Answer:
-3.7771 × 10² kJ/mol
Explanation:
Let's consider the following equation.
3 Mg(s) + 2 Al³⁺(aq) ⇌ 3 Mg²⁺(aq) + 2 Al(s)
We can calculate the standard Gibbs free energy (ΔG°) using the following expression.
ΔG° = ∑np . ΔG°f(p) - ∑nr . ΔG°f(r)
where,
n: moles
ΔG°f(): standard Gibbs free energy of formation
p: products
r: reactants
ΔG° = 3 mol × ΔG°f(Mg²⁺(aq)) + 2 mol × ΔG°f(Al(s)) - 3 mol × ΔG°f(Mg(s)) - 2 mol × ΔG°f(Al³⁺(aq))
ΔG° = 3 mol × (-456.35 kJ/mol) + 2 mol × 0 kJ/mol - 3 mol × 0 kJ/mol - 2 mol × (-495.67 kJ/mol)
ΔG° = -377.71 kJ = -3.7771 × 10² kJ
This is the standard Gibbs free energy per mole of reaction.
Answer:
Correct, because B it is reported to the nearest miligram
Explanation:
4.6 rounded up is 5
Here we have to get the correct statements among the given, applicable for Diels-Alder reaction.
The true statements in case Diels-Alder reaction are-
1. An excess of Maleic anhydride is used.
2. The I.R. of the products are indistinguishable.
The Diels-Alder reaction is the most is the most important cyclo-addition reaction in organic chemistry. These are addition reactions in which ring systems are formed without eliminating any compounds.
There remains one diene and one dienophile. The reaction is reversible in nature and requires elevated temperature to obtain its transition state. The reaction rate become faster in certain condition like using of polar solvents.
Among the given statements the following statements are true-
1. An excess of maleic anhydride (the most effective di-enophile) is used to process the reaction in forward direction.
2. The products obtain in this reaction are stereoisomers thus are indistinguishable by infrared spectroscopy (IR).
The statements which are not true for the Diels-Alder reaction:
3. The re-crystallization of the products by any polar solvent like methanol is not feasible as it will cause the retro reaction due to stability of the transition state in polar solvent.
4. Cleaning of glassware are compulsory for any reaction it is not specifically true for Diels-Alder reaction.
5. The reaction occurs at elevated temperature thus flame is required.
The pH of a buffer solution : 4.3
<h3>Further explanation</h3>
Given
0.2 mole HCNO
0.8 mole NaCNO
1 L solution
Required
pH buffer
Solution
Acid buffer solutions consist of weak acids HCNO and their salts NaCNO.
![\tt \displaystyle [H^+]=Ka\times\frac{mole\:weak\:acid}{mole\:salt\times valence}](https://tex.z-dn.net/?f=%5Ctt%20%5Cdisplaystyle%20%5BH%5E%2B%5D%3DKa%5Ctimes%5Cfrac%7Bmole%5C%3Aweak%5C%3Aacid%7D%7Bmole%5C%3Asalt%5Ctimes%20valence%7D)
valence according to the amount of salt anion
Input the value :
![\tt \displaystyle [H^+]=2.10^{-4}\times\frac{0.2}{0.8\times 1}\\\\(H^+]=5\times 10^{-5}\\\\pH=5-log~5\\\\pH=4.3](https://tex.z-dn.net/?f=%5Ctt%20%5Cdisplaystyle%20%5BH%5E%2B%5D%3D2.10%5E%7B-4%7D%5Ctimes%5Cfrac%7B0.2%7D%7B0.8%5Ctimes%201%7D%5C%5C%5C%5C%28H%5E%2B%5D%3D5%5Ctimes%2010%5E%7B-5%7D%5C%5C%5C%5CpH%3D5-log~5%5C%5C%5C%5CpH%3D4.3)
Answer:
well I think the answer is it depends on the friction
