.40 grams of CO2 and 46.96 grams of H2O. What is the empirical formula of the alcohol? Express your answer as a chemical formula.
Chemistry
1 answer:
seraphim [82]1 year ago
3 0

Answer:

The answer to your question is:    C₂H₆O₁   = C₂H₆O

Explanation:

Data

CxHyOz

mass = 40 g  produced 76.40 g of CO2

                                       46.96 g of H2O

Empirical formula = ?

Process

                         CxHyOz    + O2    ⇒    CO2  + H2O

                         44g of CO2 --------------------  12 g of Carbon

                         76.40 g of CO2 --------------- x

                          x = 20.84 g of Carbon

                         12 g of Carbon ---------------  1 mol

                         20.84 g of C    ---------------   x

                         x = (20.84 x 1) / 12

                         x = 1.74 mol of Carbon

                        18 g of H2O --------------------  2 g of H

                        46.96 g of H2O --------------   x

                        x = (46.96 x 2) / 18

                        x = 5.22 g of H

                        1 g of H ------------------------  1 mol of H

                        5.22 g of H -------------------   x

                        x = 5.22 mol of H

Mass of Oxygen = 40 - 20.84 - 5.22g

                           = 13.94 g

                         16 g of Oxygen ----------------  1 mol

                         13.94 g of O --------------------   x

                         x = 0.87 mol of O

Divide by the lowest number of moles

Carbon = 1.74 / 0.87 = 2

Hydrogen = 5.22 / 0.87 = 6

Oxygen = 0.87 / 0.87 = 1

                           

Empirical formula

                                 C₂H₆O₁   = C₂H₆O

                         

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Which of the compounds above are strong enough acids to react almost completely with a hydroxide ion (pka of h2o = 15.74) or wit
luda_lava [24]

The compounds can react with OH⁻ and HCO₃⁻ only C₅H₆N pyridinium

<h3><em>Further explanation </em></h3>

In an acid-base reaction, it can be determined whether or not a reaction occurs by knowing the value of pKa or Ka from acid and conjugate acid (acid from the reaction)

Acids and bases according to Bronsted-Lowry

Acid = donor (donor) proton (H + ion)

Base = proton (receiver) acceptor (H + ion)

If the acid gives (H +), then the remaining acid is a conjugate base because it accepts protons. Conversely, if a base receives (H +), then the base formed can release protons and is called the conjugate acid from the original base.

From this, it can be seen whether the acid in the product can give its proton to a base (or acid which has a lower Ka value) so that the reaction can go to the right to produce the product.

The step that needs to be done is to know the pKa value of the two acids (one on the left side and one on the right side of the arrow), then just determine the value of the equilibrium constant

Can be formulated:

K acid-base reaction = Ka acid on the left : K acid on the right.

or:

pK = acid pKa on the left - pKa acid on the right

K = equilibrium constant for acid-base reactions

pK = -log K;

K~=~10^{-pK}

K value> 1 indicates the reaction can take place, or the position of equilibrium to the right.

There is some data that we need to complete from the problem above, which is the pKa value of some compounds that will react, namely:

pyridinium pKa = 5.25

acetone pKa = 19.3

butan-2-one pKa = 19

Let's look at the K value of each possible reaction:

pka H₂O = 15.74, pka of H₂CO₃ = 6.37)

  • 1. C₅H₆N pyridinium

* with OH⁻

C₅H₆N + OH- ---> C₅H₅N- + H₂O

pK = pKa pyridinium - pKa H₂O

pK = 5.25 - 15.74

pK = -10.49

K~=~10^{4.9}

K values> 1 indicate the reaction can take place

* with HCO3⁻

C₅H₆N + HCO₃⁻-- ---> C₅H₅N⁻ + H₂CO₃

pK = 5.25 - 6.37

pK = -1.12

K`=~10^{1.12]

Reaction can take place

  • 2. Acetone C₃H₆O

* with OH-

C₃H₆O + OH⁻ ---> C₃H₅O- + H₂O

pK = 19.3 - 15.74

pK = 3.56

K~=~10^{ -3.56}

Reaction does not happen

* with HCO₃-

C₃H₆O + HCO₃⁻ ----> C₃H₅O⁻ + H₂CO₃

pK = 19.3 - 6.37

pK = 12.93

K`=~10 ^{-12.93}

Reaction does not happen

  • 3. butan-2-one C₄H₇O

* with OH-

C₄H₇O + OH- ---> C₄H₆O- + H₂O

pK = 19 - 15.74

pK = 3.26

K~=~10^{-3.26}

Reaction does not happen

* with HCO₃⁻

C₄H₇O + HCO₃⁻ ---> C₄H₆O⁻ + H₂CO₃

pK = 19 - 6.37

pK = 12.63

K~=~ 10^{-12.63}

Reaction does not happen

So that can react with OH⁻ and HCO₃⁻ only C₅H₆N pyridinium

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the lowest ph

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the concentrations at equilibrium.

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Keywords : acid base reaction, the equilibrium constant

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Answer:

Molecular formula for the gas is: C₄H₁₀

Explanation:

Let's propose the Ideal Gases Law to determine the moles of gas, that contains 0.087 g

At STP → 1 atm and 273.15K

1 atm . 0.0336 L = n . 0.082 . 273.15 K

n = (1 atm . 0.0336 L) / (0.082 . 273.15 K)

n = 1.500 × 10⁻³ moles

Molar mass of gas = 0.087 g / 1.500 × 10⁻³ moles = 58 g/m

Now we propose rules of three:

If 0.580 g of gas has ____ 0.480 g of C _____ 0.100 g of C

58 g of gas (1mol) would have:

(58 g . 0.480) / 0.580 = 48 g of C  

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7 0
2 years ago
A compound that is composed of carbon, hydrogen, and oxygen contains 70.6% C, 5.9% H, and 23.5% O by mass. The molecular weight
zhannawk [14.2K]

Answer: The molecular formula will be C_8H_8O_2

Explanation:

If percentage are given then we are taking total mass is 100 grams.

So, the mass of each element is equal to the percentage given.

Mass of C= 70.6 g

Mass of H = 5.9 g

Mass of O = 23.5 g

Step 1 : convert given masses into moles.

Moles of C =\frac{\text{ given mass of C}}{\text{ molar mass of C}}= \frac{70.6g}{12g/mole}=5.9moles

Moles of H =\frac{\text{ given mass of H}}{\text{ molar mass of H}}= \frac{5.9g}{1g/mole}=5.9moles

Moles of O =\frac{\text{ given mass of O}}{\text{ molar mass of O}}= \frac{23.5g}{16g/mole}=1.5moles

Step 2 : For the mole ratio, divide each value of moles by the smallest number of moles calculated.

For C = \frac{5.9}{1.5}=4

For H = \frac{5.9}{1.5}=4

For O =\frac{1.5}{1.5}=1

The ratio of C : H: O= 4: 4:1

Hence the empirical formula is C_4H_4O

The empirical weight of C_4H_4O = 4(12)+4(1)+1(16)= 68g.

The molecular weight = 136 g/mole

Now we have to calculate the molecular formula.

n=\frac{\text{Molecular weight }}{\text{Equivalent weight}}=\frac{136}{68}=2

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