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Murljashka [212]
2 years ago
8

A system undergoes a two-step process. In step 1, it absorbs 50. J of heat at constant volume. In step 2, it releases 5J of heat

at 1 atm. as it returned to its original internal energy. Find the change in the volume of the system during the second step and identify it as an expansion or compression.
Chemistry
1 answer:
ycow [4]2 years ago
6 0

Answer:

\Delta V=0.44\ L.

Expansion.

Explanation:

In step 1:

Since, volume is constant.

Therefore, Work Done , w=0.

q= 50\ J.

We know equation of thermodynamics,

\Delta U=q+w=0+50=50\ J  

Step 2:

Heat is released therefore, q'=-5\ J.

As system returned to its initial state.

Therefore, \Delta U'=-50\ J.

So, Work Done, w'=\Delta U'-q'=-50 -(-5)\ J=-45\ J.

Also, w'=P\times \Delta V=101325\ atm\times \Delta V.

Therefore, \Delta V=0.44\ L.

Since, \Delta V is positive.

Therefore, it is expansion.

Hence, this is the required solution.

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ra1l [238]

Answer: The oxidation state of selenium in SeO3 is +6

Explanation:

SeO3 is the chemical formula for selenium trioxide.

- The oxidation state of SeO3 = 0 (since it is stable and with no charge)

- the oxidation number of oxygen (O) IN SeO3 is -2

- the oxidation state of selenium in SeO3 = Z (let unknown value be Z)

Hence, SeO3 = 0

Z + (-2 x 3) = 0

Z + (-6) = 0

Z - 6 = 0

Z = 0 + 6

Z = +6

Thus, the oxidation state of selenium in SeO3 is +6

8 0
2 years ago
Using the following standard reduction potentials, Fe3+(aq) + e- → Fe2+(aq) E° = +0.77 V Ni2+(aq) + 2 e- → Ni(s) E° = -0.23 V ca
lina2011 [118]

<u>Answer:</u> The above reaction is non-spontaneous.

<u>Explanation:</u>

For the given chemical reaction:

Ni^{2+}(aq.)+2Fe^{2+}(aq.)\rightarrow 2Fe^{3+}(aq.)+Ni(s)

Here, nickel is getting reduced because it is gaining electrons and iron is getting oxidized because it is loosing electrons.

We know that:

E^o_{(Fe^{3+}/Fe^{2+})}=0.77V\\E^o_{(Ni^{2+}/Ni)}=-0.23V

Substance getting oxidized always act as anode and the one getting reduced always act as cathode.

To calculate the E^o_{cell} of the reaction, we use the equation:

E^o_{cell}=E^o_{cathode}-E^o_{anode}

E^o_{cell}=-0.23-0.77=-1.0V

Relationship between standard Gibbs free energy and standard electrode potential follows:

\Delta G^o=-nFE^o_{cell}

As, the standard electrode potential of the cell is coming out to be negative for the above cell. Thus, the standard Gibbs free energy change of the reaction will become positive making the reaction non-spontaneous.

Hence, the above reaction is non-spontaneous.

3 0
2 years ago
During a combustion reaction, 9.00 grams of oxygen reacted with 3.00 grams of CH4.
Monica [59]

Answer:

0.74 grams of methane

Explanation:

The balanced equation of the combustion reaction of methane with oxygen is:

  • CH₄ + 2 O₂ → CO₂ + 2 H₂O

it is clear that 1 mol of CH₄ reacts with 2 mol of O₂.

firstly, we need to calculate the number of moles of both

for CH₄:

number of moles = mass / molar mass = (3.00 g) /  (16.00 g/mol) = 0.1875 mol.

for O₂:

number of moles = mass / molar mass = (9.00 g) /  (32.00 g/mol) = 0.2812 mol.

  • it is clear that O₂ is the limiting reactant and methane will leftover.

using cross multiplication

1 mol of  CH₄ needs → 2 mol of O₂

???  mol of  CH₄  needs → 0.2812 mol of O₂

∴ the number of mol of CH₄ needed = (0.2812 * 1) / 2 = 0.1406 mol

so 0.14 mol will react and the remaining CH₄

mol of CH₄ left over = 0.1875 -0.1406 = 0.0469 mol

now we convert moles into grams

mass of CH₄ left over = no. of mol of CH₄ left over *  molar mass

                                    = 0.0469 mol * 16 g/mol = 0.7504 g

So, the right choice is 0.74 grams of methane

3 0
2 years ago
The decomposition of nitramide, O2NNH2, in water has the chemical equation and rate law O2NNH2(aq)⟶N2O(g)+H2O(l)rate=k[O2NNH2][H
FinnZ [79.3K]

Answer:

It can be concluded that the third step of the reaction is very fast, in this way, it does not contribute to the rate law

Explanation:

Please, observe the solution in the attached Word document.

Download docx
7 0
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WARRIOR [948]

Answer:

See explanation

Explanation:

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k= Ae^-Ea/RT

Where;

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A= pre-exponential factor

Ea=activation energy

R= gas constant

T= temperature

We can see from the foregoing that, as the activation energy increases, the rate of reaction decreases and vice versa. reactions that have a very high activation energy are markedly slow.

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