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avanturin [10]
1 year ago
14

The equilibrium constant, Kc, for the reaction H2 (g) + I2 (g) ⇄ 2HI (g) at 425°C is 54.8. A reaction vessel contains 0.0890 M H

I, 0.215 M H2, and 0.498 M I2. Which statement is correct about this reaction mixture? View Available Hint(s) The equilibrium constant, Kc, for the reaction H2 (g) + I2 (g) ⇄ 2HI (g) at 425°C is 54.8. A reaction vessel contains 0.0890 M HI, 0.215 M H2, and 0.498 M I2. Which statement is correct about this reaction mixture? The reaction is not at equilibrium and will proceed to make more reactants to reach equilibrium. The reaction quotient is greater than 1. The reaction is not at equilibrium and will proceed to make more products to reach equilibrium. The reaction mixture is at equilibrium.
Chemistry
1 answer:
Mars2501 [29]1 year ago
4 0

Answer: The reaction is not at equilibrium and will proceed to make more products to reach equilibrium.

Explanation:  

Equilibrium constant is defined as the ratio of concentration of products to the concentration of reactants each raised to the power their stoichiometric ratios. It is expressed as K_{eq}

K is the constant of a certain reaction when it is in equilibrium, while Q is the reaction  quotient of activities of products and reactants at any stage other than equilibrium of a reaction.

For the given chemical reaction:

H_2(g)+I_2(g)\rightarrow 2HI(g)

The expression for Q is written as:

Q=\frac{[HI]^2}{[H_2]^1[I_2]^1}

Q=\frac{[0.0890]^2}{[0.215]^1[0.498]^1}

Q=0.074

Given : K_{eq} = 54.8

Thus as Q, the reaction will shift towards the right i.e. towards the product side.

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Boron has an average mass of 10.81. One isotope of boron has a mass of 10.012938 and a relative abundance of 19.80 percent. The
Andrej [43]

The average mass of an atom is calculated with the formula:

average mass = abundance of isotope (1) × mass of isotope (1) + abundance of isotope (2) × mass of isotope (2) + ...  an so on

For the boron we have two isotopes, so the formula will become:

average mass of boron = abundance of isotope (1) × mass of isotope (1) + abundance of isotope (2) × mass of isotope (2)

We plug in the values:

10.81 = 0.1980 × 10.012938  + 0.8020 × mass of isotope (2)

10.81 = 1.98 + 0.8020 × mass of isotope (2)

10.81 - 1.98 = 0.8020 × mass of isotope (2)

8.83 = 0.8020 × mass of isotope (2)

mass of isotope (2) = 8.83 / 0.8020

mass of isotope (2) = 11.009975

mass of isotope (1) = 10.012938 (given by the question)

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2 years ago
Write the expression for the equilibrium constant Kp for the following reaction.Enclose pressures in parentheses and do NOT writ
maxonik [38]

<u>Answer:</u> The expression for K_p is written below.

<u>Explanation:</u>

Equilibrium constant in terms of partial pressure is defined as the ratio of partial pressures of the products and the reactants each raised to the power their stoichiometric ratios. It is expressed as K_p

For a general chemical reaction:

aA+bB\rightleftharpoons cC+dD

The expression for K_p is written as:

K_p=\frac{P_{C}^c\times P_{D}^d}{P_{A}^a\times P_{B}^b}

The partial pressure for solids and liquids are taken as 1.

For the given chemical equation:

NH_4HS(s)\rightleftharpoons NH_3(g)+H_2S(g)

The expression for K_p for the following equation is:

K_p=\frac{(P NH_3)\times (P H_2S)}{(P NH_4HS)}

The partial pressure of NH_4HS will be 1 because it is solid.

So, the expression for K_p now becomes:

K_p=\frac{(P NH_3)\times (P H_2S)}{1}

Hence, the expression for K_p is written above.

5 0
2 years ago
BH+ClO4- is a salt formed from the base B (Kb = 1.00e-4) and perchloric acid. It dissociates into BH+, a weak acid, and ClO4-, w
Len [333]

Answer:

The pH of 0.1 M BH⁺ClO₄⁻ solution is <u>5.44</u>

Explanation:

Given: The base dissociation constant: K_{b} = 1 × 10⁻⁴, Concentration of salt: BH⁺ClO₄⁻ = 0.1 M

Also, water dissociation constant: K_{w} = 1 × 10⁻¹⁴

<em><u>The acid dissociation constant </u></em>(K_{a})<em><u> for the weak acid (BH⁺) can be calculated by the equation:</u></em>

K_{a}. K_{b} = K_{w}    

\Rightarrow K_{a} = \frac{K_{w}}{K_{b}}

\Rightarrow K_{a} = \frac{1\times 10^{-14}}{1\times 10^{-4}} = 1\times 10^{-10}

<em><u>Now, the acid dissociation reaction for the weak acid (BH⁺) and the initial concentration and concentration at equilibrium is given as:</u></em>

Reaction involved: BH⁺  +  H₂O  ⇌  B  +  H₃O+

Initial:                     0.1 M                    x         x            

Change:                   -x                      +x       +x

Equilibrium:           0.1 - x                    x         x

<u>The acid dissociation constant: </u>K_{a} = \frac{\left [B \right ] \left [H_{3}O^{+}\right ]}{\left [BH^{+} \right ]} = \frac{(x)(x)}{(0.1 - x)} = \frac{x^{2}}{0.1 - x}

\Rightarrow K_{a} = \frac{x^{2}}{0.1 - x}

\Rightarrow 1\times 10^{-10} = \frac{x^{2}}{0.1 - x}

As, x

\Rightarrow 0.1 - x = 0.1

\therefore 1\times 10^{-10} = \frac{x^{2}}{0.1 }

\Rightarrow x^{2} = (1\times 10^{-10})\times 0.1 = 1\times 10^{-11}

\Rightarrow x = \sqrt{1\times 10^{-11}} = 3.16 \times 10^{-6}

<u>Therefore, the concentration of hydrogen ion: x = 3.6 × 10⁻⁶ M</u>

Now, pH = - ㏒ [H⁺] = - ㏒ (3.6 × 10⁻⁶ M) = 5.44

<u>Therefore, the pH of 0.1 M BH⁺ClO₄⁻ solution is 5.44</u>

5 0
1 year ago
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Mandarinka [93]

Answer:

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3 0
2 years ago
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Answer:

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